塩化マグネシウム水溶液と塩化カルシウム水溶液の熱力学的性質について(その1)

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(50) . !"#$%&'(D. !"#. ⪺⠪ Baabor et al. (1999) Baabor et al. (2001) Gibbard and Gossmann (1974) Haghighi et al. (2008). ࿶ജ(MPa) 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ 0.1. ᷷ᐲ(°C) 40 40 0. Ớᐲ(mol kg−1)* 0.0861–2.4420 0.0434–3.007 0.02805–1.01610. ᷹ቯ୯ ᶐㅘଥᢙ ᶐㅘଥᢙ ಝ࿕ὐ㒠ਅᐲ**. 0.1. 0. ಝ࿕ὐ㒠ਅᐲ***. ⊕↰߶߆(1974). 㘻๺᳓⫳᳇࿶. Holmes and Mesmer (1996). 㘻๺᳓⫳᳇࿶. 100.125 –103.594 109.90–250.97. 0.1839–1.8535 (0.1839–1.5900) 0.1035–1.8704. ᶐㅘଥᢙ. Jones and Pearce (1907) Loomis (1896) Menzel (1927) Patil et al. (1991) Pitzer et al. (1999)# Rivett (1912) Rodebush (1918). 0.1 0.1 0.1 㘻๺᳓⫳᳇࿶ 0.1 0.1 0.1. 0 0 0 30–70 25 0 0. 0.4242–3.9499 (0.4242–3.1589) 0.004932–0.9613 0.00996–0.29686 0.0640–0.6724 1.047–4.801 (1.047–3.737) 0.0001–5.90 (0.1–4.0) 0.0562–0.7907 0.92321–2.94084 (0.92321–1.23305) 1.051–4.104 (1.051–3.102) 1.21–17.9 (1.21–2.74). ᴣὐ਄᣹ᐲ****. ಝ࿕ὐ㒠ਅᐲ*** ಝ࿕ὐ㒠ਅᐲ** ಝ࿕ὐ㒠ਅᐲ** 㘻๺᳓⫳᳇࿶ ᶐㅘଥᢙ ಝ࿕ὐ㒠ਅᐲ** ಝ࿕ὐ㒠ਅᐲ**. Sako et al. (1985) 49.45–124.65 㘻๺᳓⫳᳇࿶ ᴣὐ਄᣹ᐲ**** Urusova 250 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ and Valyashko (1984) Valyashko et al. (1988) 249.85 1.21–15.9 (1.21–2.74) 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ Pitzer et al. (1999)# 0.1 25 0.0001–5.90 (0.1–4.0) ᐔဋᵴ㊂ଥᢙ # ᷹ቯ୯ࠍࠦࡦࡄࠗ࡞ߒߡ⸘▚ᑼࠍ␜ߒߚ‫▚⸘ߩߎޕ‬ᑼࠍ↪޿ߡᧄ⎇ⓥߢߪ 0.1 mol kg−1 ೞߺߢ⸘▚ߒߚ‫ޕ‬ * ᜝ᒐౝߢ␜ߒߚỚᐲ▸࿐ߪᧄ⎇ⓥߢᬌ⸛ߒߚ▸࿐ࠍ␜ߔ‫ޕ‬ ** Goldberg and Nuttall (1978)ߩ⸘▚୯ࠍ↪޿ߚ‫ޕ‬ *** Goldberg and Nuttall (1978)ߩᑼࠍ↪޿ߚ‫ޕ‬ **** ᄢ᳇࿶ࠍ 0.101325 MPa ߣ⟎޿ߡ᳞߼ߚ‫ޕ‬. .

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(54) . ⪺⠪ Baabor et al. (2001) Baker and Waite (1921). ࿶ജ(MPa) 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶. ᷷ᐲ(°C)* 40 58.02–173.4. Bechtold and Newton (1940). 㘻๺᳓⫳᳇࿶. Brandani et al. (1985). 㘻๺᳓⫳᳇࿶. 25–45 (35–45) 30–95. Childs and Platford (1971) Davis et al. (1986) Duckett et al. (1986). 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶. 15 50 50. Gibbard and Fong (1975) Grjotheim et al. (1988). 0.1 㘻๺᳓⫳᳇࿶. 0 100.3. Gruszkiewicz and Simonson (2005) Gruszkiewicz and Simonson (2005) Haghighi et al. (2008). 㘻๺᳓⫳᳇࿶. 140–250. 㘻๺᳓⫳᳇࿶. 107–250. 0.1. 0. ⊕↰߶߆(1974) Harrison and Perman (1927). 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶. 100.110–102.693 40–80. Holmes et al. (1978). 㘻๺᳓⫳᳇࿶. 108.85–200.85. Holmes et al. (1994). 㘻๺᳓⫳᳇࿶. 170.77–250.97. Jakli and van Hook (1972). 㘻๺᳓⫳᳇࿶. Jones and Pearce (1907) Loomis (1897) Oakes et al. (1990). 0.1 0.1 0.1. 19.702–101.000 (39.788–78.684) 0 0 0. Patil et al. (1991). 㘻๺᳓⫳᳇࿶. 30–70. Perman and Price (1913) Pitzer et al. (1999)# Plake (1935). 㘻๺᳓⫳᳇࿶ 0.1 㘻๺᳓⫳᳇࿶. 69.96–90 25 100.00124 –100.411 0.01. !". Ớᐲ(mol kg−1)* 0.0398–3.0965 2.335– 㘻 ๺ ᳓ ṁ ᶧ (2.335) 0.3043–7.0310 (0.3043–3.0335) 0.3316–8.431 (0.3316–3.661) 0.1–7.0 (0.1–4.0) 0.2438–2.7648 3.1040–12.0222 (3.1040–3.8071) 0.02755–0.72735 0.35081–7.0724 (0.35081–2.9726) 2.9485–21.8803 (2.9485–3.8206) 2.3849–5.3993 (2.3849–3.6872) 0.444–2.7679 (0.444–0.935) 0.0952–1.6431 0.1783–13.801 (0.1783–3.936) 0.7940–3.9568 (0.7940–3.5537) 0.4074–4.8131 (0.4074–3.6971) 2.9573–7.8767 (2.9573) 0.009994–1.023 0.01–0.5021 0.2911–9.4534 (0.2911–1.0234) 1.002–7.885 (1.002–3.887) 0.256–9.26 (0.256–3.63) 0.001–5.25 (0.1–4.0) 0.00081–0.315. ᷹ቯ୯ ᶐㅘଥᢙ 㘻๺᳓⫳᳇࿶ ᳓ߩᵴ㊂㘻๺᳓⫳᳇࿶ ᶐㅘଥᢙ ᶐㅘଥᢙ ᶐㅘଥᢙ ಝ࿕ὐ㒠ਅᐲ** ᶐㅘଥᢙ 㘻๺᳓⫳᳇࿶ ᶐㅘଥᢙ ಝ࿕ὐ㒠ਅᐲ*** ᴣὐ਄᣹ᐲ**** 㘻๺᳓⫳᳇࿶ ᶐㅘଥᢙ ᶐㅘଥᢙ 㘻๺᳓⫳᳇࿶ ಝ࿕ὐ㒠ਅᐲ*** ಝ࿕ὐ㒠ਅᐲ** ಝ࿕ὐ㒠ਅᐲ*** 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ ᶐㅘଥᢙ ᴣὐ਄᣹ᐲ****. 0.4959–6.972 ᶐㅘଥᢙ (0.4959–3.761) Rodebush (1918) 0.1 0 0.76676–4.32495 ಝ࿕ὐ㒠ਅᐲ** (0.76676–1.3362) Sako et al. (1985) 49.55–129.55 0.9568–5.002 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ (0.9568–3.084) Selecki and Tyminski (1967) 59.5 1.133–11.369 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ (1.133–3.859) Wood et al. (1984) 200–350 (200–250) 0.5–6.8 (0.5–3.9) 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ Zarembo et al. (1980) 149.85–349.85 0.246–5.536 㘻๺᳓⫳᳇࿶ 㘻๺᳓⫳᳇࿶ (149.85–249.85) (0.246–3.889) McLeod and Gordon (1946) 0.1 15–35 (15, 35) 0.0029934–0.075054 ᐔဋᵴ㊂ଥᢙ Mussini and Pagella (1971) 0.1 25–70 (40–70) 0.009197–0.09680 ᐔဋᵴ㊂ଥᢙ Pitzer et al. (1999)# 0.1 25 0.001–5.25 (0.1–4.0) ᐔဋᵴ㊂ଥᢙ # ᷹ቯ୯ࠍࠦࡦࡄࠗ࡞ߒߡ⸘▚ᑼࠍ␜ߒߚ‫▚⸘ߩߎޕ‬ᑼࠍ↪޿ߡᧄ⎇ⓥߢߪ 0.1 mol kg−1 ೞߺߢ⸘▚ߒߚ‫ޕ‬ * ᜝ᒐౝߢ␜ߒߚ᷷ᐲ޽ࠆ޿ߪỚᐲߩ▸࿐ߪᧄ⎇ⓥߢᬌ⸛ߒߚ▸࿐ࠍ␜ߔ‫ޕ‬ ** Staples and Nutall (1977)ߩ⸘▚୯ࠍ↪޿ߚ‫ޕ‬ *** Goldberg and Nuttall (1978)ߩᑼࠍ↪޿ߚ‫ޕ‬ **** ᄢ᳇࿶ࠍ 0.101325 MPa ߣ⟎޿ߡ᳞߼ߚ‫ޕ‬ Platford (1973). 㘻๺᳓⫳᳇࿶. !. .

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(129) . Ớᐲ(mol kg−1)* Initial Fricke (1929) 0.1 19–22.5 2.598–5.901 (20) (2.598–3.524) Gillespie et al. (1992) 10.3–13.2 250–325 0.24702–1.03868 (10.3) (250) (0.50815–1.03868) Jahn and Wolf (1993) 0.1 25 0.5015–5.700 (0.5015–4.000) Lange and Streeck (1931) 0.1 25 0.006018–0.09643 Leung and Millero (1975a) 0.1 30 1.21316 Mayrath and Wood (1983) 0.2–15.6 100–199.80 0.00324–5.428 (0.00324–3.861) 㧔㘻๺᳓⫳᳇࿶㧕 Snipes et al. (1975) 0.1 25–80 0.0652–2.053 Wang et al. (1997) 20.5 250–300 0.2470–1.5451 (250) (0.5151–1.5451) * ᜝ᒐౝߢ␜ߒߚ࿶ജ㧘᷷ᐲ㧘޽ࠆ޿ߪỚᐲߩ▸࿐ߪᧄ⎇ⓥߢᬌ⸛ߒߚ▸࿐ࠍ␜ߔ‫ޕ‬ ⪺⠪. . ࿶ജ(MPa)*. ᷷ᐲ(°C)*. Final 0.184–0.200 (0.184–0.186) 0.03358–0.71883 0.005069–0.05215 (0.005069–0.03904) 0.0001024–0.003369 0.16582–0.91288 0.00162–2.518 (0.00162–1.834) 0–0.04190 0.0997–0.7589 (0.1998–0.7589).

(130) . ⪺⠪. ࿶ജ(MPa)*. ᷷ᐲ(°C)*. Del Re et al. (1990). 0.1. 25. Gillespie et al. (1992) Holmes et al. (1994)#. 10.3–13.2 (10.3) 7.2–43.5. Lange and Streeck (1931) Leung and Millero (1975b) Lilich et al. (1978)##. 0.1 0.1 0.1. 250–325 (250) 24.96–253.38 (24.96–200.20) 25 30 0–50. Oakes et al. (1998). 20.9–21.8. Ớᐲ(mol kg−1)* Initial (Add)** 0.928–7.070 (0.928–3.981) 0.2489–1.0463 (0.50457–1.0463) 0.0500–7.2589 (0.0500–3.2261)*** 0.006018–0.09647 0.98994 0.2–11.9 (0.2–4.0) 1.048–6.040 (1.048–3.772)*** 0.025–3.291*** 0.0125–0.5. Final 0.087–6.587 (0.087–3.981) 0.10007–0.82223 0.0083–5.8071 (0.0083–1.0012)*** 0.0001062–0.003369 0.18961–0.68652 0. 100.03–299.85 0.010–4.869 (100.03–249.85) (0.010–2.742)*** Perachon and Thourey (1978) 0.1 25 0*** Plake (1932) 0.1 0.26–20.34 0.00025–0.02 (0.26–20)**** Richards and Dole (1929) 0.1 20–25 1.110–0.0173 0.555–0.00867 # 7.3MPa㧘200.2°C ߩ᧦ઙਅߢ initial ߇ 1 mol kg−1 ߢ final ߇ 0.025 mol kg−1 ޽ࠆ޿ߪ 0.0166 mol kg−1 ߩ࠺࡯࠲ߪߘ ߩઁߩ୯ߣ⺞๺⊛ߢߪߥ޿ߩߢ㧘⸘▚ߦ฽߼ߡ޿ߥ޿‫ޕ‬ ## ේႎߩ⹦⚦߇ਇ᣿ߥߩߢ Ananthaswamy and Atkinson (1985)ਛߩ୯ࠍ↪޿ߚ‫ޕ‬ * ᜝ᒐౝߢ␜ߒߚ࿶ജ㧘᷷ᐲ㧘޽ࠆ޿ߪỚᐲߩ▸࿐ߪᧄ⎇ⓥߢᬌ⸛ߒߚ▸࿐ࠍ␜ߔ‫ޕ‬ ** Initial ޽ࠆ޿ߪ Add ߩౝߩỚᐲߩ㜞޿ᣇߩ୯‫ޕ‬ *** Initial ߩỚᐲ߇ 4 mol kg−1 ࠍ⿥߃ߡ޿ࠆታ㛎⚿ᨐߢ޽ߞߡ߽㧘Final ߩỚᐲ߇ 4 mol kg−1 ࠍਅ࿁ߞߡ޿ࠆ႐วߦ ߪ㧘ታ㛎⚿ᨐࠍ⚵ߺวࠊߖߡᏗ㉼ᾲࠍ⸘▚ߒߚ‫ޕ‬Holmes et al. (1994)ࠍ଀ߦߒߡ⺑᣿ߔࠆߣᰴߩࠃ߁ߦߒߚ‫ޕ‬Initial ߩỚᐲ߇ 7.2589 mol kg−1 ߢ Final ߩỚᐲ߇ 3.2261 mol kg−1 ߩታ㛎⚿ᨐߣ 2.0739 mol kg−1 ߩታ㛎⚿ᨐࠍ⚵ߺวࠊߖߡ㧘 Initial ߩỚᐲ߇ 3.2261 mol kg−1 ߢ Final ߩỚᐲ߇ 2.0739 mol kg−1 ߩᤨߩᏗ㉼ᾲࠍ⸘▚ߒߚ‫ޕ‬ **** 20°C ઃㄭߩ୯ߪ Garvin et al. (1987)߇ 20°C ߦ឵▚ߒߚ୯ࠍ૶↪ߒߚ‫ޕ‬ F

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(155) ]^_àbcd0ef]^gbcd0ef!567yz*. . . ൻ. . ⪺⠪ ࿶ജ(MPa) ᷷ᐲ(°C)* Ớᐲ(mol kg−1)* Call et al. (2000) 0.35 5–120 0.00837–0.99851 Eigen and Wicke (1951) 0.382–0.949 㘻๺᳓⫳᳇࿶ 10–130 Fedyainov et al. (1970) 0.1 25 0.0395–5.5231 (0.1976–3.8427) Likke and Bormley (1973) 0.2192–0.8981 㘻๺᳓⫳᳇࿶ 80–180 Perron et al. (1974) 0.1 25 0.00386–0.34096 (0.01332–0.34096) Perron et al. (1981) 0.1 25 0.13680–5.02800 (0.13680–3.44500) Saluja and LeBlanc (1987) 0.6 25–100 0.10844–0.52775 Saluja et al. (1995) 0.6 25–100 0.4422–5.1855 (0.4422–3.5806) Vasilev et al. (1973) 0.1 25 0.4636–5.1139 (0.4636–3.5081) White (1988) 2.33–17.90 75.92–324.66 (75.92–225.70) 0.0311–2.2616 * ᜝ᒐౝߢ␜ߒߚ᷷ᐲ޽ࠆ޿ߪỚᐲߩ▸࿐ߪᧄ⎇ⓥߢᬌ⸛ߒߚ▸࿐ࠍ␜ߔ‫ޕ‬ .

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