⚿᥏⴫㕙䈱ⷙೣ᭴ㅧ䉕↪䈇䈩ᯏ⢻ᕈಽሶ䈱䉝䉶䊮䊑䊥䉕૞ᚑ䈜䉎䈢䉄䈱ⷐ⚛ᛛⴚ䈫䈚䈩䇮㽲⴫㕙ⷙೣ᭴ㅧ䈱૞ᚑ䊶

ℂᎿቇ⎇ⓥᚲ ౒ห⎇ⓥ╙㧝㘃

⎇ⓥઍ⴫⠪ ᣂ⮮ᢪ ⎇ⓥຬ

⚿᥏⴫㕙᭴ㅧ䈱቟ቯᕈ䈱೙ᓮ䈍䉋䈶ಽሶ㈩೉䈻䈱ᔕ↪

⚿᥏⴫㕙᭴ㅧ䈱቟ቯᕈ䈱೙ᓮ䈍䉋䈶ಽሶ㈩೉䈻䈱ᔕ↪

⚿᥏⴫㕙䈱ⷙೣ᭴ㅧ䉕↪䈇䈩ᯏ⢻ᕈಽሶ䈱䉝䉶䊮䊑䊥䉕૞ᚑ䈜䉎䈢䉄䈱ⷐ⚛ᛛⴚ䈫䈚䈩䇮㽲⴫㕙ⷙೣ᭴ㅧ䈱૞ᚑ䊶

⹏ଔᛛⴚ䈱㐿⊒䇮㽳ᯏ⢻ᕈಽሶ䈱᭴ㅧ⸳⸘䈫ⷙೣ㈩೉䇮㽴⚿᥏⴫㕙᭴ㅧ䈫ಽሶ䈫䈱⋧੕૞↪䈱⸃᣿䇮䈱䋳ὐ䈮䈧䈇 䈩䋳ᐕ㑆䈮䉒䈢䈦䈩⎇ⓥ䈚䈩䈐䈢䇯㽲䈮䈧䈇䈩䈲ᣂ⮮䊶ㇳ䈏ේሶ㑆ജ㗼ᓸ㏜䋯៺ᡂജ㗼ᓸ㏜䈮䉋䉎὇㉄䉟䉥䊮䉕฽䉃

᭴ㅧ䈱⹏ଔ䉕ⴕ䈇䇮䉟䉥䊮䈱ะ䈐䈱⛘ኻ⊛್೎ᴺ[1]䈍䉋䈶 䌰H 䈮ଐሽ䈚䈢⴫㕙䈱቟ቯᕈ䈱ᄌൻ䈮䈧䈇䈩⺞䈼䈢[2,3]䇯 㽳䈮䈧䈇䈩䈲౒ห⎇ⓥ⠪䈱⧐⾐䊶⼾䈏᦭ᯏEL↪

㍲૕䈱⸳⸘䈫ᯏ⢻⹏ଔ䉕[4]䇮䉁䈢䇮ጊㄝ-⠀↰䉌䈏᳓⚛⚿ว䉕฽

䉃ಽሶᕈ⚿᥏䈱᭴ㅧ቟ቯᕈ䈱⎇ⓥ䉕ⴕ䈦䈢[5,6]䇯એ਄䈮䈧䈇䈩䈲ᣢ䈮ႎ๔䈚䈢䈱䈪䇮੹࿁䈲㽴䈮䈧䈇䈩ㅀ䈼䉎䇯․䈮䇮

᭴ㅧ䈏න⚐䈪䈅䉍䇮ᣢሽ䈱ᣇᴺ䈮䉋䉎⎇ⓥ଀䉅⼾ን䈭㘩Ⴎ⚿᥏⴫㕙䈱ේሶᐔမൻ䈱଀䉕ข䉍਄䈕䈢䇯

࿑䋱䈮␜䈚䈢䈱䈲HgCl

䈱䉣䉺䊉䊷䊦ṁᶧ䉕↪䈇䈩NaCl(110)㕙䉕ᐔမൻ䈚䈢䈫䈐䈱ේሶ㑆ജ㗼ᓸ㏜௝䈪䈅䉎䇯⚿᥏ 䈎䉌ಾ䉍಴䈚䈢䈣䈔䈱㕙䈲䋨䌡䋩䈱䉋䈉䈮☻㕙䈪䈅䉎䈏䇮ṁᶧ䈮䈧䈔䈩䈍䈒䈫ᷝട‛ಽሶ䈱቟ቯ䈭ๆ⌕᭴ㅧ䈏↢ᚑ䈚䇮ᐔ မൻ䈏⿠䈖䉎䇯䋨䌢䋩ਛ䈱ᢙ୯䈲ᲑᏅ䈱㜞䈘䈪䈅䉍䇮䊙䉪䊨䉴䊁䉾䊒䈮䈭䈦䈩䈇䉎䇯䈚䈎䈚䇮⹜ᢱ䉕ᄢ᳇ਛ䈮ข䉍಴䈚䈩ᐔမ ㇱ䉕᜛ᄢ䈜䉎䈫䋨䌣䋩䈱䉋䈉䈮ේሶ௝䈏ᓧ䉌䉏䇮ේሶᐔမ䈪䈅䉎䈖䈫䈏ಽ䉎䇯䈖䉏એᄖ䈮䉅᭽䇱䈭ᷝട‛䉕↪䈇䇮䉴䊁䉾䊒 㕙䉅฽䉄䈩䈇䉐䈇䉐䈭㕙䉕ᐔမൻ䈜䉎䈖䈫䈏䈪䈐䈢䇯ๆ⌕ಽሶ䈱᭴ㅧ䈫䈱⋧㑐䉕⺞䈼䉎䈖䈫䈮䉋䉍䇮ಽሶ䈫⴫㕙᭴ㅧ䈱

⋧੕૞↪䈏ಽ䉎䇯

References

[䋱] Kwak

䋧

[2] Kwak & Shindo, J. Cryst. Growth,275, e1655 (2004).

[3] Shindo & Kwak, Phys. Chem. Chem. Phys.,7, 691 (2005).

[4] Yutaka et al.,Inorg. Chem.,44, 4737 (2005).

[5] Yamanobe-Hada, et al., J. Cryst. Growth,275, e1739 (2005).

[6] Ito et al., J. Cryst. Growth,275, e1691 (2005).

[7] Karino & Shindo, submitted.

2.32nm 2.32nm 4.60nm

4.60nm Dissolution process

䋨

㱘

䋩

(b) After䋨90min䋩

0.53nm

䋨

䋦䋩

[001]

[-110]

0.72nm

䋨

䋦䋩

<100>

<110> <100>

<110>

<110>

<112>

(100) (110) (111)

0.0 0.1 0.2 0.3 0.4 0.5

<100>

<100>

<110>

<110>

<110>

<112>

Ratio₍₁₀₀₎=1.64

Ratio₍₁₁₀₎=2.19 Ratio₍₁₁₁₎=1.06

࿑䋱䋮䌈䌧䌃䌬

䋯䌅䌴䌏䌈䈮䉋䉎䌎䌡䌃䌬䋨䋱䋱䋰䋩㕙䈱ᐔမൻ䈱䌁䌆䌍ⷰኤ䋮 એ਄䈱䉋䈉䈮䈚䈩ᓧ䉌䉏䈢䌎䌡䌃䌬䋨䋱䋱䋰䋩䈍䉋䈶䋨䋱䋱䋱䋩

ේሶᐔမ㕙䉕↪䈇䈩ේሶ䊧䊔䊦䈱៺ᡂ䈱⇣ᣇᕈ䉕⺞

䈼䈢[7]䇯࿑䋲䈮䋨䋱䋰䋰䋩㕙䉅฽䉄䈩ਃ䈧䈱ૐᜰᢙ㕙䈱

᭴ㅧ䉕␜䈜䇯៺ᡂജ㗼ᓸ㏜䉕↪䈇䈩⍫ශ䈱ᣇะ䈮ត

㊎䉕⿛ᩏ䈚䈢䈫䈐䈱៺ᡂଥᢙ䉕࿑䋳䈮␜䈚䈢䇯੍᷹䈚䈢 䈫䈍䉍䇮䋨䋱䋱䋰䋩㕙䈪䋼䋱䋱䋰䋾ᣇะ䈮⿛ᩏ䈚䈢䈫䈐䈱៺

ᡂ䈲⋡┙䈦䈩ዊ䈘䈒䇮䈖䈱㕙䈏⚿᥏䈱䈜䈼䉍㕙䈫䈚䈩௛

䈒䈖䈫䈏ℂ⸃䈪䈐䉎䇯

ᭂᕈ䈱䋨䋱䋱䋱䋩㕙䈪䈲៺ᡂ䈏Ᏹ䈮ዊ䈘䈒䇮⇣ᣇᕈ䉅䈭 䈇䈏䇮䈖䈱㕙䈮䈧䈇䈩䈲ૐḨᐲ䈪䉅᳓䈏⴫㕙䈮ๆ⌕䈚䇮 ẢṖ೷䈫䈚䈩௛䈇䈩䈇䉎น⢻ᕈ䈏ᒝ䈇䇯ઁ䈱㕙䈪䈲Ḩ ᐲ䈮䉋䉍៺ᡂଥᢙ䈏ᄢ䈐䈒ᄌൻ䈜䉎䇯

࿑䋲䋮䌎䌡䌃䌬⚿᥏ૐᜰᢙ㕙䈱᭴ㅧ䈫៺ᡂ䈱᷹ቯᣇะ䋮

࿑䋳䋮៺ᡂജ㗼ᓸ㏜䈪᷹ቯ䈚䈢䌎䌡䌃䌬⚿᥏ૐᜰᢙ 㕙䈱⇣ᣇᕈ៺ᡂଥᢙ䋮

(a)Before (c)