- Metal-support interaction and the effect of second metal addition in supported metal catalyst

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-

Metal-support interaction and the effect of second metal addition in supported metal

catalyst

Daiki MUKAI

2014 12

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F T

6 1 2 3

4 5

6 1

2 N i

N i N i-

H

2

N i / L a

2

O

3

N i/ - A l

2

O

3

N i/ L a AlO

3

7 7 3 K 7 2 3 K 6 7 3 K N i/ M g O

8 2 3 K M g O L a

2

O

3

N i

N i O

x

- A l

2

O

3

L a A l O

3

N i

Ni O

x

Ni O

x

N i

Ni / L a AlO

3

P d N i / L a AlO

3

6 7 3 K

H

2

P d / L aA lO

3

No . 1

(3)

C H

4

N iO

x

P d

C H

4

Ni

⁰

C o N i/ - A l

2

O

3

H

2

C o 7 2 3 K 5 9 8 K

X R D S T E M - ED X H

2

N i - C o

3 ( )

P t

P t / L a

0 . 8

S r

0 . 2

A l O

2 . 9

P t / L a

0 . 7

S r

0 . 3

A l O

2 . 8 5

1 0 2 3 K P t / - A l

2

O

3

P t - A l

2

O

3

P t

L a

0 . 8

S r

0 . 2

A l O

2 . 9

L a

0 . 7

S r

0 . 3

A l O

2 . 8 5

P t

H e X R D X P S

X A FS P t / L a

0 . 8

S r

0 . 2

A l O

2 . 9

P t / L a

0 . 7

S r

0 . 3

A l O

2 . 8 5

P t

O

s

P t - O

s

H

2

P t - O

s

P t

4 N i

N i L a

0 . 7

S r

0 . 3

A l O

3 -

N i

N i / L a

0 . 7

S r

0 . 3

A l O

3 -

8 7 3 K N i / L a Al O

3

N i/ - A l

2

O

3

1 8

O

Ni / L a

0 . 7

S r

0 . 3

A l O

3 -

8 7 3 K L a

0 . 7

S r

0 . 3

A l O

3 -

L a

0 . 7

Sr

0 . 3

A l O

3 -

(4)

Ni L a

0 . 7

S r

0 . 3

A l O

3 -

Ni / L a AlO

3

9 7 3 K

X R D X PS L a S r

r e d o x N i / L a

0 . 7

S r

0 . 3

A l O

3 -

N i / L a AlO

3

5 4

N i / L a

0 . 7

S r

0 . 3

A lO

3 -

P t

P t P t / N i /L a

0 . 7

S r

0 . 3

A l O

3 -

N i/ L a

0 . 7

S r

0 . 3

A l O

3 -

3 h N i/ L a

0 . 7

S r

0 . 3

A l O

3 -

P t / Ni P t N i

P t N i

P t / Ni / L a

0 . 7

S r

0 . 3

A l O

3 -

N i / P t / L a

0 . 7

S r

0 . 3

A l O

3 -

P t - Ni / L a

0 . 7

S r

0 . 3

A l O

3 -

N i / LS AO N i / Pt / La

0 . 7

S r

0 . 3

A lO

3 -

N i / L a

0 . 7

S r

0 . 3

A l O

3 -

P t

X P S N i P t

P t N i P t Ni

N i P t / N i

P t / Ni / L a

0 . 7

S r

0 . 3

A l O

3 -

N i / Pt / La

0 . 7

S r

0 . 3

A lO

3 -

( P t + N i) / Al P t / Ni

P t / Ni / L a

0 . 7

S r

0 . 3

A l O

3 -

P t N i

6 2 5

No . 3

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.

1

2014 12

1.

1. ( )

-Al2O3

, in press.

Daiki Mukai,Yuji Kondo, Toshinari Eda, Shuhei Ogo, Yasushi Sekine 2. ( )

Effect of catalyst structure on steam reforming of toluene over Ni/La0.7Sr0.3AlO3- catalyst , in press.

Kento Takise, Masaya Imori, Daiki Mukai, Shuhei Ogo, Yukihiro Sugiura, Yasushi Sekine 3. ( )

Effect of hydrocarbon structure on steam reforming over Ni/perovskite catalyst , in press.

Takuma Higo, Takashi Hashimoto, Daiki Mukai, Satoshi Nagatake, Shuhei Ogo, Yukihiro Sugiura, Yasushi Sekine

4. ( )

0.7Sr0.3AlO3- catalyst on steam reforming of toluene for , 471, 157-164 (2014).

Daiki Mukai, Yuki Murai, Takuma Higo, Shuhei Ogo, Yukihiro Sugiura, Yasushi Sekine 5. ( )

IR study for elucidating reaction mechanism of toluene steam reforming over Ni/La0.7Sr0.3AlO3-

, 466, 190-197 (2013).

Daiki Mukai, Yuki Murai, Takuma Higo, Satoshi Tochiya, Takashi Hashimoto, Yukihiro Sugiura, Yasushi Sekine

6. ( )

0.7Sr0.3AlO3- catalyst for hydrogen production by steam reforming of toluene

, 464-465, 78-86 (2013).

Daiki Mukai, Satoshi Tochiya, Yuki Murai, Masaya Imori, Yukihiro Sugiura, Yasushi Sekine 7. ( )

0.7Sr0.3AlO3- catalyst for steam reforming of model aromatic , 38, 7822-7829 (2013).

Yukihiro Sugiura, Daiki Mukai, Yuki Murai, Satoshi Tochiya, Yasushi Sekine 8. ( )

ysts supported over La1-xSrxAlO3-0.5x perovskite for , 458, 71-81 (2013).

Daiki Mukai, Yoshiyuki Izutsu, Yasushi Sekine

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.

2

2.

9. ( )

ion over Ni/LaAlO3

, 56 (3), 156-164 (2013).

Daiki Mukai, Toshinari Eda, Keisuke Tanaka, Eiichi Kikuchi, Yasushi Sekine 10. ( )

ction over Ni/La0.7Sr0.3AlO3-

, 453, 60-70 (2013).

Daiki Mukai, Satoshi Tochiya, Yuki Murai, Masaya Imori, Takashi Hashimoto, Yukihiro Sugiura, Yasushi Sekine

11. ( )

-supporte , 451, 160-167 (2013).

Yasushi Sekine, Daiki Mukai, Yuki Murai, Satoshi Tochiya, Yoshiyuki Izutsu, Kei Sekiguchi, Naomi Hosomura, Hirohisa Arai, Eiichi Kikuchi, Yukihiro Sugiura

1. La0.7Sr0.3AlO3-

40 2014. 11

2.

Ni/LSAO-

248^th American Chemical Society National Meeting Exposition (2014.8, San Francisco, USA)

Daiki Mukai, Kento Takise, Masaya Imori, Shuhei Ogo, Yukihiro Sugiura, Yasushi Sekine

3. Ni/La0.7Sr0.3AlO3- Pt

113 B 2014.3,

4. Ni-

112 2013.9,

5. 0.7Sr0.3AlO2.85 catalyst: role of lattice oxygen of 245^th American Chemical Society National Meeting Exposition (2013.4, New Orleans, USA)

Daiki Mukai, Satoshi Tochiya, Yuki Murai, Masaya Imori, Takashi Hashimoto, Yukihiro Sugiura, Yasushi Sekine

6. pported Ni catalysts

10^thNatural Gas Conversion Symposium (2013.3, Doha, Qatar) Daiki Mukai, Toshinari Eda, Keisuke Tanaka, Yasushi Sekine

(7)

.

3

( )

3.

7. Pt/LaSrAlOx

42 2012.10,

8. Ni/ -Al2O3

110 2012.9,

9. 0.7Sr0.3AlO3-x

15^thInternational Congress on Catalysis 2012 (2012.6, Munich, Germany) Daiki Mukai, Yuki Murai, Satoshi Tochiya, Eiichi Kikuchi, Yasushi Sekine 10.

61 2012.5,

1. Low temperature ignition for partial oxidation of methane by Co addition to Ni/ -Al2O3

catalyst

The 6th Asia-Pacific Congress on Catalysis (2013.10, Taipei, Taiwan) Daiki Mukai, Toshinari Eda, Yuji Kondo, Yasushi Sekine

2. Pt/La1-xSrxAlO3-0.5x

111 2013.3,

1.

, 92 (11), 1028-1033 (2013).

2.

, 55 (3), 130-135 (2013)