㫽ྲྀᏛᕤᏛ㒊≀㉁ᕤᏛ⛉࠾ࡅࡿࢭ࣑ࣛࢵࢡࢫ⣔◊✲ᐊࡢ࠶ࡺࡳ
㸫 ᶵ⬟ᛶࢭ࣑ࣛࢵࢡࢫᮦᩱࡢⓎᒎ 㸫
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Ụᆏ㻌 ா⏨㻌
㫽ྲྀᏛᏛ㝔ᕤᏛ◊✲⛉Ꮫ䞉⏕≀ᛂ⏝ᕤᏛᑓᨷ㻌
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Prospect and Development of Functional Inorganic Materials
Takao ESAKA
Department of Chemistry and Biotechnology,
Graduate School of Engineering, Tottori University,
Tottori, 680-8552 Japan
E-mail: [email protected]
Abstract: To develop high performance solid ionic conductors, various kinds of compounds and solid solutions have
been prepared and the relations between their crystal structures and conductivities have been studied. Here, the prospect and development of the solid ionic conductors were mentioned especially focusing on the 38 year’s results by the present author’s laboratory together with the innovative experimental methods.
Keywords: Solid state ionics, Ionic conductor, Solid electrolyte, Solid oxide fuel cell, Neutron radiography㻌 㻌 㻌 㻌 㸯㸬 ࡣࡌࡵ 㻌 㻌 ☜䛛㻞㻜㻜㻜ᖺ䛾䝉䝷䝭䝑䜽䝇༠グᛕㄅ䛻◊✲ᐊ⤂䜢 ව䛽䛯䛣䜜䜎䛷䛾䛒䜖䜏䜢ᢞ✏䛧䠈䇿㒊ᒇ䛾ቨ䛻䛿ྛ䝁 䞊䝘䞊䛻㻡䝭䝸ᖜ䜒䛒䜛㛗䛔ட䛜ධ䜚䠈㻶㻾䛾㧗ᯫᶫ䛷䛿 䛺䛔䛜㧗ᗘᡂ㛗ᮇ䛻䛷䛝䛯䝁䞁䜽䝸䞊䝖ᘓ㐀≀䛾⤒ᖺኚ 䛾⃭䛧䛥䜢≀ㄒ䛳䛶䛔䜛䠊䛣䛾㒊ᒇ䛾ఫே䜒⚾䛷㻞௦ ┠䛸䛺䜚᪤䛻㻝㻜ᖺ௨ୖ㐣䛞䛯䠊ᮏᙜ䛻᭶᪥䛾㐣䛞䜛䛾䛿 ㏿䛔䜒䛾䛷䛒䜛䠊䇿䛸᭩䛔䛯䠊⌧ᅾ䛷䛿ᘓ≀䛜⪏㟈⿵ᙉ 䛷ᨵಟ䛥䜜䠈෭ᬮᡣഛ䛷ᛌ㐺䛷䛒䜛䠊䛩䜉䛶ᛮ䛔㏻䜚 䛻䛺䛳䛯䜟䛡䛷䛿䛺䛔䛾䛰䛜䠈㛗ᖺ䛔䜛䛸䛔䛔䛣䛸䜒䛒䜛 䛾䛰䛺䛸ឤ䛨䛶䛔䜛䠊㻌 㻌 䛥䛶䛣䛾㛫䛾◊✲ᐊ䛾䛒䜖䜏䜢⤂䛧䜘䛖䛸䛩䜛䛾䛜ᮏ ✏䛾┠ⓗ䛷䛒䜛䠊㐣ཤ䛾Ṕྐ䜢Ꮫ⏕䛾ྡ๓䛸㢦䜢ᛮ䛔 ฟ䛧䛺䛜䜙ಶ䚻䛻䜚㏉䛳䛶㒓ឋ䛻ᾐ䜛䛾䜒䛔䛔䛛䜒䛧 䜜䛺䛔䠊䛧䛛䛧䛭䛖䛩䜛䛣䛸䛷䛿⦅㞟ጤဨ䛾ᇳ➹౫㢗 䛾ពྥ䛻ῧ䛖䛣䛸䛻䛺䜙䛺䛔Ẽ䛜䛩䜛䠊䛧䛯䛜䛳䛶䛣䛣䛷 䛿䛭䜜䜢㋃䜎䛘䛴䛴䠈䛣䛾ศ㔝䛾Ⓨᒎ䛻㛵䛩䜛≉ᚩⓗ 䛺◊✲ෆᐜ䛸䛸䜒䛻ᕤᏛ㒊䛷䝉䝷䝭䝑䜽䝇䜢ᢅ䛳䛶䛝䛯ᙜ ◊✲ᐊ䛻㛵䛩䜛䛣䜜䜎䛷䛾◊✲䜢⤂䛩䜛䛣䛸䛸䛩䜛䠊㻌 㻌 㸰㸬 ≀㉁ᕤᏛ⛉↓ᶵᮦᩱᏛ◊✲ᐊ 㻌 㻌 ᙜヱ◊✲ᐊ䛿䠈⌧ᅾỤᆏ୍ே䛜ᢸᙜ䛧䛶䛔䜛䠊㻞㻜㻝㻞ᖺ 䜎䛷䛿༡᮲ᩍᤵ䛸㧗ຓᩍ䠈᭦䛻䛭䜜௨๓䛾㻞㻜㻜㻡ᖺ 䜎䛷䛿ᆏཱྀຓᩍᤵ䛸㧗ຓᡭ䜢ྵ䜑䛶䜾䝹䞊䝥䜢⤌䜣 䛷䛔䛯䠊䛣䛾◊✲ᐊ䛿ᨵ⤌๓䛾㈨※ᚠ⎔Ꮫ⛉㈨※ Ꮫ◊✲ᐊ㻔ᒾཎᩍᤵ䠈Ụᆏຓᩍᤵ䠈ෆ⏣ຓᡭ㻕䛾ὶ䜜䜢 Ữ䜐䜒䛾䛷䛒䜛䠊㛗ᖺ䠈┬㈨※䞉┬䜶䝛䝹䜼䠉䜢┠ᣦ䛧 䛯ᶵ⬟ᛶᮦᩱ㛤Ⓨ䛸䛭䛾ᛂ⏝䜢䝔䞊䝬䛸䛧䛶㑅䜣䛷◊ ✲䛸ᩍ⫱άື䜢⾜䛳䛶䛝䛯䠊䛣䛾୰䛷䛾䝉䝷䝭䝑䜽䝇䛻㛵 䛩䜛◊✲䛸䛧䛶➨୍䛻ᣲ䛢䜛䛣䛸䛜䛷䛝䜛䜒䛾䛻䠈㟁Ẽఏ ᑟᛶ䝉䝷䝭䝑䜽䝇ᮦᩱ䠈≉䛻䜲䜸䞁ఏᑟᛶᮦᩱ䛾㛤Ⓨ䛜 䛒䜛䠊䛣䜜䛿䠈䛭䜜䜙䛾ᑟ㟁ᛶ䝉䝷䝭䝑䜽䝇䛜⇞ᩱ㟁ụ䠈䝸 䝏䜴䝮㟁ụ䠈䜺䝇䝉䞁䝃䞊䠈䜺䝇ศ㞳䛺䛹䛻ᛂ⏝䛷䛝䜛䛣
䛸䜢⪃䛘䛯䜒䛾䛷䛒䜛䠊㻌 㻌 㸱㸬 ࢜ࣥఏᑟᮦᩱࡢタィ 㻌 㻌 㻌 ᅛయ୰䜢䛒䜛⛬ᗘ⮬⏤䛻䜲䜸䞁䛜ື䛝ᅇ䜚䠈䛣䜜䛻㟁 ሙ䜢䛛䛡䜛䛸䛭䛾䜲䜸䞁䛻䜘䜛ᑟ㟁ᛶ䛜⌧䜜䜛䜒䛾䛿䜲䜸 䞁ఏᑟయ䛸ゝ䛖䠊䛣䛾䛖䛱≉䛻㧗䛔䜲䜸䞁ఏᑟᛶ䜢♧䛩䜒 䛾䛿ᅛయ㟁ゎ㉁䛸䜀䜜䜛䠊ᅛయᏛ⪅䛻䛸䛳䛶䠈⮬ศ 䛾ὀ┠䛧䛶䛔䜛ᶵ⬟䜢Ⓨ䛩䜛ᅛయ㟁ゎ㉁䜢⮬⏤䛻タ ィ䛧ྜᡂ䛩䜛䛣䛸䛿䠈䛝䛺ክ䛷䛒䜚㢪ᮃ䛷䜒䛒䜛䠊䜒䛖䛛 䛺䜚๓䛻䛺䜛䛜᪥ᮏᏛ䛛䜙䇿ᶵ⬟ᛶ䝉䝷䝭䝑䜽䝇䛾タ ィ䇿䛸㢟䛩䜛ᮏ䛜ห⾜䛥䜜䛶䛔䜛䛾䜒䠈䛣䛾䛣䛸䜢຺䛧 䛯䜒䛾䛷䛒䜝䛖䠊䜲䜸䞁ఏᑟయ䛻㛵䛩䜛ㄽᩥ䜔◊✲Ⓨ⾲ 䛾ᩘ䛿㏆ᖺ䜒⾶䛘䜛䛣䛸䛿䛺䛟䠈୍㒊㠀ᖖ䛻䝬䝙䜰䝑䜽䛺 䜒䛾䜒䛒䜛䛜䠈䛭䛾ෆᐜ䜒ᇶ♏⌮ㄽ䛛䜙ᛂ⏝䜎䛷ከ✀ከ ᵝ䛸䛺䛳䛶䛚䜚䠈䛣䛾䜒䛾䛜䛔䛛䛻ᗈ䛔ศ㔝䛻䛚䛔䛶㛵 ᚰ䜢ᣢ䛯䜜⥆䛡䛶䛔䜛䛛䜢♧䛧䛶䛔䜛䠊䛥䛶㧗䛔䜲䜸䞁 ఏᑟᛶ䜢䜒䛴᪂つ䛺ᅛయ䛾䜲䜸䞁ఏᑟᛶ䜢ྜᡂ䛧䜘䛖䛸 䛩䜛䛸䛝䠈䛹䛾䜘䛖䛺䛣䛸䛻ὀ┠䛧䛯䜙䜘䛔䛾䛷䛒䜝䛖䛛䠊䛣 䜜䛻䛿䛣䜜䜎䛷䛾◊✲⤒⦋䛸䛭䛾ᡂᯝ䜢䛯䛹䛳䛶䜏䜛ᚲ せ䛜䛒䜛䠊㻌 㻌 䜲䜸䞁ఏᑟయ䛾ᮏ᱁ⓗ䛺◊✲䛿䠈㻝㻥㻢㻜ᖺ௦ึ䜑䛾Ᏻ ᐃ䝆䝹䝁䝙䜰⣔㓟≀䜲䜸䞁ఏᑟయ䛻ጞ䜎䜚䠈䛣䜜䛻 㖟䜲䜸䞁ఏᑟయ䠈䝘䝖䝸䜴䝮䜲䜸䞁ఏᑟయ䛾㛤Ⓨ䛺䛹䛜⥆ 䛔䛯䠊䛭䛧䛶䛺䛚ᑗ᮶䛾ᶵ⬟ᛶᮦᩱ䛸䛧䛶䛾ᮇᚅ䛛䜙䠈 䛯䛟䛥䜣䛾◊✲⪅䛻䜘䛳䛶◊✲㛤Ⓨ䛜㐍䜑䜙䜜䛶䛔䜛䠊 䛧䛛䛧䛺䛜䜙䠈ὀ┠䛩䜛ྜ≀୰䛷ពᅗ䛧䛯䜲䜸䞁䜢⮬ ⏤䛻ື䛛䛩䛣䛸䛜䛷䛝䜛䛛䛸ゝ䛖䛸䠈䛭䛖䛷䛺䛔ሙྜ䛜ከ 䛔䠊᪤䛻㏙䜉䛯䜘䛖䛻䛣䛾䜘䛖䛺䜲䜸䞁ఏᑟయ䛻㛵䛩䜛⥲ ㄝ㢮䛿䛣䜜䜎䛷䛻䜒ฟ䛥䜜䛶䛔䜛䛜䠈௨ୗ䛻䛿䜎䛪䠈㓟 ≀䛾ᑟ㟁యྜᡂ䛻㛵䛧䛶⚾⮬㌟䛜ὀ┠䛧䛶䛔䜛ヰ㢟 ⓗ㡯䛻䛴䛔䛶ᴫㄝ䛩䜛䠊㻌 㻌 ᪂䛧䛔ᑟ㟁య䛾タィ䛸䛔䛖ព䛷䛿䠈䜎䛪䃑㻙䜰䝹䝭䝘 㢮䛻䛿ὀ┠䛧䛺䛡䜜䜀䛺䜙䛺䛔㻔ᅗ㻝䠅䠊㻺㼍䃑㻙䜰䝹䝭䝘䛿 㻺㼍㻞㻻䡡㻝㻝㻭㼘㻞㻻㻟䛾୍⯡ᘧ䛷⾲䛥䜜䠈㓟⣲䛾ᐦሸ䛧䛯ᒙ ≧䝇䝢䝛䝹䝤䝻䝑䜽㻔䝇䝢䝛䝹୰䛾㻹㼓䛾⨨䛿䛩䜉䛶㻭㼘 䛷⨨䛝䛘䜙䜜䛶䛔䜛㻕䛾㛫䛻㻺㼍㻗䛜ᣳ䛳䛯ᵓ㐀䜢䛸䜚䠈䛣 䛾ᒙ㛫䜢㻺㼍㻗䛜⛣ື䛧䛖䜛䛾䛷㻺㼍㻗䛻䜘䜛㧗䛔ᑟ㟁ᛶ䛜⌧ 䜜䜛䠊䜎䛯㻺㼍䃑㻎㻙䜰䝹䝭䝘䛿᭦䛻䛭䛾㻭㼘䛾୍㒊䜢㻺㼕㻘㻌 㻹㼓 䛺䛹䛷⨨䛧䠈䛭䛾㟁Ⲵ⿵ൾ䛾䛯䜑㻺㼍䜢ከ䛟䛧䛯䜒䛾䛷䠈 ⤖ᬗᵓ㐀䛿䃑㻙䜰䝹䝭䝘䛸䛿ᑡ䛧␗䛺䜛䛜ᑟ㟁⋡䛿䛭䜜 䜘䜚᭦䛻㧗䛔䜒䛾䛸䛺䜛䠊䛣䛾ᛶ㉁䜢Ⓨᒎ䛥䛫䜛䜉䛟㻺㼍㻗䜢 ␗✀䛾䜹䝏䜸䞁䛷⨨䛧䛶䜔䜛䛸䠈䛭䛾䜲䜸䞁䛻䜘䜛ᑟ 㟁ᛶ䛜⌧䜜䜛䠊䛘䜀㻸㼕㻯㼘⼥ᾮ୰䛻ᾐₕ䛧䛯䜒䛾䛿㻸㼕㻗 ఏᑟయ䛸䛺䜚䠈㻮㼍㻔㻺㻻㻟㻕㻞㻛㻮㼍㻯㼘㻞ΰྜ⼥ᾮ୰䛻ᾐₕ䛧䛯䜒 䛾䛿㻮㼍㻞㻗ఏᑟయ䛸䛺䜛䠊᭱䜒䝴䝙䠉䜽䛺䜒䛾䛸䛧䛶䛿䠈ᕼ ᅵ㢮ඖ⣲㻔㻸㼚㻕䛾ሷ≀䛒䜛䛔䛿◪㓟ሷ⼥ᾮ䛻ᾐₕ䛧䛶 ᚓ䛯䃑㻎㻙䜰䝹䝭䝘䛷䛾㻸㼚㻟㻗ఏᑟᛶ䛷䛒䜛㻚䛧䛛䛧㟁Ⲵᩘ䛜 䛝䛔䛯䜑䛻࿘䜚䛛䜙䛾㟼㟁ᘬຊ䛾ຠᯝ䜢ཷ䛡䛶䠈䛾 ୍౯䜲䜸䞁䛚䜘䜃౯䜲䜸䞁䜢ྵ䜐䃑㻙䜰䝹䝭䝘㢮䜘䜚᱆ 㐪䛔䛻ప䛔ᑟ㟁⋡䛧䛛♧䛥䛺䛔㻔ᅗ㻞㻕䠊䛧䛛䛧䛣䛾䜘䛖䛻䜲 䜸䞁㐣⛬䜢వศ䛻⤒䜛䛸䛿䛔䛘䠈ྠ䛨ᵓ㐀䛾ྜ≀ 䛷౯ᩘ䛾␗䛺䜛ከ✀䛾䜲䜸䞁ఏᑟయ䛜ᚓ䜙䜜䜛䛣䛸䛿䠈 ⌧ᅾ䛷䜒䛺䛚䜲䜸䞁ఏᑟయ䛾タィ䛸䛔䛖㠃䛛䜙⪃䛘䜛䛸 㠀ᖖ䛻⯆῝䛔䜒䛾䛷䛒䜛䠊㻌 ᅗ1㻌 Naȕ- 䛚䜘䜃 Naȕ"-䜰䝹䝭䝘䛾⤖ᬗᵓ㐀 ᅗ2㻌 䜲䜸䞁䛥䜜䛯M-ȕ"-䜰䝹䝭䝘䛾ᑟ㟁⋡㻌 M = 1) Na, 2) Ba, 3) Gd.
㻌 ḟ䛺䜛ᅛయᏛ⪅䛾ู䛾ᮃ䜏䛿䠈䜘䜚㧗䛔䜲䜸䞁ఏᑟ ᗘ䜢♧䛩ᅛయ䜢ぢ䛔䛰䛩䛣䛸䛷䛒䜝䛖䠊䛟᪂䛧䛔䜒䛾䜢 ᪂䛧䛔ᡭἲ䛻䜘䜚ྜᡂ䛩䜛ሙྜ䛿ู䛸䛧䛶䠈㏻ᖖ䛿௨๓ 䛻᫂䜙䛛䛸䛺䛳䛶䛔䜛⤖ᬗᏛⓗ䛒䜛䛔䛿Ꮫⓗ䝕䠉䝍䜢 䜒䛸䛻䛧䛶᳨ウ䛧䛶䜖䛟䛣䛸䛜ከ䛔䠊䛭䛣䛷㻭㼓㻵䛾䜘䛖䛻㧗 ┦䛷㧗䛔㻭㼓㻗ఏᑟᛶ䛜䛒䜛ሙྜ䛻䛿䠈㻭㼓䜔㻵䜢䛾䜲 䜸䞁䛷⨨䛩䜛䛣䛸䛻䜘䜚㧗 ┦䛜Ᏻᐃ䛥䜜䠈ᖖ 䛷 䜒㧗䛔ᑟ㟁ᛶ䛜ᚓ䜙䜜䛯䠊䜎䛯㻯㼑㻻㻞䛾䜘䛖䛻⣧≀㉁䛷䛿 㻻㻞㻙ఏᑟᛶ䛜ప䛔ሙྜ䛻䛿㓟⣲䛾✵᱁ᏊⅬ䜢⏕ᡂ䛩䜛 䜘䛖䛻ᡂศ䜢ᅛ⁐䛥䛫䜛䛣䛸䛻䜘䜚ᑟ㟁⋡䜢ྥୖ䛥䛫䜛 䛣䛸䛜䛷䛝䛯䠊䛣䜜䜙௨እ䛻䜒ὀ┠䛩䜉䛝ᡭἲ䛜䛒䜛䠊㻌 㻌 ➨୍䛻䛿䠈㻸㼕㻗ఏᑟయ䛾㻸㼕㻵䛻⤯⦕య䛷䛒䜛㻭㼘 㻞㻻㻟䛾ᚤ⢊ ᮎ䜢ΰ䛬䛯䜘䛖䛺ΰྜ≀ᑟ㟁య䛷䠈⣧≀㉁䜘䜚䜒୍᱆௨ ୖ㧗䛔ᑟ㟁⋡䜢♧䛩䛣䛸䛜▱䜙䜜䛶䛔䜛䠊䛣䛾⌧㇟䛿䠈 㻸㼕㻵䛸㻭㼘㻞㻻㻟䛾⢏⏺䛷䛾ఏᑟ䛜㛵ಀ䛧䛶䛚䜚䠈┦㛫䛾✵ 㛫㟁Ⲵᒙ䛾⏕ᡂ䛜䜲䜸䞁ఏᑟ䛻㔜せ䛺ᙳ㡪䜢䛘䛶䛔 䜛䛸⪃䛘䜙䜜䛶䛔䜛䠊䛛䛳䛶㻹㻚㻺㼍㼓㼍㼕䜙䛿ከᏍ㉁䜰䝹䝭䝘 ୰䛷㻸㼕㻻㻴䛸㻺㻴㻠㻴㻞㻼㻻㻠䜢ᛂ䛥䛫䜛䛣䛸䛻䜘䜚㻸㼕㻟㻼㻻㻠䛸 㻭㼘㻞㻻㻟䛾」ྜ≀䜢ㄪ〇䛧䛯㼇㻝㼉䠊䛭䛾ᑟ㟁⋡䛿ຍᅽᡂᆺ≀ 䜘 䜚 ⣙ 䠍 ᱆ 㧗 䛔 䛸 䛧 䛶 䛔 䜛 䛜 䠈 㻠㻜㻜 䉝 䛷 䛾 ᑟ 㟁 ⋡ 䛿 㻝㻜㻙㻡㻿㼏㼙㻙㻝䛷䛒䜛䠊ㄪ〇ἲⓗ䛻䛿⯆῝䛔䛾䛷䠈ᚋ 䛾㧗䛔ఏᑟᛶ䛾㓟≀⣔ᅛ⁐య䛜ྠ䛨᪉ἲ䛷ྜᡂ䛷䛝 䜛䛣䛸䜢ᮇᚅ䛩䜛䜒䛾䛷䛒䜛䠊㻌 㻌 㻌 ➨䛻䛿䠈䜺䝷䝇䛒䜛䛔䛿䜰䝰䝹䝣䜯䝇䛩䜛䛣䛸䛻 䜘䜛ᑟ㟁⋡䛾ᨵၿ䛷䛒䜛䠊䛹䛾䜘䛖䛺䜲䜸䞁ఏᑟయ䛷䜒䜺 䝷䝇䛷䛝䜛ヂ䛷䛿䛺䛟䠈⌧ᅾ▱䜙䜜䛶䛔䜛䜒䛾䛿୍㒊䛾 䜰䝹䜹䝸㔠ᒓ䜲䜸䞁ఏᑟయ䛸㖟䛚䜘䜃䝣䝑≀䜲䜸䞁ఏ ᑟయ䛷䛒䜛䠊䛣䛾✀䛾◊✲䛿ẚ㍑ⓗከ䛟ሗ࿌䛥䜜䛶䛔䜛䠊 䛭䛾䜢ᣲ䛢䜜䜀䠈㻱㼤㼜㼘㼛㼟㼕㼛㼚㻌 ἲ䛸䜀䜜䜛ᾮయ❅⣲୰ 䜈䛾ᛴ෭༷ἲ䛻䜘䜚ㄪ〇䛥䜜䛯䜺䝷䝇䛜䛒䛳䛯㼇㻞㼉䠊䛣䛾ሙ ྜᑟ㟁ᛶ䛿㻠㻜㻜䉝䛾㧗 䛷䛿↝⤖య䜘䜚ⱝᖸ㧗䛟䛺䜛䛜䠈 ᐊ 䛷䛾ᑟ㟁⋡䛿㻝㻜㻙㻡㻿㼏㼙㻙㻝䛸↝⤖య䛻䛿ཬ䜀䛺䛔䠊䛧 䛛䛧䛣䛾᪉ἲ䛷ᚓ䜙䜜䛯䜺䝷䝇䛿䠈ṍ䜏䜔䜽䝷䝑䜽䛾䛺䛔 ┿⌫䛻㏆䛔䜒䛾䛷䛒䜛䛣䛸䛿⯆῝䛔䛣䛸䛷䛒䜛䠊㻌 㻌 䛣䜜䜙䛾䛣䛸䛛䜙⪃䛘䠈┦⏺㠃䛾≧ែ䜢ไᚚ䛩䜛䛣䛸䛿 䜲䜸䞁ఏᑟయ䛾ᑟ㟁⋡䜢ᨵၿ䛩䜛䛾䛻㔜せ䛺ᙺ┠䜢ᯝ 䛯䛧䛶䛔䜛䛸ゝ䛘䠈᭦䛻䛿ඛ䛻㏙䜉䛯㻯㼑㻻㻞䛻㓟⣲✵᱁ ᏊⅬ䜢⏕ᡂ䛥䛫ᑟ㟁⋡䜢ྥୖ䛥䛫䜛䛾䜒䠈✵᱁Ꮚ䛸䛔䛖 ୍✀䛾⏺㠃䛾ຠᯝ䜢䜏䛶䛔䜛䛸ゝ䛘䜛䛛䜒䛧䜜䛺䛔䠊䛧 䛯䛜䛳䛶䜎䛯ྛ䜲䜸䞁ఏᑟయ䛾ᑟ㟁⋡䛿䠈⪃䛘᪉䛻䜘䛳 䛶䛿⏺㠃䛾ᙳ㡪䛜᭱䜒䛝䛔䛭䛾⇇⼥య䛾್䛻㏆䛔䛸 䛣䜝䜎䛷䛿㧗䛟䛺䜛䛾䛷䛿䛺䛔䛛䛸⪃䛘䜙䜜䜛䠊㻌 㻌 ➹⪅䜙䛿䠈䛣䜜䜙䛸䛿ⱝᖸ␗䛺䜛䛜ప 䛷䜒㧗䛔㓟 ≀䜲䜸䞁ఏᑟᛶ䜢♧䛩ᮦᩱ䜢ᚓ䜛┠ⓗ䛷㓟≀⁐⼥ሷ 䝍䜲䝹䜢᳨ウ䛧䛯㼇㻟㻘㻠㼉䠊ከᏍ㉁㻹㼓㻻䜢䝬䝖䝸䝑䜽䝇䛸䛧䠈䛣䛾 㝽㛫䛻ప⼥Ⅼ䛾㓟≀䜢ධ䜜䛯䜒䛾䛷䛒䜛䠊㓟≀ᮦ ᩱ䛸䛧䛶䛿䠈⼥Ⅼ䜢ୗ䛢䜛䛯䜑䛻㻮㼕㻞㻻㻟䛻㻸㼕㻞㻻ΰྜ䛧䛯䜒 䛾䜢⏝䛧䛯䠊䛣䛾䜒䛾䛿䠈㻢㻜㻜䉝䛷㻝㻜㻙㻝㻿㼏㼙㻙㻝䜢㉺䛘䜛㧗 䛔ᑟ㟁ᛶ䜢♧䛧䠈䛭䛾ᑟ㟁✀䛻䛿⁐⼥ሷ䛷䛒䜛䛜ᨾ䛻 ⥲䛶䛾䜲䜸䞁䛜⪃䛘䜙䜜䛯䛜䠈㓟⣲䜺䝇⃰ῐ㟁ụ䛾ᨺ㟁 ⤖ᯝ䛛䜙䛿䜋䜌㓟≀䜲䜸䞁ఏᑟయ䛸䛧䛶ാ䛟䛣䛸䛜☜ ㄆ䛥䜜䛯䠊㻌 㻌 ௨ୖ䛾⤖ᯝ䛿ᑟ㟁ᛶ䜢ᨵⰋ䛩䜛䛯䜑䛻ᑟ㟁య⮬య䛾 ᵝᏊ䜢䛩䛳䛛䜚ኚ䛘䛶䛧䜎䛳䛯䜒䛾䛷䛒䜛䠊䛣䜜䛻ᑐ䛧ᑟ 㟁య䜢ᚓ䜛ㄪ〇ἲ䜢ᨵၿ䛩䜛䛣䛸䜒ヨ䜏䜙䜜䛶䛔䜛䠊㻌 㻌 䜎䛪㓟≀䜲䜸䞁ఏᑟᛶ䜢♧䛩Ᏻᐃ䝆䝹䝁䝙䜰⣔ 㓟≀䛻䛴䛔䛶䛾䝯䜹䝙䜹䝹䜰䝻䜲䞁䜾䛻䜘䜛ㄪ〇䛷䛒 䜛㼇㻡㼉䠊㔠ᒓ㛫ྜ≀䜔ྜ㔠䠈䛒䜛䛔䛿䜹䝹䝁䝀䞁≀䛻 ᑐ䛩䜛䛣䛾ㄪ〇ἲ䛿䜘䛟▱䜙䜜䛶䛔䜛䛜䠈㏻ᖖ㧗 䛷䛾 ↝ᡂ䛜ᚲせ䛸⪃䛘䜙䜜䜛㓟≀䛾ྠἲ䛻䜘䜛ྜᡂ䛾ሗ ࿌䛿⌋䛧䛔䠊䝇䝏䞊䝹〇䛾ᐜჾ䛻䜔䛿䜚䝇䝏䞊䝹䛾䝪䞊 䝹䛸䛭䜜䛮䜜䛾㓟≀⢊ᮎヨ⸆䜢ධ䜜䠈䛣䜜䜢ẖศᩘ ⓒᅇ㌿䛷㻞㻠㛫⮬බ㌿ᘧ䝪䞊䝹䝭䝹䛻䛛䛡䛯䠊䛭䛾⤖ ᯝ䠈䜹䝹䝅䜰䠈䝬䜾䝛䝅䜰䛚䜘䜃䜲䝑䝖䝸䜰Ᏻᐃ䝆䝹䝁 䝙䜰䛜䛷䛝䛯䛸䛔䛖䛾䛷䛒䜛䠊䜒䛱䜝䜣䛣䜜䜙䛾ሙྜ䝇䝏 䞊䝹䛾ᐜჾ䛸䝪䞊䝹䜢⏝䛧䛶䛔䜛䛾䛷㕲ᡂศ䛾ΰධ 䛿㑊䛡䜙䜜䛺䛔㻔ᅗ㻟㻕䠊䜎䛯䛣䛾⢊ᮎ䜢↝ᡂ䛧䛶䛹䛾䜘䛖䛺 ᑟ㟁ᛶ↝⤖య䛜ᚓ䜙䜜䜛䛾䛛䛻䛴䛔䛶䛿グ㏙䛜䛺䛔䠊㻌 㻌 ➹⪅䜙䛿䠈௨ୗ䛷䜒㏙䜉䜛㻮㼕㻞㻻㻟䜢ẕయ䛸䛧䛯㓟≀䜲 䜸䞁ఏᑟయ䜢ጞ䜑㻼㼎㻝㻙㼤㻸㼍㼤㼃㻻㻠㻗㼤㻛㻞⣔䜔㻸㼍㻞㻛㻟㻙㼤㻸㼕㼤㼀㼕㻻㻟⣔ 㓟≀⢊ᮎ䛾䝯䜹䝙䜹䝹䜰䝻䜲䞁䜾䛻䜘䜛ྜᡂἲ䜢᳨ウ 䛧䠈䛭䛾ᅛ⁐య⏕ᡂ䛸Ḟ㝗ᑟධ䛾㛵ಀ䛻䛴䛔䛶ヲ䛧䛟ゎ ᯒ䛧䠈↝ᡂἲ䛷ᚓ䛯ሙྜ䛸䛿␗䛺䜛Ḟ㝗⏕ᡂ䜢᫂䜙䛛䛻 䛧䛯㼇㻢㻙㻥㼉䠊䛣䜜䛿䛭䛾ᮦᩱ䛾྾╔⌧㇟䜔ⓎⰍᣲື䜢⏕䛛 䛩ሙྜ䛿䛔䛔䛸䛧䛶䜒䠈௨ୗ䛻㏙䜉䜛㧗 㟁ụᮦᩱ䛻 ᛂ⏝䛥䜜䜛䝉䝷䝭䝑䜽䝇䜢ᚓ䜘䛖䛸䛩䜛ሙྜ䛿䜔䛿䜚᭱ᚋ 䛻↝⤖䛸䛔䛖䝥䝻䝉䝇䜢⤒䛽䜀䛺䜙䛪䠈ከᑡ䛾↝⤖ ᗘ ᅗ3㻌 ྛ✀Ᏻᐃ䝆䝹䝁䝙䜰䛾X⥺ᅇᢡᅗ㻌 1) 20% CaO 2) 20% MgO 3) 10% Y2O3
䛾పୗ䜢䜒䛯䜙䛩䛸䛔䛖Ⅼ䛜䛒䜛䛸䛿䛔䛘䠈ၥ㢟䛜䛺䛔 䛸䛿ゝ䛘䛺䛔䛸⪃䛘䜙䜜䛯䠊㻌 㻌 䛣䛾䜘䛖䛺㓟≀䜲䜸䞁ఏᑟᛶ䜢♧䛩䜒䛾䛻䛿䠈Ᏻᐃ 䝆䝹䝁䝙䜰䛰䛡䛷䛿䛺䛟㢮ఝ䛾Ḟᦆ⺯▼ᆺᵓ㐀䛾㓟 ≀䜢䛿䛨䜑䝨䝻䝤䝇䜹䜲䝖ᆺ㓟≀䠈䝟䜲䝻䜽䝻䜰䠉ᆺ 㓟≀䛜䛒䜛䛜䠈᭱䜒㧗䛔ᑟ㟁⋡䜢♧䛩䜒䛾䛸䛧䛶䛿๓ 䛷ᑡ䛧㏙䜉䛯㻮㼕㻞㻻㻟䜢ẕయ䛸䛧䛯䜒䛾䜒䛒䜛䠊䛧䛛䛧➨୕ ୡ௦䛾⇞ᩱ㟁ụ⏝䛾ᅛయ㟁ゎ㉁䛸䛧䛶᭷ᮃど䛥䜜䛶䛔 䜛Ᏻᐃ䝆䝹䝁䝙䜰⣔㟁ゎ㉁䛜᭱䜒ከ䛟◊✲䛥䜜䛶䛔䜛䠊 䛭䛾ෆᐜ䛿ḟ❶䛷㏙䜉䜛⇞ᩱ㟁ụ㟁ゎ㉁䜈䛾ᮇᚅ䛛䜙 ⷧ⭷䛾᳨ウ䛜ከ䛔䠊䛭䛾䜢ᣠ䛔䛒䛢䛶䜏䜛䛸䠈☜䛛 䛻ᄇ㟝⇕ศゎἲ㼇㻝㻜㼉䠈㼂㻱㻰㼇㻝㻝㼉㻘㻌㻯㼂㻰㼇㻝㻞㼉䠈䝥䝷䝈䝬㻯㼂㻰㼇㻝㻟㼉䛒 䜛䛔䛿䝺䞊䝄䞊㻯㼂㻰ἲ㼇㻝㻠㼉䛷䜲䝑䝖䝸䜰Ᏻᐃ䝆䝹䝁䝙䜰 㻔㼅㻿㼆㻕ⷧ⭷䜢స〇䛧䛯䜒䛾䛷䛿䛒䜛䛜䠈䛣䜜䜢䛳䛶ᵓᡂ 䛧䛯⇞ᩱ㟁ụ䛾≉ᛶ䜢᳨ウ䛧䛯䜒䛾䛷䛿䛺䛔䜘䛖䛷䠈 䛻⭷⏕ᡂᶵᵓ䜔⏕ᡂ⭷≧ែ䜢ホ౯䛩䜛䜒䛾䛷䛒䛳䛯䠊㻌 㻌 䜎䛯䛭䛾ᚋ䠈䜘䜚ప 䛷䛾⇞ᩱ㟁ụ✌ാ䜢⪃䛘䛶䠈 㼆㼞㻻㻞⣔䛾䜒䛾䜘䜚㧗䛔ᑟ㟁⋡䜢♧䛩㻯㼑㻻㻞⣔䛾㓟≀䜲 䜸䞁ఏᑟయ䛻䛴䛔䛶䜃᳨ウ䛥䜜䜛䜘䛖䛻䛺䛳䛶䛝䛯䠊䛣 䜜䛿⇕ຊᏛⓗ䛻䛿Ᏻᐃ䝆䝹䝁䝙䜰䜋䛹Ᏻᐃ䛷䛺䛟䠈ᗄ ศ㟁Ꮚ㍺⋡䜒䛝䛔䠊ᚑ䛳䛶㟁ụ䜢ᵓᡂ䛧䛯䛸䛝㟁Ꮚఏ ᑟᛶ䛾ศ䛰䛡㟁ゎ㉁ෆ㒊䛷▷⤡㟁ὶ䛜ὶ䜜䜛䛯䜑䠈 㻢㻜㻜䉝䡚㻣㻜㻜䉝䛷䛿➃Ꮚ㟁ᅽ䛜⌮ㄽ್䛸ẚ㍑䛧䛶㻜㻚㻟䡚 㻜㻚㻠㼂䜒పୗ䛧䛶䛧䜎䛖䠊䛣䛾䜘䛖䛺ᛶ㉁䛿䠈Ᏻᐃ䛺㓟≀ 䜢㟁ゎ㉁⮬య䛾ᛶ㉁䜢↓䛟䛥䛺䛔⛬ᗘ䛻ⷧ䛟⾲㠃䛻䝁䠉 䝔䜱䞁䜾䛩䜛䛣䛸䛻䜘䛳䛶ඞ᭹䛥䜜䜛䠊㻯㼑㻻㻞⣔ᅛయ㟁ゎ ㉁䛻㼅㻿㼆䜢䝇䝟䝑䝍䝸䞁䜾䝁䠉䝔䜱䞁䜾䛩䜛䛸➃Ꮚ㟁ᅽ䛿 ୖ᪼䛧䠈ᨺ㟁≉ᛶ䜒㻯㼑㻻㻞⣔⮬య䛾ᛶ⬟䜢ᦆ䛺䜟䛺䛔䛸 ゝ䛖㼇㻝㻡㼉䠊䛭䛾ᚋ䜒䛣䜜䜢┠ᣦ䛧䛯᳨ウ䛜䛺䛥䜜䛶䛔䜛㼇㻝㻢㻘㻝㻣㼉䠊 ≉䛻㻯㻚㻯㻚㻯㼔㼑㼚䜙䛿䝉䝸䜴䝮䛸䝃䝬䝸䜴䝮䛾◪㓟ሷ䛸䜶䝏䝺 䞁䜾䝸䝁䞊䝹䛛䜙ྜᡂ䛧䛯㧗ศᏊ๓㥑య䜢䝇䝢䞁䝁䞊䝔䜱 䞁 䜾 䛧 䛯 ᚋ 䠈 㻟㻞㻜 䉝 䛷 ⇱ 䛩 䜛 䛰 䛡 䛷 ⦓ ᐦ 䛷 ᆒ ୍ 䛺 㻯㼑㻜㻚㻤㻿㼙㻜㻚㻞㻻㻝㻚㻥䛾ⷧ⭷䛜ᚓ䜙䜜䜛䛸ሗ࿌䛧䛯㼇㻝㻢㼉䠊䛣䛾⭷䛿 㻝㻞㻜㻜䉝䜎䛷㼅㻿㼆䜔㻸㼍㻜㻚㻤㻿㼞㻜㻚㻞㻹㼚㻻㻟㻙䃓䛸䜒䛟ᛂ䛧䛺䛔䛸 䛔䛖䛜䠈ḟ⠇䛷㏙䜉䜛⇞ᩱ㟁ụ䛻ᮏᙜ䛻ᛂ⏝䛷䛝䜛䛛䛹 䛖䛛䛿᭦䛻᳨ウ䛜ᚲせ䛷䛒䜝䛖䠊㻌 㻌 㸲㸬 ⇞ᩱ㟁ụࡢཎ⌮≉ᚩ 㻌 㻌 ㏆ᖺ䜶䝁䝻䝆䞊䛸䛔䛖ゝⴥ䛜┒䜣䛻䜟䜜䜛䜘䛖䛻䛺䛳 䛶䛝䛯䠊䛣䛾ゝⴥ䛿䛭䜣䛺䛻᪂䛧䛔䜒䛾䛷䛿䛺䛔䠊➹⪅ 䛿 䠈 ㄡ 䛾 ⴭ స 䛛 䛿 ᛀ 䜜 䛶 䛧 䜎 䛳 䛯 䛜 㻝㻥㻣㻜 ᖺ ௦ 䛻 㻱㼏㼛㼘㼛㼓㼕㼏㼍㼘㻌 㻱㼘㼑㼏㼠㼞㼛㼏㼔㼑㼙㼕㼟㼠㼞㼥㻌 䛸ྡ䛡䜙䜜䛯ᮏ䜢◊✲ᐊ 䛾㍯ㅮ䛷ㄞ䜣䛰ぬ䛘䛜䛒䜛䠊䜒䛱䜝䜣䛭䛾୰䛻⇞ᩱ㟁ụ 䛾ㄝ᫂䛜䛒䛳䛯䠊ᙜ䛿䛭䛖䜔䛳䛶㟁Ẽ䜢㐀䜜䜀⎔ቃ䛻 ඃ䛧䛔䛾䛛䛸ᛮ䛳䛯䜒䛾䛷䛒䜛䠊㻌 㻌 䛥䛶䠈⇞ᩱ㟁ụ䛷䛒䜛䠊ඛ䛻᭩䛔䛯䜘䛖䛻䠈䛣䛾䜒䛾䜒᪂ 䛧䛔ᴫᛕ䛷䛿䛺䛔䠊㻝㻥㻣㻜ᖺ௦ึ㢌䛻䛿᪤䛻➹⪅䛾ᜠᖌ 䛷䛒䜛ྡྂᒇᏛྡᩍᤵ䛾ᨾ㧗ᶫṊᙪẶ䛻䜘䜛ゎㄝ 䜔⥲ㄝ䜒ከ䛟䜏䜙䜜䛯䠊䝆䜵䝭䝙䜔䜰䝫䝻䛾Ᏹᐂ⯪䛻㍕ 䛫䜙䜜䠈䛭䛾㟁※⨨䛸䛧䛶ാ䛔䛯䛛䜙䜒᭷ྡ䛻䛺䛳 䛯䛜䠈⚾䛾┠䛻䛿୍䛭䛾◊✲䛿ୗⅆ䛻䛺䛳䛶䛝䛯䜘䛖 䛻䜏䛘䛯䠊䛧䛛䛧䠈䛣䛾ᮇ䛷䜒ᙜヱ䝅䝇䝔䝮䛻⏝ྍ ⬟䛺䠈௨ୗ䛻㏙䜉䜛ᅛయ㟁ゎ㉁䛻㛵䛩䜛◊✲䛿⢭ຊⓗ 䛻⥆䛡䜙䜜䛯䠊㻌 㻌 ᅛయ㟁ゎ㉁䜢䛖䠈䜟䛺䛔䛻ᣊ䜟䜙䛪䠈⇞ᩱ㟁ụ䛻 䛿㈇ᴟ䠄㑏ඖ䠅䛸ṇᴟ䠄㓟䠅䛸䜢ศ㞳䛩䜛䛸ྠ 䛻䜲䜸䞁䛾䜏䛾㍺㏦䜢ྍ⬟䛸䛩䜛㝸⭷䛜ᚲせ䛸䛺䜛䠊 䛛䛟䛧䛶㟁ụᵓᡂ䛿䠈䛂㈇ᴟ㻘㻌㻼㼠㻌㻛㻌 䜲䜸䞁ఏᑟయ㻌 㻛㻌㻼㼠㻘㻌 ṇᴟ䛃䛸䛺䜛䠊㻼㼠䛿ⓑ㔠䛷㟁Ẽ䜢ྲྀ䜚ฟ䛩䛯䜑䛾௬䛻 ⪃䛘䛯㟁ᴟᮦ䛷䛒䜛䠊䛣䜜䛿Ᏻᐃ䛺ᮦᩱ䛷䛒䜜䜀㻼㼠䛻 㝈ᐃ䛥䜜䛺䛔䠊ṇᴟ䛸㈇ᴟ䛾௦⾲䛿Ỉ⣲䜺䝇䛸㓟 ⣲䜺䝇䛷䛒䜛䠊䜲䜸䞁ఏᑟయ䛸䛧䛶䛿㓟䜔䜰䝹䜹䝸Ỉ⁐ᾮ䠈 ⁐⼥Ⅳ㓟ሷ䠈᭦䛻ඛ䛻㏙䜉䛯ᅛయ㟁ゎ㉁䛜䛒䜛䠊䛘 䜀䛂䠉㻌 Ỉ⣲㻘㻌 㻼㼠㻌 㻛㻌 㓟ᛶỈ⁐ᾮ㻌 㻛㻌 㻼㼠㻘㻌 㓟⣲㻌 䠇䛃䛷ᵓᡂ 䛥䜜䜛㟁ụ䛷䛿䠈Ỉ⣲䛸㓟⣲䛾ᛂ䛷䛾⮬⏤䜶䝛䝹䜼 䞊ኚศ䛜┤᥋㟁Ẽ䜶䝛䝹䜼䞊䛻ኚ䛥䜜䜛䠊䛭䛾⤖ ᯝ䠈ᅗ㻠䛻♧䛩䜘䛖䛻ᚑ᮶䛾ⅆຊⓎ㟁䜘䜚ຠ⋡䛜㧗䛔䛸䛥 䜜䛶䛔䜛䠊䛯䛰䛧ᅗ㻡䛻♧䛧䛯䜘䛖䛻䠈㟁ụ䝉䝹䜔䝇䝍䝑䜽 䛿༢⣧䛺ᵓᡂ䛷䛿䛺䛟䠈ᐊ ㏆䛟䛷ᛂ䜢䛖䜎䛟⾜䜟䛫䜛 䛯䜑䛻ᐇ㝿䛻㟁ᴟ䛻䛚䛔䛶䛿㧗౯䛺ⓑ㔠䜢⏝䛧䛺䛡 䜜䜀䛺䜙䛺䛔䠊㻌 㻌 䛭䛣䛷➨୕ୡ௦䛾⇞ᩱ㟁ụ䛸䜀䜜⬮ග䜢ᾎ䜃䛶䛝 䛯䛾䛜㧗 ᆺᅛయ㟁ゎ㉁⇞ᩱ㟁ụ䛷䛒䜛䠊㧗 䛷సື 䛩䜛䛣䛸䛷㧗౯䛺ⓑ㔠⣔䛾㟁ᴟᮦ䠄ゐ፹䠅䛿せ䜙䛪䠈㓟 ≀⣔䛾䜒䛾䛻⨨䛝䛘䜛䛜ྍ⬟䛷䛒䜛䠊⇞ᩱ㟁ụ䛾 㟁ゎ㉁䛻⏝䛷䛝䜛䜒䛾䛻䛿䠈䜘䛟▱䜙䜜䛯㓟≀䜲䜸 䞁䠄㻻㻞㻙䠅䛜ື䛟䜒䛾䛸ḟ⠇䛷㏙䜉䜛Ỉ⣲䜲䜸䞁䠄㻴㻗䠖䝥䝻䝖 䞁㻕䛾ື䛟䜒䛾䛜䛒䜛䠊๓⪅䛷䛿⺯▼ᆺ䛾⤖ᬗᵓ㐀䜢ᣢ 䛴Ᏻᐃ䝆䝹䝁䝙䜰⣔䜔䝨䝻䝤䝇䜹䜲䝖⣔䛾㟁ゎ㉁䛜䠈 ᚋ⪅䛷䛿䜔䛿䜚ඛ䛻㏙䜉䛯䝨䝻䝤䝇䜹䜲䝖⣔䛾㟁ゎ㉁䛜 ᭷ྡ䛷䛒䜛䠊䛣䜜䜙䛾䜒䛾䜢⏝䛔䛯ሙྜ䛾≉ᛶ䛾㐪䛔䜢 ᅗ㻢䛻♧䛧䛯䠊ඹ䛻䛂䠉㻌 Ỉ⣲㻌 㻛㻌 ᅛయ㟁ゎ㉁䠄䜲䜸䞁ఏᑟ య䠅㻌 㻛㻌 㓟⣲㻌 䠇䛃䛷ᵓᡂ䛥䜜䜛䛸䠈Ỉ⣲䛜㓟⣲䛷㓟 䛥䜜䜛ᛂ䛜⏕䛨䜛䛣䛸䛻㐪䛔䛺䛔䠊䛧䛛䛧䠈⏕ᡂ䛧䛯Ỉ ᅗ4㻌 Ⓨ㟁᪉ἲ䛸䜶䝛䝹䜼䞊⏝ຠ⋡䛾ẚ㍑
Ẽ䛾Ⓨ⏕䛩䜛ሙᡤ䛜䠈Ỉ⣲ഃ䛛㓟⣲ഃ䛛䛾㐪䛔䛜ฟ 䜛䠊ᡃ⏣ᘬỈ䛷ゝ䛘䜀➹⪅䜙䛜ᙜึᥦ䛧䛯䝥䝻䝖䞁䛾 ື䛟䜒䛾䛜⌮ⓗ䛷䛒䜝䛖䠊䛺䛬䛺䜙⇞ᩱ䜺䝇୰䛻⏕ᡂ䛧 䛯ỈẼ䛜ฟ䛪䠈䛣䜜䜢ศ㞳䛩䜛ᚲせ䛜↓䛔䛛䜙䛷䛒䜛䠊 䛯䛰䛧䠈Ỉ⣲௨እ䛾䠄Ỉ⣲䜢ྵ䜎䛺䛔䠅⇞ᩱ䜢┤᥋⏝ 䛷䛝䛺䛔䛣䛸䛿ྰ䜑䛺䛔䠊䛧䛯䛜䛳䛶⌧ᅾ䠈㧗 ᆺ⇞ᩱ 㟁ụ䛸䛧䛶ᴗ䛷ᐇ⏝䛥䜜䜘䛖䛸䛧䛶䛔䜛䛾䛿Ᏻᐃ 䝆䝹䝁䝙䜰䜢⏝䛔䛯䜒䛾䛷䛒䜛䠊㻌 㻌 䛣䛾ሙྜ㔜せ䛺㡯䛜㻝䛴䛒䜛䠊ᅗ㻠䛻䜒ᅗ㻢䛻䜒♧䛧䛯 䝉䝹㻝䛴䛾ฟ䛧䛖䜛㟁ᅽ䛿䛫䛔䛬䛔㻝㻚㻞㼂䛺䛾䛷䛒䜛䠊䜲䞁 䝞䞊䝍䞊䜔䝁䞁䝞䞊䝍䞊䜢䛖䛻䛧䛶䜒䛣䜜䛷䛿ヰ䛻䛺䜙 䛪䠈䛣䜜䜙䜢┤ิ䛸୪ิ㓄ิ䛧䛶᪼ᅽ䛩䜛䛸ඹ䛻ྲྀ䜚ฟ䛧 䛖䜛㟁ὶ䜢ቑ䜔䛩ᚲせ䛜䛒䜛㻔ᅗ䠓㻕䠊㟁ᴟᮦ䛻䛿Ᏻ౯䛺 䜒䛾䛜⏝䛷䛝䛖䜛䛜䠈䛣䜜䜙䛾㓄ิ䛻䛿┦ᙜ䛺ᢏ⾡䜢 せ䛩䜛䛣䛸䛻䛺䜛䠊㻌 㻌 䛥䛶ḟ䛻䛣䜜䜙䛾⇞ᩱ㟁ụ䛾ᐇ㝿䛾ຠ⋡䛻䛴䛔䛶⪃䛘 䛶䜏䜛䛣䛸䛸䛩䜛䠊ᮏ✏䛿㧗 ᆺᅛయ⇞ᩱ㟁ụ䛾䜢㏙ 䜉䛶䛔䜛䛾䛷䠈䛣䜜䛷ㄝ᫂䛷䛝䜜䜀䛔䛔䛾䛷䛒䜛䛜䠈ዴ ఱ䛫䜣ᕷ㈍䛾⨨䛜↓䛟ヲ䛧䛔ィ⟬䛜䛷䛝䛺䛔䠊䛭䛣䛷 䛣䛣䛷䛿䠈ᐙᗞ⏝⇞ᩱ㟁ụ䛸䛧䛶ᕷ㈍䛥䜜䛶䛔䜛⨨䛾 ᵝ䛷᳨ウ䛩䜛䛣䛸䛧䛯䠊⾲㻝䛻䛭䛾୍⯡ⓗ䛺ᵝ䜢♧ 䛧䛯䠊䛣䜜䛿ᙜヱ⨨䛾䝟䞁䝣䝺䝑䝖䛛䜙ᘬ⏝䛧䛯䜒䛾䛷 䛒䜛䠊ᐙᗞ⏝䛺䛾䛷䠈ẚ㍑䛾ᑐ㇟䛿⮬Ꮿ䛸䛧䛯䠊䛣䛾ሙ ྜ䠈᭶ᖹᆒ䜶䝛䝹䜼䞊ᾘ㈝䛿䠈㟁Ẽ㻟㻜㻜㼗㼃㼔㻘㻌 㻸㻼㻳㻝㻜❧ ᪉䝯䞊䝖䝹䛷䛒䜛䠊㻌 㻌 䜎䛪䜺䝇䛻䛴䛔䛶⪃䛘䜛䠊㻝㻜❧᪉䟑䛿㻝㻜㻜㻜㻜㻸䛷䛒䜛䠊 㻸㻼㻳䜢㻯㻟㻴㻤㻔ศᏊ㔞䛿㻠㻠㻕䛸䛧䛶䠈䛣䛾㻝㻜❧᪉䟑䛿㻌 㻌 㻌 㻯㻟㻴㻤㻌 㻙㻙㻙㻙㻪㻌㻠㻌㻴㻞㻻㻌㻗㻌㻟㻌㻯㻻㻞㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻝㻕㻌 㻌 䛺䛾䛷䠈㻌 㻌 㻌 㻌 㻌 㻟㻌㼤㻌㻠㻠㻌㼤㻌㻝㻜㻜㻜㻜㻌㻛㻌㻞㻞㻚㻠㻌㻩㻌㻡㻤㻥㻜㻜㻌㼓㻌 䛴䜎䜚㻡㻤㻚㻥㻌㼗㼓䛾Ⅳ㓟䜺䝇䜢ฟ䛩䠊ḟ䛻ၟ⏝㟁ຊ䛷䛿䠈㟁 ຊ䛾Ⅳ㓟䜺䝇ಀᩘ㻌 㻜㻚㻟㻤䠄㻝㼗㼃㼔䛾㟁ຊ䛜㻜㻚㻟㻤㻌 㼗㼓䛾Ⅳ㓟 䜺䝇䜢ฟ䛩㻕䛸䛩䜛䛸㻌 㻌 㻌 㻌 㻌 㻌 㻟㻜㻜㻌㼤㻌㻜㻚㻟㻤㻌㻩㻌㻝㻝㻠㻌㼗㼓㻌 䛷䛒䜛䠊䜺䝇䛸ే䛫䛶㻔䛣䜜䛜⥲䛶䛷䛒䜛䛜㻕ẖ᭶㻝㻣㻟㼗㼓⛬ ᗘ䛾Ⅳ㓟䜺䝇䜢ฟ䛧䛶䛔䜛䛣䛸䛻䛺䜛䠊㻌 㻌 ḟ䛻ᐙᗞ⏝⇞ᩱ㟁ụ䛷䛒䜛䠊⾲䛛䜙㻝㻜㻜㻑ฟຊ䛷⪃䛘䜛 䛸䠈㻣㻡㻜㼃䛻㻸㻼㻳䜢㻜㻚㻝㻜❧᪉䟑㻛㼔ᾘ㈝䛩䜛䠊ୖグ䛾㻟㻜㻜㻌 㼗㼃㼔䛷䛿㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻟㻜㻜㻌㻛㻌㻜㻚㻣㻡㻌㼤㻌㻜㻚㻝㻌㻩㻌㻠㻜❧᪉䟑㻌 㻌 䛾㻸㻼㻳䜢䛖䛣䛸䛻䛺䜛䠊䛣䛾䛸䛝䠈ୖ䛸ྠ䛨䜘䛖䛻⪃䛘䜛䛸㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻟㻌㼤㻌㻠㻠㻌㼤㻌㻠㻜㻌㼤㻌㻝㻜㻜㻜㻌㻛㻌㻞㻞㻚㻠㻌㻩㻌㻞㻟㻢㻜㻜㻜㻌㼓㻌 ᅗ5㻌 ⇞ᩱ㟁ụ䝉䝹䠈䝇䝍䝑䜽䛚䜘䜃㟁ᴟෆ 㒊䛾ᶍᘧᅗ ᅗ6㻌 㓟≀䜲䜸䞁䛸䝥䝻䝖䞁ఏᑟయ䜢䛳 䛯⇞ᩱ㟁ụ䛾ẚ㍑
䛴䜎䜚᭱ప㝈䛷㻞㻟㻢㻌 㼗㼓䛾Ⅳ㓟䜺䝇䛜ฟ䜛䠊䛣䜜䛷୍⯡䛾 㢼࿅䜔䝅䝱䝽䞊䛾せồ䛻䛿ᛂ䛘䜙䜜䜛䛸䛧䛶䜒䠈㢼࿅䛾 ㏣䛔⅕䛝䠈ㄪ⌮䛻䜺䝇䜢䛘䜀䜒䛳䛸ከ䛟䛾Ⅳ㓟䜺䝇䜢 ฟ䛩䠊Ⓨ㟁䛧䛯㟁Ẽ䛷䛭䜜䜢㈥䛘䜀䠈⏝㟁ຊ䛜ቑ䛘䠈 䜔䛿䜚㻌 䜒䛳䛸ከ䛟䛾Ⅳ㓟䜺䝇䜢ฟ䛩䠊᭦䛻ຍ䛘䛶䛣䛾ሙ ྜ䠈ึᮇᢞ㈨䛻㻟㻜㻜௨ୖ䛛䜛䠊⿵ຓ㔠䛜䛒䜛䛛䜙 Ⰻ䛔䛸ゝ䛖䜒䛾䛜䛔䜛䛜䠈䛣䛾䜒䛾䜢㐀䛳䛯䛻ึᮇᢞ㈨ 䛻ᑐᛂ䛧䛯ィ⟬䜒䛷䛝䛺䛔Ⳙ䛺㔞䛾Ⅳ㓟䜺䝇䜢ฟ䛧䛯 䛣䛸䛻䛿ఱ䜒ゝ䜟䛺䛔䜀䛛䜚䛛䠈䛭䛾ᚋ䛾⏝䛾ຠ⋡ 䛷⪃䛘䛶䜒䛣䛾〇㐀䛾䜶䝛䝹䜼䞊䜢ᅇฟ᮶䛺䛔䛣䛸 䜒䛟Ẽ䛵䛔䛶䛔䛺䛔䛿ၥ㢟䛷䛒䜝䛖䠊㻌 㻌 䛥䜙䛻ᅗ㻠䛾୰䛻䜒ၥ㢟䛜㞃䛥䜜䛶䛔䜛䠊㻝䛴䛿䠈ⅆຊ Ⓨ㟁䛿⇕䜶䝛䝹䜼䞊䛜ຠ⋡ⓗ䛻⏝䛥䜜䛪䠈䛭䜜⮬య 䛾ຠ⋡䛜ప䛔䛸䛥䜜䛶䛔䜛䛣䛸䛷䛒䜛䠊㻞䛴┠䛿⇞ᩱ㟁ụ 䛷䛿䝁䝆䜵䝛䝺䞊䝅䝵䞁䛸ゝ䛳䛶ᗫ⇕䜢༑ศά⏝䛧䛶䛔䜛 䛾䛻䠈㏻ᖖ䛾ⅆຊⓎ㟁䛷䛿䛣䛾⇕䜶䝛䝹䜼䞊䛜ຠ⋡ⓗ 䛻⏝䛥䜜䛺䛔䛣䛸䛷䛒䜛䠊䛧䛛䛧ᐇ㝿䛻䛿䠈ᮾ㟁䛾䜺䝇 䝍䞊䝡䞁䛸Ẽ䝍䞊䝡䞁䜢⤌䜏ྜ䜟䛫䛯᭱᪂䛾䝁䞁䝞䜲 䞁䝗䝃䜲䜽䝹Ⓨ㟁䛾ᐇ⦼䛷䛿㻡㻜㻑䛿㐭䛛䛻㉸䛘䛯ຠ⋡䜢 ♧䛧䛶䛔䜛䛧䠈䜲䜼䝸䝇䛷䛿䝻䞁䝗䞁ᕷෆ䛻㐀䛳䛯ᑠᆺⅆ ຊⓎ㟁ᡤ䛷༑ศᗫ⇕⏝䛧䛯ᐇ⦼䛜䠈㻝㻥㻜㻜ᖺ௦ึ䜑䛛 䜙䛒䜛䠊๓⪅䛿⪏⇕ᮦᩱ䛾Ⓨ㐩䛜䛭䛖䛥䛫䛯䜟䛡䛷䛒䜚䠈 ㏆䛔ᑗ᮶㻝㻢㻜㻜䉝䛷✌ാ䛷䛝䜜䜀ຠ⋡䛿⌮ㄽୖ㻤㻜㻑䜢㉺ 䛘䛶䛧䜎䛖䜒䛒䜚䛖䜛䠊䛣䛖䛺䜛䛸⇞ᩱ㟁ụ䛾ព⩏䜢ᮏᙜ 䛻ぢᴟ䜑䜛ᚲせ䛻㏕䜙䜜䛶䛟䜛䠊ᗫ⇕䜢ྵ䜑䛯⇕䜶䝛䝹 䜼䞊䜢ຠ⋡ⓗ䛻⏝䛩䜜䜀䠈䛯䛰▼Ἔ䜢⇞䜔䛩䛰䛡䛷 䜋䛸䜣䛹㻝㻜㻜㻑㏆䛔ຠ⋡䛷㟁Ẽ䛜ᚓ䜙䜜䜛䛺䜣䛶䠈䛣䜣䛺 䛩䜀䜙䛧䛔䛣䛸䛿䛺䛔䛛䜙䛷䛒䜛䠊㻌 㻌 䛣䛣䛷㛫㐪䛘䛶䛿䛔䛡䛺䛔䛾䛿䠈⇞ᩱ㟁ụ䜢ྰᐃ䛧䛶 䛔䜛ヂ䛷䛿䛺䛔䛣䛸䛷䛒䜛䠊ᢏ⾡䛾Ⓨ㐩䜔㠉᪂䛛䜙ゝ䛘 䜀䠈⇞ᩱ㟁ụᢏ⾡䛿㔜せ䛷䛒䜛䛧䠈⏝䛥䜜䜛ሙ㠃䜢⪃ 䛘䜜䜀᭦䛻䛭䛾㔜せ䛥䛿ቑ䛩䠊䛧䛛䛧䠈䛒䜛ே䛜䛣䜜䛿 䛔䛔䜣䛰䛸ゝ䛖䛸䛩䛠䛻䛭䜜䜢༢⣧䛻ಙ䛨䛶䠈䛔䛔䜣䛰 䛔䛔䜣䛰䛸㏄ྜ䛩䜛᪥ᮏே䠄⛉Ꮫ⪅䠅䛾㢼₻䛻䛿ὀព䛜 ᚲせ䛷䛒䜛䛸ゝ䛘䜛䠊䛧䛛䜛䜉䛝䝕䞊䝍䛻ᇶ䛵䛝ุ᩿䜢 ୗ䛩ᚲせ䛜䛒䜝䛖䠊㻌 㻌 㸳㸬 ᒾཎ◊✲ᐊᙜࡢ࢜ࣥఏᑟయ◊✲ 㻌 㻌 䛣䜜䜎䛷䛿ྜᡂἲ䜢ᛕ㢌䛻䛚䛝䠈䜲䜸䞁ఏᑟయ䛾タィ 䛸䛧䛶᭱㏆䛾䝖䝢䝑䜽䝇䜢㏙䜉䛶䛝䛯䛜䠈➹⪅䛜ୖグ䛾䛣 䛸䛻ὀ┠䛩䜛௨๓䠈䛴䜎䜚㻝㻥㻣㻤ᖺ䛾ᒾཎᩍᤵ䛾㉱௵ᙜ 䠈᪂䛧䛔◊✲䝔䞊䝬䛸䛧䛶ྲྀ䜚ୖ䛢䜙䜜䛯䜒䛾䛻䠈㧗 ᆺ䝥䝻䝖䞁ఏᑟయ䛾㛤Ⓨ䛜䛒䛳䛯䠊䛣䜜䛿䠈⇞ᩱ㟁ụ䛻 ⏝䛷䛝䜛䜲䜸䞁ఏᑟᛶᅛయ㟁ゎ㉁䛻䛿䠈㓟≀䜲䜸䞁 䛜ື䛟䜒䛾䛻㝈䜙䜜䜛ヂ䛷䛿䛺䛟䠈䛘䜀䝥䝻䝖䞁䛜ື䛟 ሙྜ䜢⪃䛘䜛䛸䠈⇞ᩱ䛾ᚠ⎔䛜ᚲせ䛸䛺䜚䠈Ⓨ㟁䛾ຠ ⋡䛾ྥୖ䛜ᮇᚅ䛥䜜䜛䛸⪃䛘䛯᪂䛺䜰䜲䝕䜱䜰䛻䜘䜛 䜒䛾䛷䛒䜛䠊䛣䛾ሙྜ䛷䜒䠈㧗䛔䝥䝻䝖䞁ఏᑟᛶ䛾䝉䝷䝭䝑 䜽䝇䛜㛤Ⓨ䛷䛝䛺䛡䜜䜀ヰ䛻䛺䜙䛺䛔䛾䛷䛒䜛䛜䠈✀䚻 ᳨ウ䛾⤖ᯝ㻿㼞㻯㼑㻻㻟䜢ẕయ䛸䛧䛯䝨䝻䝤䝇䜹䜲䝖ᆺ䛾ᅛ⁐ య䛺䛹䛻䠈㻤㻜㻜䉝䛷㻢䡚㻣㽢㻝㻜㻙㻟㻿㼏㼙㻙㻝䛾䝥䝻䝖䞁ᑟ㟁⋡䜢 ♧䛩䜒䛾䛜䛒䜛䛣䛸䜢ぢ䛔䛰䛧䛯㼇㻝㻤㼉䠊㻌 㻌 䛣䛣䛷䠈䛣䛾䜘䛖䛻䜒䛸䜒䛸Ỉ⣲䜢ྵ䜎䛺䛔䜒䛾䛻䛺䛬䝥 䝻䝖䞁ఏᑟᛶ䛜ฟ䜛䛛䜢⪃䛘䛶䜏䜛䠊ᙜ↛ᅇ䜚䛛䜙䛻䛺䛻 䛜䛧䛛䛾ᙳ㡪䜢ཷ䛡䛶䝥䝻䝖䞁ఏᑟ䛜Ⓨ⌧䛩䜛䛾䛷䠈ඛ 䛾┿ᛶ䛻ᑐ䛧䛶⣧≀㻔እᅉ㻕ᛶ䛾䜲䜸䞁ఏᑟయ䛷䛒䜛䛸 ゝ䛘䜛䠊䛣䛖⪃䛘䜜䜀䠈ᅇ䜚䛾㞺ᅖẼ䛻౫Ꮡ䛧䛶ఏᑟᛶ 䛜ኚ䛩䜛㓟≀୰䛷䛾㟁Ꮚఏᑟᛶ䜢ᛮ䛔ᾋ䛛䜉䜛 䛜䛷䛝䜛䠊᭱ึ䛛䜙㓟≀䜲䜸䞁✵᱁ᏊⅬ䜢䜒䛴㓟≀ 䛻䛚䛔䛶䠈ᅇ䜚䛾㓟⣲䜺䝇䛸ḟ䛾ᖹ⾮ᛂ䛜⏕䛨䛶䛔䜛 ᅗ7㻌 䝏䝳䞊䝤≧༢䝉䝹䛾┤/୪ิ㓄ิ䛾 ᵝᏊ䛸䛭䛾᩿㠃ᅗ ⾲1㻌 ᕷ㈍䛾ᐙᗞ⏝⇞ᩱ㟁ụ䛾ᵝ 䛴䜎䜚᭱ప㝈䛷㻞㻟㻢㻌 㼗㼓䛾Ⅳ㓟䜺䝇䛜ฟ䜛䠊䛣䜜䛷୍⯡䛾 㢼࿅䜔䝅䝱䝽䞊䛾せồ䛻䛿ᛂ䛘䜙䜜䜛䛸䛧䛶䜒䠈㢼࿅䛾 ㏣䛔⅕䛝䠈ㄪ⌮䛻䜺䝇䜢䛘䜀䜒䛳䛸ከ䛟䛾Ⅳ㓟䜺䝇䜢 ฟ䛩䠊Ⓨ㟁䛧䛯㟁Ẽ䛷䛭䜜䜢㈥䛘䜀䠈⏝㟁ຊ䛜ቑ䛘䠈 䜔䛿䜚㻌 䜒䛳䛸ከ䛟䛾Ⅳ㓟䜺䝇䜢ฟ䛩䠊᭦䛻ຍ䛘䛶䛣䛾ሙ ྜ䠈ึᮇᢞ㈨䛻㻟㻜㻜௨ୖ䛛䜛䠊⿵ຓ㔠䛜䛒䜛䛛䜙 Ⰻ䛔䛸ゝ䛖䜒䛾䛜䛔䜛䛜䠈䛣䛾䜒䛾䜢㐀䛳䛯䛻ึᮇᢞ㈨ 䛻ᑐᛂ䛧䛯ィ⟬䜒䛷䛝䛺䛔Ⳙ䛺㔞䛾Ⅳ㓟䜺䝇䜢ฟ䛧䛯 䛣䛸䛻䛿ఱ䜒ゝ䜟䛺䛔䜀䛛䜚䛛䠈䛭䛾ᚋ䛾⏝䛾ຠ⋡ 䛷⪃䛘䛶䜒䛣䛾〇㐀䛾䜶䝛䝹䜼䞊䜢ᅇฟ᮶䛺䛔䛣䛸 䜒䛟Ẽ䛵䛔䛶䛔䛺䛔䛿ၥ㢟䛷䛒䜝䛖䠊㻌 㻌 䛥䜙䛻ᅗ㻠䛾୰䛻䜒ၥ㢟䛜㞃䛥䜜䛶䛔䜛䠊㻝䛴䛿䠈ⅆຊ Ⓨ㟁䛿⇕䜶䝛䝹䜼䞊䛜ຠ⋡ⓗ䛻⏝䛥䜜䛪䠈䛭䜜⮬య 䛾ຠ⋡䛜ప䛔䛸䛥䜜䛶䛔䜛䛣䛸䛷䛒䜛䠊㻞䛴┠䛿⇞ᩱ㟁ụ 䛷䛿䝁䝆䜵䝛䝺䞊䝅䝵䞁䛸ゝ䛳䛶ᗫ⇕䜢༑ศά⏝䛧䛶䛔䜛 䛾䛻䠈㏻ᖖ䛾ⅆຊⓎ㟁䛷䛿䛣䛾⇕䜶䝛䝹䜼䞊䛜ຠ⋡ⓗ 䛻⏝䛥䜜䛺䛔䛣䛸䛷䛒䜛䠊䛧䛛䛧ᐇ㝿䛻䛿䠈ᮾ㟁䛾䜺䝇 䝍䞊䝡䞁䛸Ẽ䝍䞊䝡䞁䜢⤌䜏ྜ䜟䛫䛯᭱᪂䛾䝁䞁䝞䜲 䞁䝗䝃䜲䜽䝹Ⓨ㟁䛾ᐇ⦼䛷䛿㻡㻜㻑䛿㐭䛛䛻㉸䛘䛯ຠ⋡䜢 ♧䛧䛶䛔䜛䛧䠈䜲䜼䝸䝇䛷䛿䝻䞁䝗䞁ᕷෆ䛻㐀䛳䛯ᑠᆺⅆ ຊⓎ㟁ᡤ䛷༑ศᗫ⇕⏝䛧䛯ᐇ⦼䛜䠈㻝㻥㻜㻜ᖺ௦ึ䜑䛛 䜙䛒䜛䠊๓⪅䛿⪏⇕ᮦᩱ䛾Ⓨ㐩䛜䛭䛖䛥䛫䛯䜟䛡䛷䛒䜚䠈 ㏆䛔ᑗ᮶㻝㻢㻜㻜䉝䛷✌ാ䛷䛝䜜䜀ຠ⋡䛿⌮ㄽୖ㻤㻜㻑䜢㉺ 䛘䛶䛧䜎䛖䜒䛒䜚䛖䜛䠊䛣䛖䛺䜛䛸⇞ᩱ㟁ụ䛾ព⩏䜢ᮏᙜ 䛻ぢᴟ䜑䜛ᚲせ䛻㏕䜙䜜䛶䛟䜛䠊ᗫ⇕䜢ྵ䜑䛯⇕䜶䝛䝹 䜼䞊䜢ຠ⋡ⓗ䛻⏝䛩䜜䜀䠈䛯䛰▼Ἔ䜢⇞䜔䛩䛰䛡䛷 䜋䛸䜣䛹㻝㻜㻜㻑㏆䛔ຠ⋡䛷㟁Ẽ䛜ᚓ䜙䜜䜛䛺䜣䛶䠈䛣䜣䛺 䛩䜀䜙䛧䛔䛣䛸䛿䛺䛔䛛䜙䛷䛒䜛䠊㻌 㻌 䛣䛣䛷㛫㐪䛘䛶䛿䛔䛡䛺䛔䛾䛿䠈⇞ᩱ㟁ụ䜢ྰᐃ䛧䛶 䛔䜛ヂ䛷䛿䛺䛔䛣䛸䛷䛒䜛䠊ᢏ⾡䛾Ⓨ㐩䜔㠉᪂䛛䜙ゝ䛘 䜀䠈⇞ᩱ㟁ụᢏ⾡䛿㔜せ䛷䛒䜛䛧䠈⏝䛥䜜䜛ሙ㠃䜢⪃ 䛘䜜䜀᭦䛻䛭䛾㔜せ䛥䛿ቑ䛩䠊䛧䛛䛧䠈䛒䜛ே䛜䛣䜜䛿 䛔䛔䜣䛰䛸ゝ䛖䛸䛩䛠䛻䛭䜜䜢༢⣧䛻ಙ䛨䛶䠈䛔䛔䜣䛰 䛔䛔䜣䛰䛸㏄ྜ䛩䜛᪥ᮏே䠄⛉Ꮫ⪅䠅䛾㢼₻䛻䛿ὀព䛜 ᚲせ䛷䛒䜛䛸ゝ䛘䜛䠊䛧䛛䜛䜉䛝䝕䞊䝍䛻ᇶ䛵䛝ุ᩿䜢 ୗ䛩ᚲせ䛜䛒䜝䛖䠊㻌 㻌 㸳㸬 ᒾཎ◊✲ᐊᙜࡢ࢜ࣥఏᑟయ◊✲ 㻌 㻌 䛣䜜䜎䛷䛿ྜᡂἲ䜢ᛕ㢌䛻䛚䛝䠈䜲䜸䞁ఏᑟయ䛾タィ 䛸䛧䛶᭱㏆䛾䝖䝢䝑䜽䝇䜢㏙䜉䛶䛝䛯䛜䠈➹⪅䛜ୖグ䛾䛣 䛸䛻ὀ┠䛩䜛௨๓䠈䛴䜎䜚㻝㻥㻣㻤ᖺ䛾ᒾཎᩍᤵ䛾㉱௵ᙜ 䠈᪂䛧䛔◊✲䝔䞊䝬䛸䛧䛶ྲྀ䜚ୖ䛢䜙䜜䛯䜒䛾䛻䠈㧗 ᆺ䝥䝻䝖䞁ఏᑟయ䛾㛤Ⓨ䛜䛒䛳䛯䠊䛣䜜䛿䠈⇞ᩱ㟁ụ䛻 ⏝䛷䛝䜛䜲䜸䞁ఏᑟᛶᅛయ㟁ゎ㉁䛻䛿䠈㓟≀䜲䜸䞁 䛜ື䛟䜒䛾䛻㝈䜙䜜䜛ヂ䛷䛿䛺䛟䠈䛘䜀䝥䝻䝖䞁䛜ື䛟 ሙྜ䜢⪃䛘䜛䛸䠈⇞ᩱ䛾ᚠ⎔䛜ᚲせ䛸䛺䜚䠈Ⓨ㟁䛾ຠ ⋡䛾ྥୖ䛜ᮇᚅ䛥䜜䜛䛸⪃䛘䛯᪂䛺䜰䜲䝕䜱䜰䛻䜘䜛 䜒䛾䛷䛒䜛䠊䛣䛾ሙྜ䛷䜒䠈㧗䛔䝥䝻䝖䞁ఏᑟᛶ䛾䝉䝷䝭䝑 䜽䝇䛜㛤Ⓨ䛷䛝䛺䛡䜜䜀ヰ䛻䛺䜙䛺䛔䛾䛷䛒䜛䛜䠈✀䚻 ᳨ウ䛾⤖ᯝ㻿㼞㻯㼑㻻㻟䜢ẕయ䛸䛧䛯䝨䝻䝤䝇䜹䜲䝖ᆺ䛾ᅛ⁐ య䛺䛹䛻䠈㻤㻜㻜䉝䛷㻢䡚㻣㽢㻝㻜㻙㻟㻿㼏㼙㻙㻝䛾䝥䝻䝖䞁ᑟ㟁⋡䜢 ♧䛩䜒䛾䛜䛒䜛䛣䛸䜢ぢ䛔䛰䛧䛯㼇㻝㻤㼉䠊㻌 㻌 䛣䛣䛷䠈䛣䛾䜘䛖䛻䜒䛸䜒䛸Ỉ⣲䜢ྵ䜎䛺䛔䜒䛾䛻䛺䛬䝥 䝻䝖䞁ఏᑟᛶ䛜ฟ䜛䛛䜢⪃䛘䛶䜏䜛䠊ᙜ↛ᅇ䜚䛛䜙䛻䛺䛻 䛜䛧䛛䛾ᙳ㡪䜢ཷ䛡䛶䝥䝻䝖䞁ఏᑟ䛜Ⓨ⌧䛩䜛䛾䛷䠈ඛ 䛾┿ᛶ䛻ᑐ䛧䛶⣧≀㻔እᅉ㻕ᛶ䛾䜲䜸䞁ఏᑟయ䛷䛒䜛䛸 ゝ䛘䜛䠊䛣䛖⪃䛘䜜䜀䠈ᅇ䜚䛾㞺ᅖẼ䛻౫Ꮡ䛧䛶ఏᑟᛶ 䛜ኚ䛩䜛㓟≀୰䛷䛾㟁Ꮚఏᑟᛶ䜢ᛮ䛔ᾋ䛛䜉䜛 䛜䛷䛝䜛䠊᭱ึ䛛䜙㓟≀䜲䜸䞁✵᱁ᏊⅬ䜢䜒䛴㓟≀ 䛻䛚䛔䛶䠈ᅇ䜚䛾㓟⣲䜺䝇䛸ḟ䛾ᖹ⾮ᛂ䛜⏕䛨䛶䛔䜛 ᅗ7㻌 䝏䝳䞊䝤≧༢䝉䝹䛾┤/୪ิ㓄ิ䛾 ᵝᏊ䛸䛭䛾᩿㠃ᅗ ⾲1㻌 ᕷ㈍䛾ᐙᗞ⏝⇞ᩱ㟁ụ䛾ᵝ
䛸⪃䛘䜛䠊㻌 㻌 㻌 㻌 㻝㻛㻞㻌㻻㻞㻌㻗㻌 䕕㻌 䠙㻌 㻻㻞䠉㻗㻌㻞㻌㼔㻗㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻞㻕㻌 㻌 䛣䛣䛷䕕䛿㓟≀䜲䜸䞁䛾✵᱁ᏊⅬ䜢♧䛩䠊䛣䛾䠈㟁 Ꮚ㻔ṇᏍ㻕ఏᑟᛶ䛜Ⓨ⌧䛩䜛䛿䛪䛷䛒䜛䠊䛣䛣䛷㟁Ꮚఏᑟ ᗘ䃢㼔㻌 䛿ṇᏍ⃰ᗘ㻌 㼇㼔㻗㼉䛻ẚ䛩䜛䛿䛪䛷䛒䜛䛜䠈㻌 㻌 㻌 㻌 㻷㻌㻩㻌㻔㼇㻻㻞㻙㼉䞉㼇㼔㻗㼉㻞㻕㻛㻔㼜㻻 㻞㻝㻛㻞䞉㼇䕕㼉㻕㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻟㻕㻌 㻌 䛾㛵ಀ䛻䜘䜚㻌㼜㻻㻞㻝㻛㻢㻌 㻔䕕⃰ᗘ䛜ୖグᛂ⮬య䛻䜘䜚ᮏ㉁ ⓗ䛻ኚ䜟䜚䛖䜛䛸䛝㻕䠈䛒䜛䛔䛿㻌㼜㻻㻞㻝㻛㻠㻌 㻔䕕䛜ูせᅉ䛷ከ䛟 Ꮡᅾ䛧䠈ୖグᛂ䛻䜘䜚䛝䛟ኚ䜟䜙䛺䛔䛸䛝㻕䛻౫Ꮡ䛩 䜛䛣䛸䛻䛺䜛䠊㻌 㻌 ᭦䛻䛣䛣䛷ỈẼ䛸䛾ᖹ⾮䜢⪃䛘䜛䠊ỈẼ䛿㓟⣲䜢 䜒䛳䛶䛔䜛䛾䛷䠈䛣䛾㓟⣲䛜ୖグ䛾㓟≀䛾✵᱁ᏊⅬ䛻 ධ䜛ሙྜ䠈㻌 㻌 㻌 㻌 㻴㻞㻻㻌㻗㻌 䕕㻌 䠙㻌 㻻㻞䠉㻗㻌㻞㻌㻴㻗㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻠㻕㻌 㻌 䛾ᘧ䛜䛛䛡䜛䠊䛣䛾ᘧ⮬య䛜እᅉᛶ䛾䝥䝻䝖䞁ఏᑟᛶ䛾 Ⓨ⌧䜢ព䛩䜛䜒䛾䛷䛒䜛䠊௨๓䛿ỈẼ㻔㻴㻞㻻㻕䛾㻴㻙㻻 ⤖ྜ䛜⡆༢䛻ษ䜜䜛䛿䛪䛜䛺䛔䛸䛾ᢈุ䜒䛒䛳䛯䛜䠈ษ 䜜䛶䛔䜛ヂ䛷䛿䛺䛟䠈䛹䛖䜔䜙䛭䜣䛺䛻㞴䛧䛔ᛂ䛷䛿䛺 䛔䛭䛖䛷䛒䜛䠊㻔㻝㻕䛸㻔㻟㻕ᘧ䜢⤌䜏ྜ䜟䛫䛶䠈㻌 㻌 㻌 㻌 㻴㻞㻌㻗㻌㻝㻛㻞㻌㻻㻞㻌 䠙㻌 㻴㻞㻻㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻡㻕㻌 㻌 㻌 䜢⪃៖䛩䜜䜀䠈㻌 㻌 㻌 㻌 㻝㻛㻞㻌㻴㻞㻌㻗㻌㻞㻌㼔㻗㻌 䠙㻌 㻞㻌㻴㻗㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻢㻕㻌 㻌 䛸䛔䛖༢⣧䛺ᘧ䜒ᚓ䜙䜜䜛䠊䛹䜜䜒ᮏ㉁ⓗ䛻䛿ྠ䛨ព䜢 䜒䛳䛶䛔䜛䠊䛣䛾⪃䛘᪉䛿䠈␗✀ඖ⣲䛾ῧຍ䛻䜘䜚㓟 ≀䜲䜸䞁䛾✵᱁Ꮚ䜢ᙧᡂ䛧䜔䛩䛔䝨䝻䝤䝇䜹䜲䝖ᆺ㓟 ≀䛾䜘䛖䛺ྜ≀䛻䛿䛖䜎䛟ᙜ䛶䛿䜎䜛㼇㻝㻥㼉䠊㻌 㻌 ⌧ᅾ䝨䝻䝤䝇䜹䜲䝖ᆺ䝥䝻䝖䞁ఏᑟయ䜢⏝䛔䛯⇞ᩱ㟁 ụⓎ㟁䛿⾜䜟䜜䛶䛔䛺䛔䛜䠈ᙜ䛣䜜䜢⏝䛔䜛Ⓨ㟁᪉ ᘧ䛿䇿㫽ྲྀ᪉ᘧ䇿䛸䜀䜜䛶䛔䛯䠊䛭䜜௨᮶䛣䛾◊✲䛿 ྡྂᒇᏛ䛒䜛䛔䛿ᴗ䛻䜒ᘬ䛝⥅䛜䜜䛯䠊⌧ᅾ䠰䠵䠧 䛷〇㐀㈍䛥䜜䛶䛔䜛⁐⼥䜰䝹䝭䝙䜴䝮୰䛾⁐ᏑỈ⣲ ᐃ⨨㻔䝜䝖䞊䝥㻕䛿䠈ᅛయ㟁ゎ㉁䛣䛭㻯㼍㼆㼞㻻㻟䜢ẕయ䛸䛧 䛯䜒䛾䛻௦䜟䛳䛶䛔䜛䛜䠈䛣䛾◊✲䝔䞊䝬䛜䜒䛯䜙䛧䛯 䛝䛺ᡂᯝ䛾୍䛴䛸ゝ䛘䜛䛷䛒䜝䛖䠊㏆ᖺ䛣䛾◊✲䜢ᶍ䛧䛯 ㄽᩥ䜒ከᩘⓎ⾲䛥䜜䛶䛔䜛䠊䛣䜜䜙䛾୰䛻䛿䠈ᑟ㟁ᛶ䛜 㻤㻜㻜䉝䛷㻝㻜㻙㻡㻿㼏㼙㻙㻝⛬ᗘ䛾䛸䛶䜒ప䛔䜒䛾䛷䛒䛳䛯䜚䠈䝥䝻 䝖䞁䛾ఏᑟ䜢䛻ド᫂䛷䛝䛶䛔䛺䛔䜒䛾䛜ከ䛟䛒䜛䛣䛸 䛿䠈┳㐣䛷䛝䛺䛔䛣䛸䛷䛒䜛䠊㻌 㻌 䛧䛛䛧䛺䛜䜙㏆ᖺ䠈ୖグ䛻ຍ䛘䛶᫂䜙䛛䛺䝥䝻䝖䞁ఏᑟ య䛸䛧䛶䠈ఏᑟᛶ䛜ప䛔䛺䛜䜙䝸䞁㓟ሷ⣔㼇㻞㻜㻙㻞㻞㼉䜔䜿䜲㓟 ሷ⣔㼇㻞㻟㼉䠈䝅䞊䝷䜲䝖ྜ≀⣔㼇㻞㻠㼉䠈䝰䞁䝰䝸䝻䝘䜲䝖⣔㼇㻞㻡㼉䛺 䛹䛜ሗ࿌䛥䜜䜛䜘䛖䛻䛺䛳䛯䠊䛣䜜䜙䛾䜸䜻䝋㓟ሷ⣔䛾 ྜ≀䛷䛾䝥䝻䝖䞁ఏᑟᛶ䛾Ⓨ⌧䛿䛹䛖⪃䛘䛯䜙䜘䛔䛷䛒 䜝䛖䛛䠊䜸䜻䝋㓟䛷䛒䜛௨ୖ䠈䝨䝻䝤䝇䜹䜲䝖ᆺྜ≀䛷 ⾜䜟䜜䜛䜘䛖䛺␗✀ඖ⣲ῧຍ䛷䛾┤᥋ⓗ䛺㓟≀䜲䜸 䞁✵᱁ᏊⅬ䛾ᙧᡂ䛿䠈୍⯡ⓗ䛻䛿↓⌮䛾䜘䛖䛷䛒䜛䠊䛯 䛰䛧䛭䜜䛻䜘䜚䜸䝹䝖䝸䞁㓟ሷ୰䛷䛾䝢䝻䝸䞁㓟ሷ䜔୕䝸 䞁㓟ሷ䛾⏕ᡂᅛ⁐䜢⪃䛘䜛䛸䠈䛣䜜䛿୍✀䛾㓟≀䜲䜸 䞁✵᱁ᏊⅬᙧᡂ䛻䛺䜙䛺䛔䛸⪃䛘䜙䜜䜛䠊䛭䛖䛺䜜䜀 ᚋ䛿䛧䜑䛯䜒䛾䛷䠈䛣䜜䜢䛧䛶ୖグ䛸ྠ䛨⌧㇟䛜㉳䛝 䜜䜀䝥䝻䝖䞁䛿⏕ᡂ䛧䠈䛭䛾⤖ᯝ䝥䝻䝖䞁ఏᑟ䛜㉳䛝䛖䜛䠊 ᙜヱㄽᩥ୰䛻䛿㞴䛧䛔グ㏙䛜䛧䛶䛒䜛䛜䠈⡆༢䛻ゝ䛘 䜀ୖグ䛾䜘䛖䛺ㄝ᫂䛜䛷䛝䜛䠊㻌 㻌 䛣䜜௨እ䛾䜲䜸䞁ఏᑟయ䛸䛧䛶䠈ᙜ◊✲ᐊ䛷䛿๓㏙䛾 㻮㼕㻞㻻㻟䜢ẕయ䛸䛧䛯ྛ✀䛾㓟≀䜲䜸䞁ఏᑟయ㼇㻞㻢㼉䜔䠈䜸 䜻䝅䝣䝑≀⣔䛾䝣䝑≀䜲䜸䞁ఏᑟయ㼇㻞㻣㼉䠈᭦䛻䛿୕ 䛾䝣䝑≀䜲䜸䞁ఏᑟᛶ㓟≀ཬ䜃䝣䝑≀䛾ྜᡂ㼇㻞㻤㼉 䛻ᡂຌ䛧䛯䠊䜎䛯㓟≀䜲䜸䞁䛸㟁Ꮚ䛜ྠ⛬ᗘᑟ㟁䛻㛵 䛩䜛㻯㼍㼀㼕㻻㻟⣔䛾᪂䛧䛔ΰྜఏᑟయ䜔䠈㧗䛔㟁Ꮚఏᑟ ᛶ䜢♧䛩㻯㼍㻹㼚㻻㻟⣔䛾㓟≀䝉䝷䝭䝑䜽䝇䛾ྜᡂ䛻䜒ᡂ ຌ䛧䛯㼇㻝㻥㻙㻟㻝㼉䠊䛥䜙䛻䠈๓⪅䛾㓟≀䜢㝸⭷䛻⏝䛔䛶୍᪉ 䜢ῶᅽ䛻䛩䜛䛸䠈✵Ẽ୰䛛䜙⣧㓟⣲䛜ᢳฟ䛷䛝䜛䛣䛸㼇㻟㻞㼉 䜔䠈ᚋ⪅䛾㓟≀䛿㧗 ᆺ⇞ᩱ㟁ụ䛾✵Ẽᴟᮦ䛸䛧䛶 䛰䛡䛷䛿䛺䛟䠈↝⤖䛥䛫䛯ከᏍ㉁䝉䝷䝭䝑䜽䝇䜢䜰䝹䜹䝸 㟁ụ䛾ṇᴟά≀㉁䛻⏝䛷䛝䜛䛣䛸䜒ᐇ㦂䛻䜘䜚♧䛩䛣 䛸䛜䛷䛝䛯㼇㻟㻟㻙㻠㻞㼉䠊㻌 㻌 㸴㸬 ᪂つ࡞࢜ࣥఏᑟయ 㻌 㻌 䛣䜜䜙䛻ຍ䛘䛶᪂䛧䛔ᑟ㟁యྜᡂ䜒ሗ࿌䛥䜜䛶䛔䜛䛾 䛷䛣䜜䜙䛻䛴䛶䜒㏙䜉䛺䛡䜜䜀䛺䜙䛺䛔䠊䜎䛪䜰䝙䜸䞁䜢 ᑟ㟁✀䛸䛩䜛䜒䛾䜢䛒䛢䜛䠊䛣䜜䜙䛻䛿ඛ䛻㏙䜉䛯⼯▼ ᆺ䜔䝨䝻䝤䝇䜹䜲䝖ᆺᵓ㐀䜢ᣢ䛴㓟≀୰䛾㓟≀䜲䜸 䞁ఏᑟᛶ䛻㛵䛩䜛ሗ࿌䜒䛒䜛䛜䠈ᮦᩱ䛚䜘䜃⤖ᬗᵓ㐀 ⓗ䛻 ᪂つ 䛷䛒䜛䛸ᛮ 䜟 䜜䛯䜒䛾䛿ᑡ 䛺䛔䠊䛭䛾 ୰䛻 㻮㻵㻹㻱㼂㻻㼄䝅䝸䞊䝈䛸䜀䜜䜛㻮㼕㻠㼂㻞㻙㼤㻹㼤㻻㻝㻝㻙 䃓㻔㻹䛿␗✀ 㔠ᒓඖ⣲㻕⣔䛾㓟≀䜲䜸䞁ఏᑟయ䛜䛒䜛㻠㻟㻙㻠㻡㻕䠊ᑟ㟁⋡ 䛿㻣㻜㻜䉝䛷㻝㻜㻙㻝㻿㼏㼙㻙㻝䜢㉺䛘䠈䛣䛾್⮬య䛿᭱䜒㧗䛔䜒䛾 䛻ᒓ䛩䜛䠊➹⪅䜙䜒䛛䛺䜚᫇㻮㼕㻞㻻㻟⣔䛾㓟≀䜲䜸䞁ఏᑟ
య䜢◊✲䛧䛶䛚䜚䠈䜒䛱䜝䜣㻮㼕㻞㻻㻟㻙㼂㻞㻻㻡⣔䛾ヨᩱ䛻䛿㧗 䛔䜲䜸䞁ఏᑟᛶ䛾䛒䜛䛣䛸䜒ሗ࿌䛧䛶䛔䜛㼇㻠㻢㼉䠊䛧䛛䛧䛣䛾 䜘䛖䛺㓟≀䛾ḞⅬ䛿䝉䞁䝃䞊䜔⇞ᩱ㟁ụ䛾㟁ゎ㉁䛻 ⏝䛧䜘䛖䛸䛩䜛䛻䠈㟁ゎ㉁⮬య䛾⇕ຊᏛⓗᏳᐃᛶ䛻 Ḟ䛡䜛䛯䜑䛻㑏ඖ䛥䜜䜛䛣䛸䛷䛒䜛䠊せ䛩䜛䛻㻢㻜㻜䉝䛷 㻝㻜㻙㻝㻞Ẽᅽ⛬ᗘ䛾㓟⣲ศᅽୗ䛻䛚䛟䛸䠈ᐜ᫆䛻㻮㼕䛾㔠ᒓ 䛜ᯒฟ䛩䜛䠊➹⪅䜙䛿䛣䛾䛣䛸䜢㏫⏝䛧䛶䠈ᙉไⓗ䛻㏻ 㟁䛩䜛䛣䛸䛷㟁ゎ㉁䛾ෆ㒊䛻⏕ᡂ䛥䛫䛯㻮㼕㔠ᒓ䛸㟁ゎ㉁ 㓟≀㻔㻮㼕㻞㻻㻟㻙㼅㻞㻻㻟㻕䛸䛾ᖹ⾮㓟⣲ศᅽ䜢㓟⣲䝫䝔䞁䝅䝱 䝹䛾ᇶ‽䛸䛧䛶⏝䛧䛯䠈ẚ㍑ⓗ㧗㓟⣲ศᅽ㡿ᇦ䛷 ⏝䛷䛝䜛䝉䞁䝃䞊㻔ᅗ㻤㻕䛻䛴䛔䛶ሗ࿌䛧䛯䛜䠈䛣䜜䜒䛛䛺 䜚๓䛾䛣䛸䛷䛒䜛㼇㻠㻣㼉䠊㻌 㻌 㸵㸬 Ụᆏ◊✲ᐊ௨ᚋࡢ࢜ࣥఏᑟయ◊✲ 㻌 㻌 㻝㻥㻤㻥ᖺ䛾ᨵ⤌ᚋ䛛䜙䠈◊✲ᐊᢸᙜ䛜Ụᆏ䛸䛺䛳䛯䠊䛣 䛣䛻䛚䛔䛶䛣䜜䜎䛷䛾◊✲᪉㔪䜢䛝䛟㌿䛩䜛䛣䛸䛺䛟 ᪂䛧䛔ᮦᩱ䛾◊✲䛻㏕䜙䜜䛯䠊䛣䛾㝿✀䚻䛾᳨ウ䛾ᮎ䠈 ὀ┠䛧䛯䜲䜸䞁ఏᑟᛶᅛయ䛻䛿䠈䝅䞊䝷䜲䝖ᆺᵓ㐀䜔䝇 䝢䝛䝹ᆺᵓ㐀䜢䜒䛴ྜ≀䛜䛒䛳䛯䠊䛣䛾䛖䛱䝅䞊䝷䜲䝖 䛸䛿⅊㔜▼䠄㻯㼍㼃㻻㻠䠅䛾䛣䛸䛷䠈㻯㼍䛸㼃䜢➼౯䛻⪃䛘䜜䜀䠈 ᅗ㻥䛻♧䛥䜜䜛䛤䛸䛟ṍ䜣䛰⺯▼䠄㻯㼍㻲㻞䠅ᆺ䛾⤖ᬗᵓ㐀䜢 䜒䛴䛸⪃䛘䛶ᕪ䛧ᨭ䛘䛺䛔䠊ᚑ䛳䛶䛣䛾䜒䛾䛻㓟≀䜲䜸 䞁ఏᑟᛶ䛜Ⓨ⌧䛩䜛䛾䛿⌮ゎ䛧䜔䛩䛔䠊䛴䜎䜚⺯▼ᆺ ᵓ㐀䛾ᅛ⁐య䛻䛿䠈Ᏻᐃ䝆䝹䝁䝙䜰䜢ጞ䜑䠈✀䚻䛾䜲 䜸䞁䛜㟁Ẽ䜢ఏ䛘䜛ᮦᩱ䛜▱䜙䜜䛶䛔䜛䠊䛧䛯䛜䛳䛶䠈䝅 䞊䝷䜲䝖ᆺ㓟≀䜒䛣䜜䜙䛾ᮦᩱ䛾ẕయ䛸䛺䜚䛖䜛䛾䛷䛿 䛺䛔䛛䛸⪃䛘䛯䜒䛾䛷䛒䜛䠊㻌 㻌 䛧䛛䛧ᐇ㝿䛻㧗䛔ᑟ㟁ᛶ䜢♧䛩䛾䛿㻯㼍㼃㻻㻠䜢ẕయ䛸䛧 䛯䜒䛾䛷䛿䛺䛟䠈㻼㼎㼃㻻㻠㼇㻠㻤㼉䜔㻮㼕㼂㻻㻠㼇㻠㻥㼉䛺䛹䛾䜘䛖䛻ྵ䜎䜜 䜛㻞✀䛾䜹䝏䜸䞁䛾㟁Ẽ㝜ᛶᗘ䛜䛒䜎䜚␗䛺䜙䛪䠈య䛸 䛧䛶」㓟≀ⓗ䛺ᛶ㉁䜢♧䛩䜒䛾䛻㝈䜙䜜䛶䛔䜛䠊⤖ᯝ ⓗ䛻䠈䝅䞊䝷䜲䝖ᆺᵓ㐀䜢䜒䛴㓟≀䛾䛖䛱㻼㼎㼃㻻㻠䜢ẕ య䛸䛧䛯㻼㼎㻝㻙㼤㻸㼚㼤㼃㻻㻠㻗㼤㻛㻞⣔䠄㻸㼚䛿䝷䞁䝍䝜䜲䝗ඖ⣲䠅䛷♧䛥 䜜䜛䜘䛖䛻㐣䛾᱁Ꮚ㛫㓟≀䜲䜸䞁䜢⪃䛘䛯ሙྜ䛻䛿䠈 ᗈ䛔⤌ᡂ⠊ᅖ䛻䜟䛯䛳䛶ẕయ䛸ྠ䛨ᵓ㐀䛾ᅛ⁐య䛜ᚓ 䜙䜜䠈ᘧ୰䛻♧䛥䜜䜛䜘䛖䛺᱁Ꮚ㛫㓟≀䜲䜸䞁䛾⛣ື 䛻 䜘 䜚 䠈 㓟 ≀ 䜲 䜸 䞁 ఏ ᑟ ᛶ 䛜 ⌧ 䜜 䠈 䛭 䛾 ᑟ 㟁⋡ 䛿 㻤㻜㻜䉝䛷㻞䡚㻟㽢㻝㻜㻙㻞㻿㼏㼙㻙㻝䛻䜒䛺䜛䛣䛸䜢♧䛩䛣䛸䛜䛷䛝䛯 㼇㻡㻜㻙㻡㻢㼉䠊䛣䜜䜙䛾㓟≀䛷䛿ᑟ㟁䛻䜛䛸⪃䛘䜙䜜䜛᱁Ꮚ 㛫㓟≀䜲䜸䞁䛾⏕ᡂ䛾䛒䜛䛣䛸䛜㠀ᖖ䛻⯆῝䛔䠊᭱ ㏆䛻䛺䛳䛶䠈䛣䛾㓟≀䜲䜸䞁ఏᑟᛶ䜢Ⓨ⌧䛩䜛᱁Ꮚ㛫 㓟≀䜲䜸䞁䜢䜒䛴ᅛ⁐య䛿䠈䜘䛟▱䜙䜜䛶䛔䜛䝨䝻䝤䝇 䜹䜲䝖ᆺ㓟≀䛻䛚䛔䛶䜒䛭䛾Ꮡᅾ䜢♧၀䛩䜛ㄽᩥ䜢Ⓨ ⾲䛩䜛䛣䛸䛜䛷䛝䛯㼇㻡㻣㼉䠊㻌 㻌 ୍᪉䝇䝢䝛䝹ᆺ㓟≀䛾ᵓ㐀䛿䠈䜘䛟▱䜙䜜䛶䛔䜛䜘䛖 䛻㓟≀䜲䜸䞁䛾ᐦሸ䛧䛯㝽㛫䛾୍㒊䛻つ๎ⓗ䛻㔠 ᒓ䜲䜸䞁䛜ධ䛳䛯䜒䛾䛷䠈୍⯡ⓗ䛻䛿㓟≀䜲䜸䞁䛾ື 䛝䛿ᅔ㞴䛸⪃䛘䜙䜜䜛䠊䛧䛛䛧㏫䝇䝢䝛䝹ᆺᵓ㐀䜢䜒䛱䛣 䜜 䛻 䜹 䝏 䜸 䞁 䛾 Ḟ ᦆ 䜢 ྵ 䜐 䜘 䛖 䛻 タ ィ 䛧 䛯 ᅛ ⁐ య 㻔㼆㼚㻞㻙㼤㻛㻞㼀㼕㻝㻙㼤㼀㼍㼤㻻㻠㻕䛷䛿㻝㻜㻜㻜䉝䛷㻝㻜㻙㻟㻿㼏㼙㻙㻝䛸䛒䜎䜚㧗䛔ᑟ 㟁⋡䛷䛿䛺䛔䛜☜䛛䛻㓟≀䜲䜸䞁䛾ఏᑟᛶ䜢♧䛩䛣 䛸䛜ศ䛛䛳䛯㼇㻡㻤㻘㻡㻥㼉䠊䛣䜜䛿ᅗ㻝㻜䛻♧䛧䛯䜘䛖䛻䜹䝏䜸䞁䝃 䜲䝖䛜✵㝽䛷䛒䜛䛸㓟≀䜲䜸䞁⨨䛜㏻ᖖ䛾⨨䛛䜙 ✵㝽ഃ䛻ⱝᖸ䝅䝣䝖䛧䠈ぢ䛛䛡ୖ㓟≀䜲䜸䞁䛾✵᱁Ꮚ Ⅼ䛷䛝䠈䛭䛣䜢䛧䛯୍✀䛾‽᱁Ꮚ㛫ᶵᵓ䛷㓟≀䜲䜸 䞁䛜⛣ື䛩䜛䛸⪃䛘䜜䜀⌮ゎ䛷䛝䜛䠊䛣䛾㓟≀䜲䜸䞁 䛾䝅䝣䝖䛿୰ᛶᏊᅇᢡ䛻䜘䛳䛶䜋䜌ド᫂䛥䜜䛯䛸ゝ䛘䜛 㼇㻢㻜㻙㻢㻞㼉䠊䜒䛱䜝䜣ᮏ◊✲ᐊ䛾ᡂᯝ䛷䛒䜛䠊㻌 㻌 㻌 ḟ䛻䜹䝏䜸䞁䜢ᑟ㟁✀䛸䛩䜛䜒䛾䛷䛿䠈䜔䛿䜚䜰䝹䜹䝸 ᅗ8㻌 Bi2O3䜢ẕయ䛸䛧䛯㓟⣲䜺䝇䝉䞁䝃䛾 ᶍᘧᅗ ᅗ9㻌 䝅䞊䝷䜲䝖ᆺ⤖ᬗᵓ㐀䛾ᶍᘧᅗ
䜲䜸䞁ఏᑟయ䠈≉䛻䝸䝏䜴䝮䜲䜸䞁ఏᑟయ䛾◊✲䛜ከ䛔䠊 ᙜ◊✲ᐊ௨እ䛷䜒䠈㓟⣲㓟ሷ㼇㻢㻟㼉䛚䜘䜃」㓟≀㼇㻢㻠㻘㻢㻡㼉䜢 ẕయ䛸䛧䛯ὀ┠䛩䜉䛝䜒䛾䛾ሗ࿌䛜䛒䜛䛜䠈ᑟ㟁⋡䛾㧗 䛥䛛䜙䛔䛘䜀䝨䝻䝤䝇䜹䜲䝖ᆺ㓟≀䛾㻸㼍㻜㻚㻡㻸㼕㻜㻚㻡㼀㼕㻻㻟䛚䜘 䜃䛭䛾⤌ᡂ䜢ⱝᖸኚ䛘䛯ᅛ⁐య䛜ᆺⓗ䛺䜒䛾䛷䛒䜝 䛖㼇㻢㻢㼉䠊ᐊ 䛷㻝㻜㻙㻟㻿㼏㼙㻙㻝䜢㉺䛘䜛ᑟ㟁⋡䜢♧䛩䛸ゝ䛖䠊䛧䛛 䛧㼀㼕䜢㻡㻜㼏㻛㼛䜒ྵ䜐䛾䛷䠈㟁ụ㟁ゎ㉁䛸䛧䛶⏝䛔䜛ሙྜ 䛻䛿䝸䝏䜴䝮䛺䛹䛾㝜ᴟά≀㉁䛸䛾᥋ゐ䛻䜘䜛㑏ඖᛂ 䜢ඞ᭹䛩䜛ᚲせ䛜䛒䜛䠊䜎䛯䝸䝏䜴䝮ఏᑟᛶ௨እ䛻䜒㻴ᆺ 䝰䝹䝕䝘䜲䝖䛻ᐊ 䛷㻝㻜㻙㻡㻿㼏㼙㻙㻝䛾䝥䝻䝖䞁ఏᑟᛶ䛜ሗ࿌ 䛥䜜䛶䛔䜛㼇㻢㻣㼉䛣䛸䜒䛡ຍ䛘䛶䛚䛝䛯䛔䠊㻌 㻌 㻌 ୍ ᪉ ᙜ ◊ ✲ ᐊ 䛷 䛿 䠈 ๓ ㏙ 䛾 䝅 䞊 䝷 䜲 䝖 ᆺ ᵓ 㐀 䛷 䜒 㻯㼍㼃㻻㻠䛾㻯㼍䛾୍㒊䜢䛭䛾㻞ಸ㔞䛾୍౯䛾䝸䝏䜴䝮䜲䜸䞁 䛷⨨䛧䛯㻯㼍㻝㻙㼤㻸㼕㻞㼤㼃㻻㻠⣔ヨᩱ䛜䝸䝏䜴䝮䜲䜸䞁ఏᑟ䜢 Ⓨ⌧䛩䜛䛣䛸䜢᫂䜙䛛䛻䛧䛯㼇㻢㻤㼉䠊䛣䛾ሙྜ䝸䝏䜴䝮䜲䜸䞁 䛾ື䛝䜢䠈୰ᛶᏊ䝷䝆䜸䜾䝷䝣䜱䞊㻔㻺㻾㻳㻕䜢䛳䛶䝣䜱䝹 䝮ୖ䛻᫂ⓑ䛻♧䛩䛣䛸䛜䛷䛝䛯㼇㻢㻥㼉䠊䛣䛾୰ᛶᏊ䝷䝆䜸䜾 䝷䝣䜱䞊䜢ᮦᩱ㛤Ⓨ䛾◊✲䛻ᛂ⏝䛩䜛⪃䛘᪉䛿䠈ᙜ◊ ✲ᐊ䛻୍ᅾ⡠䛧䛶䛔䛯㙊⏣ຓᩍᤵ㻔⌧ᅾᮾிᏛⱁ Ꮫᩍᤵ㻕䛾䜰䜲䝕䜱䜰䛻䜘䜛䜒䛾䛷䠈ୡ⏺ⓗ䛻䜏䛶᪂䛺 䜒䛾䛷䛒䜛䛸䛔䛘䜛䠊䛣䛾᪉ἲ䛾≉ᚩ䜢ḟ⠇䛷㏙䜉䜛䛜䠈 ⌧ᅾ䠈ᙜ◊✲ᐊ䛷䛿䛣䛾᪉ἲ䜢䠈ከ䛟䛾䝸䝏䜴䝮䜲䜸䞁ఏ ᑟయ୰䛾䝸䝏䜴䝮䜲䜸䞁ᣑᩓಀᩘ䛾ホ౯㼇㻣㻜㻙㻣㻢㼉䜔Ỉ⣲྾ ⶶྜ㔠୰䛾Ỉ⣲ᣑᩓ䛾ᵝᏊ䛾ྍど㼇㻣㻣㻙㻤㻝㼉䛺䛹䛻ᖜᗈ䛟 ⏝䛧䠈䛭䛾ᡂᯝ䜢Ⓨ⾲䛧䛶䛔䜛䠊㻌 㻌 㸶㸬 15*ࡢཎ⌮ᛂ⏝ 㻌 ᅛయ㟁ゎ㉁䛾㟁ẼᏛⓗᛶ㉁䜢ㄪ䜉䜛ᇶ♏ⓗ◊✲䛿䠈 ᛂ⏝◊✲䛸䛸䜒䛻㏆ᖺ┒䜣䛻⾜䜟䜜䛶䛔䜛䠊䛧䛛䛧䛺䛜 䜙䠈ఏᑟ䜲䜸䞁䛾⃰ᗘศᕸ䜔ఏᑟᶵᵓ䜢᫂䜙䛛䛻䛧䛯ሗ ࿌䛿ᩘ䛜㝈䜙䜜䛶䛔䜛䠊䛣䜜䛿䠈㧗 䛷ᅛయヨᩱ୰䛾ఏ ᑟ䜲䜸䞁䜢ᐃ㔞䛩䜛᭷ຠ䛺 ᐃ᪉ἲ䛜䛺䛛䛳䛯䛣䛸䛻䜘 䜛䜒䛾䛸⪃䛘䜙䜜䜛䠊㻌 㻌 䛣䛾䜘䛖䛺≧ἣ䛾ୗ䠈➹⪅䜙䛿୰ᛶᏊ䝷䝆䜸䜾䝷䝣䜱䞊 㻔㻺㻾㻳㻕䛻䜘䛳䛶┤᥋䝸䝏䜴䝮䜲䜸䞁ఏᑟᛶᅛయ㟁ゎ㉁୰ 䛾䜲䜸䞁䛾ື䛝䜔䜲䜸䞁ศᕸ≧ἣ䜢ほᐹ䛧䛯䠊䜎䛯䠈䝸䝏 䜴䝮㠀Ỉ⁐፹⣔䛾㟁ゎ㉁䜢⏝䛔䛯䝸䝏䜴䝮㟁ụ䛾䠈ᨺ㟁 䛚䜘䜃㟁䛾䝸䝏䜴䝮䛾ື䛝䛻䛴䛔䛶䜒᳨ウ䛧䠈䛣䛾 ሙྜᅛ䛔䝇䝔䞁䝺䝇䛾⿕そ䜢㏻䛧䛶䜒㻺㻾㻳䜢⏝䛔䜜䜀᫂ ░䛻䝸䝏䜴䝮䛾ື䛝䜢ྍど䛷䛝䜛䛣䛸䜢ሗ࿌䛧䛯㼇㻤㻞㻘㻤㻟㼉䠊㻌 㻌 䛣䛾㻺㻾㻳䛿䠈㼄⥺䝷䝆䜸䜾䝷䝣䜱䞊䛸ྠᵝ䛾㠀◚ቯ᳨ᰝ ἲ䛾䜂䛸䛴䛷䛒䜚䠈ヨᩱ୰䛻ྵ䜎䜜䜛ඖ⣲㻔ྠయ㻕䛾୰ ᛶᏊῶ⾶ಀᩘ䛾ᕪ䜢⏝䛧䛶䠈ヨᩱ୰䛾ඖ⣲䛾ศᕸ䜢 ྍど䛩䜛䛣䛸䛜䛷䛝䜛䜒䛾䛷䛒䜛䠊䛣䛾ཎ⌮䛾ᴫ␎䜢ᅗ 㻝㻝䛻♧䛧䛯䠊ヨᩱ䜢㏱㐣䛧䛯୰ᛶᏊ䛿䠈䝣䜱䝹䝮䜹䝉䝑䝖 ෆ䛾䝁䞁䝞䞊䝍䞊䛻ሬᕸ䛥䜜䛯䜺䝗䝸䝙䜴䝮䛻ᤕ䛘䜙䜜䠈 ௨ୗ䛾᰾ᛂ䜢ᘬ䛝㉳䛣䛩䠊㻌 㻌 㻌 㻌 㻌 㻌㻝㻡㻡㻳㼐㻌 䠇㻌 㼚㻌 䊻㻌㻝㻡㻢㻳㼐㻌 䠇㻌 䃒㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻣㻕㻌 㻌 ᅗ10㻌 ✵㝽䜹䝏䜸䞁䝃䜲䝖䜢䛧䛯㓟≀䜲䜸䞁⛣ື䛾ᶍᘧᅗ ୰ᛶᏊ ; ⥺ࣇ࣒ࣝ ࣑ࣝヨᩱྎ ࢥࣥࣂ࣮ࢱ Ỉ⣲⃰ᗘ㸸 Ỉ⣲⃰ᗘ㸸ᑠ 㟁Ꮚ ヨᩱ 15* ീ ᅗ11㻌 ୰ᛶᏊ䝷䝆䜸䜾䝷䝣䜱䞊(NRG)䛾ཎ⌮
㻌 㻌 㻌㻝㻡㻣㻳㼐㻌 䠇㻌 㼚㻌 䊻㻌㻝㻡㻤㻳㼐㻌 䠇㻌 䃒㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻔㻤㻕㻌 㻌 ୖグ䛾᰾ᛂ䛷⏕䛨䛯㟁Ꮚ㻔ෆ㒊㌿㟁Ꮚ㻕䛜㼄⥺䝣䜱䝹 䝮䜢ឤග䛥䛫䜛䠊Ⓨ⏕䛩䜛㟁Ꮚ䛾ᩘ䛿䜺䝗䝸䝙䜴䝮䝁䞁䝞 䞊䝍䞊䛻฿㐩䛧䛯୰ᛶᏊ䛾ᩘ䛻ẚ䛩䜛䛾䛷䠈ヨᩱ䜢 ㏱㐣䛧䛯୰ᛶᏊᩘ㻔୰ᛶᏊ䛾㏱㐣ᗘ㻕䛻ᛂ䛨䛶䝣䜱䝹䝮⃰ ᗘ㻔㯮ᗘ㻕䛜ኚ䛧䠈㻺㻾㻳ീ䛜ᚓ䜙䜜䜛䠊䛣䛾᪉ἲ䛿䠈䛣 䜜䜎䛷䛻▱䜙䜜䛶䛔䜛⥲䛶䛾䜲䜸䞁ఏᑟయ䛾᳨ウ䛻ᛂ ⏝䛷䛝䜛ヂ䛷䛿䛺䛔䛜䠈䝸䝏䜴䝮䜲䜸䞁ఏᑟయ䜔䝥䝻䝖䞁 ఏᑟయ䛻䛿ᛂ⏝ྍ⬟䛷䠈ྛ᮲௳ୗ䛷ㄪ〇䛧䛯ヨᩱ䛾䝷 䝆䜸䜾䝷䝮䛜᫂░䛻ᚓ䜙䜜䛥䛘䛩䜜䜀䠈ྛᅛయ㟁ゎ㉁ෆ 䜢⛣ື䛩䜛䜲䜸䞁䛾⃰ᗘศᕸ䛸䜲䜸䞁䛾ື䛝䛭䛾䜒䛾䜢 ゎ᫂䛷䛝䜛䛾䛷䛿䛺䛔䛛䛸⪃䛘䜙䜜䛯䠊㻌 㻌 䛸䛧䛶䠈ᅗ㻝㻞䛻㻸㻵㻿㻵㻯㻻㻺䛾ᶆ‽ヨᩱ䛸ᣑᩓᑐヨᩱ䛾 㻺㻾㻳ീ䜢♧䛧䛯䠊䛣䛾ሙྜ䠈ྛヨᩱ䛿ྠయ㛫䛷୰ᛶ Ꮚῶ⾶䛜䛝䛟␗䛺䜛ᛶ㉁䜢䜒䛴䝸䝏䜴䝮䜢ྵ䜐䜒䛾䛸䛧 䛶䛔䜛䠊㻣㻸㼕䛿୰ᛶᏊ䜢䜘䛟㏱㐣䛩䜛䛜䠈㻢㻸㼕䛿㧗䛔୰ᛶᏊ ῶ⾶ಀᩘ䜢䜒䛴䠊ᅗ୰䛷ⓑ䛔㒊ศ䛜㻢㻸㼕䜢ྵ᭷䛩䜛㻺㻸㼕䛾 Ꮡᅾ㔞䛜ከ䛔㡿ᇦ䜢♧䛧䛶䛔䜛䠊䛧䛯䛜䛳䛶⇕ฎ⌮㛫 䛾▷䛔ᣑᩓᑐヨᩱ䛷䛿䠈㯮䛔㒊ศ䛸ⓑ䛔㒊ศ䛜᫂░䛷 䛒䜛䛜䠈㛫䛾⤒㐣䛸䛸䜒䛻䛣䛾㯮䛔㒊ศ䛜ḟ➨䛻ⓑ䛳 䜍䛟ኚ䛩䜛䠊䛣䜜䛿┦ᣑᩓ䛻䜘䜚䝸䝏䜴䝮䛜⛣ື䛩䜛 䛣䛸䜢♧䛩䜒䛾䛷䛒䜛䠊䛣䜜䜙䛾⤖ᯝ䛛䜙䠈ᣑᩓᑐヨᩱ䛾 ྛ㒊䛾㯮ᗘ䜢ᶆ‽ヨᩱ䛾䛭䜜䛸ẚ㍑᳨ウ䛩䜛䛸䠈 㻺㻸㼕䛾⃰ᗘ䝥䝻䝣䜯䜲䝹㻔ᅗ㻝㻟㻕䛜ᚓ䜙䜜䜛䠊䛣䜜䜢㻲㼕㼏㼗䛾 ᘧ䛷䛒䜟䛫䜛䛸䠈䝸䝏䜴䝮䛾ᣑᩓಀᩘ䛜ᚓ䜙䜜䜛䠊䛣䛾ᐇ 㦂䛿⇕䛻䜘䜛䜲䜸䞁䛾ᣑᩓ䜢ᢅ䛳䛯䜒䛾䛷䛒䜛䛜䠈㟁ᴟ 䜢䛡䛶㏻㟁䛧㟁Ẽศゎ䛥䛫䛯ヨᩱ䛻䛴䛔䛶䜒䠈ヨᩱෆ 㒊䛷䛾䝸䝏䜴䝮䜲䜸䞁䛾ᣑᩓ䛾ᵝᏊ䛿䠈䛔䛟䛴䜒䛾ヨᩱ 䛻䛴䛔䛶᪤䛻ྍど䛷䛝䛶䛚䜚䠈䜲䜸䞁㍺⋡䛾 ᐃ䜔ᑟ 㟁ᶵᵓ䛾⪃ᐹ䛻⏝䛥䜜䛶䛔䜛䠊㻌 㻌 Ỉ⣲䛿䠈๓㏙䛾䝸䝏䜴䝮䛸ྠᵝ䛻䠈䛭䛾㉁㔞ᩘ䛜␗䛺䜛 ྠయ䠈䛴䜎䜚㻝㻴䛸㻞㻰䛷䛿୰ᛶᏊῶ⾶ಀᩘ䛜䛝䛟␗䛺 䜛䛸䛔䛖ᛶ㉁䜢ᣢ䛴䠊㻞㻰䛿୰ᛶᏊ䜢䜘䛟㏱㐣䛥䛫䜛䛜䠈㻝㻴 䛿㧗䛔୰ᛶᏊῶ⾶ಀᩘ䜢䜒䛴䠊䛧䛯䛜䛳䛶㻝㻴䛾䜋䛛䛻 ୰ᛶᏊῶ⾶ಀᩘ䛾䛝䛺ඖ⣲䜢ᣢ䛯䛺䛔ヨᩱ䛻ᑐ䛧䛶䠈 㻺㻾㻳ἲ䜢⏝䛔䛶ヨᩱ୰䛾Ỉ⣲䛾ศᕸ䜢ほᐹ䛩䜛䛣䛸䛜 ᅗ12㻌 LISICON䛾ᶆ‽ヨᩱ䛚䜘䜃ᣑᩓᑐヨᩱ䛾NRGീ ᅗ13㻌 ᣑᩓᑐヨᩱ䛻䛚䛡䜛䠪Li⃰䝥䝻䝣䜯䜲䝹 ᅗ14㻌 Ỉ⣲྾ⶶ䜢♧䛩Mg3Ni䛾┿䛸RGീ
䛷䛝䜛䛸⪃䛘䜙䜜䜛䠊䛣䛣䛷䛿䠈㻹㼓㻙㻺㼕⣔䛾Ỉ⣲྾ⶶᮦᩱ 䛻ᑐ䛧䛶㻺㻾㻳ἲ䛾㐺⏝䜢ヨ䜏䛯⤖ᯝ䛻䛴䛔䛶㏙䜉䜛䠊䛣 䛾ሙྜ䠈ヨᩱ䛿ᩚᙧ䛧䛯㻹㼓㻙㻺㼕ྜ㔠䜢䠈㻞㻚㻢㻹䛾Ỉ⣲ 䝩䜴⣲䝘䝖䝸䜴䝮㻔㻺㼍㻮㻴㻠㻕Ỉ⁐ᾮ䛻ᾐₕ䛧Ỉ⣲䛥䛫䛯䜒 䛾䛸䛧䛶䛔䜛䠊㻌 㻌 ᅗ㻝㻠䛿䠈㻹㼓㻟㻺㼕䛾Ỉ⣲ฎ⌮㛫䛻ᑐ䛩䜛ヨᩱ䛾ኚ 䜢♧䛧䛯䜒䛾䛷䛒䜛䠊ヨᩱ䛾┿䛸㻺㻾㻳ീ䜢ᑐᛂ䛥䛫 䛶♧䛧䛶䛔䜛䠊䛣䛾ീ䛿㼄⥺䝣䜱䝹䝮䛛䜙䝇䜻䝱䝘䞊䛷䝁 䞁䝢䝳䞊䝍䞊䛻ྲྀ䜚䛣䜏䠈⏬ീฎ⌮䝋䝣䝖䜢⏝䛔䛶ᫎീ 䛧䛯䜒䛾䛷䛒䜛䠊┿䛷䛿ᮍฎ⌮䛾ヨᩱ䛿㔠ᒓගἑ䜢 ᣢ䛴䛜䠈Ỉ⣲ฎ⌮䜢⾜䛖䛸䛭䛾㔠ᒓගἑ䛿ኻ䜟䜜䠈⭾ ᙇ䛧䛶䛔䛟ᵝᏊ䛜䜟䛛䜛䠊䜎䛯䠈㻺㻾㻳ീ䛷䛿䠈Ỉ⣲䛜Ꮡ ᅾ䛩䜛ሙྜ䛾᪉䛜᫂䜙䛛䛻ྜ㔠䛾⦕䛜ⓑ䛟䛺䛳䛯㻺㻾㻳 ീ䛜ᚓ䜙䜜䛶䛔䜛䠊䛣䛾䛣䛸䛛䜙䠈㻺㻾㻳䛻䜘䜚Ỉ⣲྾ⶶྜ 㔠䛾ึᮇỈ⣲㐣⛬䜢ྍど䛷䛝䜛䛣䛸䛜䜟䛛䛳䛯䠊䛥 䜙䛻ྛヨᩱ䛻ᑐ䛩䜛㻺㻾㻳ീ䜢ヲ䛧䛟ぢ䜛䛸䠈┿䛻ぢ䜙 䜜䜛䜘䛖䛺Ỉ⣲ฎ⌮㛫䛾ቑຍ䛻䛸䜒䛺䛖ヨᩱ䛾⭾ᙇ䛻 䛧䛯䛜䛳䛶䠈ヨᩱෆ㒊䜈Ỉ⣲䛜ධ䛧䛶䛔䛟ᵝᏊ䛜ほᐹ 䛷䛝䜛䠊䜎䛯䠈ฎ⌮㛫䛸Ỉ⣲ධ῝䛥䛸䛾㛵ಀ䛛䜙䠈Ỉ ⣲䛾ᣑᩓ䛻㛵䛩䜛ሗ䛜ᚓ䜙䜜䜛䛿䛪䛷䛒䜛䠊ᅗ㻝㻡䛿䠈 Ỉ⣲ฎ⌮㛫䛾␗䛺䜛ྛヨᩱ䛾㻺㻾㻳ീ䛻ᑐ䛧䛶䠈ᤄ ධᅗ୰䛾ⓑ䛔䝷䜲䞁䛷♧䛧䛯㒊ศ䛻䛴䛔䛶䠈ⓑ㯮䛾⃰ ῐ䛾ኚ䜢ᩘ್䛧䛯㯮ᗘ䛾⤖ᯝ䜢♧䛧䛶䛔䜛䠊䛣䛾 ᅗ䛻䜘䜚䠈Ỉ⣲྾ⶶ䛻䜘䜛ྜ㔠䛾⭾ᙇ䛾䛝䛥䛸Ỉ⣲䛾 ྜ㔠ෆ㒊䜈䛾ධ䛾῝䛥䛾ኚ䜢ᩘ್䛸䛧䛶♧䛩䛣䛸䛜 䛷䛝䜛䠊䛣䛾ᩘ್䛧䛯䝥䝻䝣䜯䜲䝹䛛䜙䠈Ỉ⣲ධ῝䛥 䛸Ỉ⣲྾ᒙ䛾ཌ䛥䛾㛵ಀ䛜♧䛥䜜䠈⭾ᙇ⋡䛜ィ⟬䛷 䛝䜛䛧䠈᭦䛻䠈Ỉ⣲ฎ⌮㛫䛾ᖹ᪉᰿䛻ᑐ䛩䜛ྜ㔠䜈 䛾Ỉ⣲ධ῝䛥䛾㛵ಀ䛛䜙䛿䠈䛣䛾ྜ㔠୰䛻ᅛ⁐䛧䛶䛔 䜛Ỉ⣲䛾ᣑᩓಀᩘ䛜ồ䜑䜙䜜䜛䠊䛔䛪䜜䛻䛫䜘Ỉ⣲䛾 Ꮡᅾ䜒䝸䝏䜴䝮䛸ྠᵝ䛻ྍど䛷䛝䜛䛣䛸䛿᫂䜙䛛䛷䛒 䜛䠊㻌 㻌 ୖ䛷㏙䜉䛯᪉ἲ䛷ᚓ䜙䜜䜛䛾䛿䛒䛟䜎䛷ヨᩱ䛾ᢞᙳീ 䛷䛒䜛䠊䛭䛾䛯䜑䠈୰ᛶᏊ⥺䛾↷ᑕ᪉ྥ䛻Ꮡᅾ䛩䜛⥲䛶 䛾ඖ⣲䛾ῶ⾶ಀᩘ䛜⏬ീ䛾⃰ῐ䛻㛵ಀ䛧䠈ヨᩱ୰䛾ඖ ⣲ศᕸ䜢┤᥋ほ 䛩䜛䛣䛸䛜䛷䛝䛺䛔䠊䛧䛯䛜䛳䛶䠈㻺㻾㻳 ᐇ㦂䛻⏝䛔䜛䛣䛸䛜䛷䛝䜛䝸䝏䜴䝮䜲䜸䞁䛾ᣲື䜢ゎᯒ䛧 䜘䛖䛸䛩䜛ヨᩱ䛷䛿䠈୰ᛶᏊ↷ᑕ᪉ྥ䛾䝸䝏䜴䝮䜲䜸䞁ศ ᕸ䛜ᆒ୍䛷䛒䜛ᚲせ䛜䛒䜚䠈↷ᑕ᪉ྥ䛻ᆒ୍ศᕸ䛩 䜛䜘䛖䛺ヨᩱ䛾⢭ᐦ䛺 ᐃ䛿ྍ⬟䛷䛒䜛䠊䛭䛣䛷䛭䛾 䜘䛖䛺ሙྜ䛻䛿䠈୰ᛶᏊ⥺䜢⏝䛔䛯᪂䛧䛔ᢏ⾡䛷䛒䜛୰ ᛶᏊ⥺䝷䝆䜸䜾䝷䝣䜱䞊᩿ᒙᙳἲ䛜ὀ┠䛥䜜䜛䠊㻌 㻌 ᩿ᒙᙳ㻔㻯㼀㻦㻯㼛㼙㼜㼡㼠㼑㼐㻌 㼀㼛㼙㼛㼓㼞㼍㼜㼔㻕ἲ䛿䠈ほᐹᑐ㇟ 䛾ෆ㒊ᵓ㐀䜢㠀◚ቯ䛷ྍど䛩䜛ᢏ⾡䛾୍䛴䛷䛒䜛䠊 䛣䜜䜎䛷䛿䛻་⒪䛾ศ㔝䛷⏝䛔䜙䜜䛶䛝䛶䛚䜚䠈⥺※ 䛻䛿㼄⥺䜔㉸㡢Ἴ䛜⏝䛔䜙䜜䛶䛔䜛䠊䛣䛾⥺※䛻୰ᛶᏊ ⥺䜢⏝䛔䛯䜒䛾䛜୰ᛶᏊ⥺᩿ᒙᙳ㻔㻺㻾㻳㻙㻯㼀㻕ἲ䛷䛒 䜛䠊䛣䛾᪉ἲ䜢⏝䛩䜛䛣䛸䛻䜘䜚䝉䝷䝭䝑䜽䝇䛾᩿ᒙീ䜢 ᚓ䜛䛣䛸䛜䛷䛝䠈䛭䛾ീ䛻⌧䜜䛶䛔䜛ඖ⣲䛾ศᕸ䛛䜙䝉 䝷䝭䝑䜽䝇୰䛾䜲䜸䞁䛾ᣲື䜢ゎᯒ䛩䜛䛣䛸䛜䛷䛝䜛䠊䛣䛾 ᪉ἲ䛸䠈ู䛻᳨ウ䛩䜛㟁ᴟ䛸㟁ゎ㉁⏺㠃䛸䛾䜲䞁䝢䞊䝎 䞁䝇⢭ᐦ ᐃ䛾⤖ᯝ䛸ే䛫䛶䠈㟁ศᕸ䛸㟁ᴟᛂ䛾 ゎ᫂䜢⾜䛖䛣䛸䛜䛷䛝䜛䛾䛷䛿䛺䛔䛛䛸⪃䛘䜙䜜䜛䠊ᐇ㝿 ᅗ15㻌 Ỉ⣲ฎ⌮䛻క䛖㯮ᗘ䛾ኚ ᅗ16㻌 Ỉ⣲ฎ⌮䛧䛯ሢ≧Mg3Ni䛾 NRG-CT┿
䛻➹⪅䜙䛿↝⤖యヨᩱ㻔㻸㼕㻜㻚㻟㻡㻸㼍㻜㻚㻡㼀㼕㻻㻟䛸㻸㼕㻝㻚㻟㻟㼀㼕㻝㻚㻢㻣㻻㻠㻕䛻 䛴䛔䛶ᐇ㦂䜢⾜䛔䠈ヲ⣽䛺ㄝ᫂䛿┬␎䛩䜛䛜䠈䝸䝏䜴䝮 䜲䜸䞁䛿ヨᩱ୰䛷䛭䛾㟁Ẽຊ⥺䛻ἢ䛳䛶ᗈ䛜䜛༙ᙧ 䛾ศᕸ䜢䛧䛶䛔䜛䛣䛸䜢♧䛧䛯㼇㻣㻢㼉䠊㻌 㻌 ᅗ㻝㻢䛻䛿䚸Ỉ⣲ฎ⌮䜢䛧䛯㻹㼓㻟㻺㼕㻌 ሢ≧ヨᩱ䛻䛴 䛔䛶ᚓ䜙䜜䛯㻺㻾㻳㻙㻯㼀ീ䜢♧䛧䛯䠊ᶍᘧᅗ䛾㻝䡚㻠䛾ྛ ᩿㠃䛻䛚䛡䜛㻺㻾㻳ീ䛛䜙䠈⾲㠃㏆䛷䛿Ỉ⣲䛜୍ᵝ䛻 ศᕸ䛧䛶䛚䜚䠈䛭䛾䛾㒊ศ䛷䛿⾲㠃䛸ෆ㒊䛸䛾㛫䛻Ỉ ⣲⃰ᗘ䛾ᕪ䛜᫂░䛻䛒䜛䛣䛸䛜♧䛥䜜䛯䠊䛣䛾䛣䛸䛛䜙Ỉ ⣲䛿┤᪉యヨᩱ䛾ྛ㠃䛾⾲㠃䛛䜙୍ᵝ䛻ධ䛧䛶䛔䛟 䛣䛸䛜䜟䛛䛳䛯䠊䛣䛾ᐇ㦂䛻䛚䛔䛶䜒㻹㼓㻟㻺㼕䛿Ỉ⣲྾ⶶ 㔞䛜ከ䛟Ỉ⣲ධ㐣⛬䛜᫂☜䛻ศ䛛䛳䛯䠊㻌 㻌 ୖグ䛾䜘䛖䛻䠈䝸䝏䜴䝮䜲䜸䞁ఏᑟయ䛒䜛䛔䛿Ỉ⣲䜢ྵ 䜐ᮦᩱ䛻䛴䛔䛶䠈㻺㻾㻳䛚䜘䜃㻌 㻺㻾㻳㻙㻯㼀䜢ᛂ⏝䛧䠈䝸䝏䜴 䝮䜔Ỉ⣲䛾ື䛝䜢ྍど䛷䛝䜛䛣䛸䜢♧䛧䛯䠊᭦䛻䠈䛭䛾 ⛣ື㔞䜔⛣ືᶵᵓ䜢ᐃ㔞ⓗ䛻᳨ウ䛩䜛㝿䛻䜒༑ศᙺ❧ 䛴䜒䛾䛷䛒䜛䛣䛸䜢♧䛫䛯䛾䛷䛿䛺䛔䛛䛸ᛮ䜟䜜䜛䠊䛧䛛 䛧䠈ᚓ䜙䜜䛯ᙳീ䛿ΰᅾ䛩䜛䛾ᡂศඖ⣲䛾ᙳ㡪䜢ཷ 䛡䜛䛣䛸䜒᫂䜙䛛䛷䛒䜛䠊≉䛻䠈᩿ᒙീ䛾⃰ᗘ䝥䝻䝣䜯䜲 䝹䛷䛿୍⯡ⓗ䛻䝜䜲䝈䛜ᙉ䛩䛞䜛䛯䜑䠈䜘䜚⢭ᐦ䛺ᩘᏛ ⓗゎᯒ䜢⾜䛖䛣䛸䛜䛷䛝䛺䛔䛣䛸䛿ၥ㢟䛷䛒䜛䠊ᢞᙳീ䛾 䝜䜲䝈㍍ῶ䠄ᙳ䛾㝿䛾୰ᛶᏊ௨እ䛾ᨺᑕ⥺䜢㝖䛩 䜛䛣䛸䠈䝜䜲䝈㝖ཤ䛾䛯䜑䛾䝣䜱䝹䝍䛾᭱㐺䠈䝞䝑䜽䜾䝷 䜴䞁䝗䛾ฎ⌮䛺䛹䠅䜔᩿ᒙീᵓᡂ䛾㝿䛾␚䜏㎸䜏㛵 ᩘ䛾᭱㐺䠈䛺䛹䛻ὀព䛧䛶᳨ウ䛧䛶䝜䜲䝈䛾ᑡ䛺䛔Ⰻ ㉁䛺⏬ീ䜢ᚓ䜛䛣䛸䛜䛷䛝䜜䜀䠈⦓ᐦ䛺ゎᯒ䛜ྍ⬟䛻䛺 䜛䛿䛪䛷䛒䜛䠊㻌 㻌 㸷㸬 ⤖ㄒ 㻌 㻌 㻌 ᭱㏆䛾ሗ࿌䜢ᇶ䛻䠈⌧ᅾ䛹䛾䜘䛖䛺◊✲䛜㓟≀⣔䜲 䜸䞁ఏᑟయ䛻䛴䛔䛶⾜䜟䜜䛶䛔䜛䛛䛻䛴䛔䛶㏙䜉䛯䠊 ◊✲┠ⓗ䛜⣧⢋䛻䜰䜹䝕䝭䝑䜽ⓗ䛷䛒䜜䜶䞁䝆䝙䜰䝸䞁 䜾ⓗ䛷䛒䜜䚸䛣䜜䜎䛷䛻䛺䛔᪂䛧䛔䜲䜸䞁ఏᑟయ䜢ྜᡂ 䛧䜘䛖䛸䛛䠈䛒䜛䛔䛿ᑟ㟁ᛶ䜢ᨵၿ䛧䜘䛖䛸䛩䜛ື䛝䛿 ᚋ䜒┈䚻ᙉ䛟䛺䛳䛶䛟䜛䛸ᛮ䜟䜜䜛䠊䛣䜜䛻㝿䛧䛶䛹䛾䜘䛖 䛺ᵓ㐀䛾䜒䛾䜢స䜜䜀䛹䛾䜘䛖䛺ᑟ㟁ᛶ䛾䜒䛾䛜ᚓ䜙䜜 䜛䛛᫂☜䛻䛧䛯䛔䜒䛾䛷䛒䜛䠊䛣䛾䜘䛖䛺䛣䛸䜢ྍ⬟䛻䛩 䜛䛯䜑䛻䠈ᮏ✏䛜ᑡ䛧䛷䜒ᙺ䛻❧䛶䜀ᖾ䛔䛸ᛮ䛖䠊ᚋ 䛾⤖ᬗᵓ㐀䛒䜛䛔䛿ᑟ㟁ᶵᵓ䜢ྵ䜑䛯ᇶ♏◊✲䠈ᛂ⏝ ◊✲䛾䛥䜙䛺䜛Ⓨᒎ䜢䛔䛻ᮇᚅ䛩䜛䜒䛾䛷䛒䜛䠊䛯䛰䛧 ᮏ✏䛻㛵ಀ䛩䜛䛛䛹䛖䛛䛿ู䛸䛧䛶䠈䜶䝛䝹䜼䞊㛵㐃◊ ✲䜢⾜䛖ሙྜ䠈᭱⤊ⓗ䛻ᚓ䜙䜜䜛䜉䛝䠍༢䛾䜶䝛䝹䜼 䞊䜢㐀䜛䛾䛻䝖䞊䝍䝹䛷䛿㻝༢௨ୖ䠈㻞༢㻟༢䛾䜶 䝛䝹䜼䞊䜢⏝䛔䛶䛔䛶䜒䠈༢䛻䝞䜲䜸䛸䛛ኴ㝧ග䠈㢼ຊ 䛺䛹䛸䛔䛖䜘䛖䛺ྡ๓䛜䛒䜛䛸䠈䛣䜜䛰䛡䛷䝃䝇䝔䜲䝘䝤䝹 䛸䛛䜾䝸䞊䞁䛷䛒䜚䚸⥲䛶ຠ⋡ⓗ䛰䛸䛩䜛䜘䛖䛺ุ᩿䛻ᇶ 䛵䛟◊✲䛿㑊䛡䛶䜋䛧䛔䜒䛾䛷䛒䜛䠊 ཧ⪃ᩥ⊩
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