6.2. ᐇ㦂᪉ἲ
6.3.5. film seeding ࡢ⌧ᛶ᭷⏝ᛶ
seeding ᕤ⛬ࡢ⌧ᛶࡣࠊࢮ࢜ࣛࢺ⭷ࡢྜᡂᑐࡋ࡚㔜せ࡞ၥ㢟࡛࠶ࡿࠋࡑࡇ࡛ࠊfilm
seeding ࡢ⌧ᛶࢆ☜ࡵࡿࡓࡵࠊᮏ〇ἲࢆ⏝࠸࡚ྠᵝࡢ᮲௳࡛ silicalite-1 ⭷ࢆㄪ〇ࡋࠊ
ᚓࡽࢀࡓ⭷ࡢPVᛶ⬟ࢆẚ㍑ࡋࡓࠋTable 6.2♧ࡍࡼ࠺ࠊㄪ〇ࡋࡓ࡚ࡢ⭷࡛ࠊྠᵝࡢ㧗
࠸ศ㞳ᛶ⬟ࢆ♧ࡋࠊᮏ◊✲ࡢfilm seeding ἲࡣࢩࣥࣉ࡛ࣝ⌧ᛶࡀ㧗ࡃࠊ㧗ᛶ⬟silicalite-1
⭷ࡢㄪ〇ࡗ࡚᭷⏝࡛࠶ࡿࡇࡀ♧ࡉࢀࡓࠋ
ࡉࡽࠊࡢᨭᣢయୖࡢfilm seedingࡢ᭷⏝ᛶࢆ᳨ウࡋࡓࠋFig. 6.9seeding๓ᚋࡢ
࣑ࣝࢼᨭᣢయ⾲㠃ࡢSEMീࢆ♧ࡍࠋFig. 6.9 a, bࡽࡶศࡿࡼ࠺ࠊᅇ⏝ࡋࡓ࣑ࣝ
ࢼᨭᣢయ㸦㛗ࡉ㸸80 mm, እᚄ㸸12 mm, ෆᚄ㸸9 mm, ⣽Ꮝᚄ㸸1.4 μm, ✵㝽⋡㸸38%, ࢽࢵ
࢝ࢺ࣮〇㸧ࡣࠊ✀⤖ᬗࡢ⢏Ꮚᚄࡼࡾࡶࡁ࡞1 μm௨ୖࡢ⣽Ꮝࢆ᭷ࡋࠊ⾲㠃ࡢพฝࡶࡁ࠸ࠋ
ࡋࡋࠊfilm seedingᚋࡢᨭᣢయ⾲㠃ࡣࠊᆒ୍࡛㐃⥆ⓗ࡞✀⤖ᬗᒙ࡛そࢃࢀ࡚࠸ࡓ㸦Fig.
6.9 c, d㸧ࠋࡇࡢࡇࡽࠊᮏ◊✲ࡢseeding᪉ἲࡣࠊ1ᅇࡢseedingࢫࢸࢵࣉࡢࡳ࡛ࠊ✀⤖ᬗ
ࡢ⢏ᚄࡼࡾࡶࡁ࡞࣐ࢡࣟᚄࢆ᭷ࡋࠊ⾲㠃⢒ࡉࡀࡁ࡞ᨭᣢయୖᑐࡋ࡚ࡶᆒ୍࡛㐃⥆ⓗ
࡞✀⤖ᬗᒙࡢᙧᡂࡀྍ⬟࡛࠶ࡿࡇࡀศࡗࡓࠋ
Table 6.1♧ࡍࡼ࠺ࠊdip coating࠾ࡼࡧrub coatingࡀsilicalite-1⭷ྜᡂᑐࡋ࡚ᗈࡃ⏝
࠸ࡽࢀ࡚࠸ࡿࡀࠊࡇࢀࡽࡢ᪉ἲࡣᨭᣢయୖᆒ୍࡛㐃⥆ⓗ࡞✀⤖ᬗᒙࢆ1ᅇࡢseedingᕤ⛬
࡛⌧ᛶⰋࡃㄪ〇ࡍࡿࡇࡣ㞴ࡋ࠸ࠋ✀⤖ᬗᒙࢆ⌧ᛶⰋࡃࠊㄪ〇ฟ᮶ࡿࡇࡣࠊ㧗ᛶ⬟
࡞ࢮ࢜ࣛࢺ⭷ࢆᕤᴗⓗᛂ⏝ࡍࡿୖ࡛ᚲせྍḞ࡞せ⣲࡞ࡿࠋࡑࡢࡓࡵࠊᮏ◊✲࡛㛤
Ⓨࡋࡓࢩࣥࣉ࡛ࣝ㧗࠸⌧ᛶࢆ♧ࡍ᪂つ࡞✀⤖ᬗሬᕸ᪉ἲ࡛࠶ࡿ film seeding ࡣࠊᚑ᮶ࡢ
seeding᪉ἲ᭰ࢃࡿ᪂ࡓ࡞seedingἲ࡞ࡿྍ⬟ᛶࢆ࠸⛎ࡵ࡚࠾ࡾࠊ㧗ᛶ⬟ࢮ࢜ࣛࢺ
⭷ࡢㄪ〇ᑐࡋ࡚㨩ຊⓗ࡞᪉ἲ࡛࠶ࡿࠋ
131
Table 6.2 film seedingࢆ⏝࠸࡚ྠ᮲௳࡛ㄪ〇ࡉࢀࡓsilicalite-1⭷ࡢPVᛶ⬟
Sample No. Separation Factor Flux [kg m-2 h-1] PSI
M1 117 3.02 350
M2 120 3.16 376
M3 119 3.07 362
M4 115 3.21 366
PV conditions: 10 wt.% EtOH solution at 323 K
Fig. 6.9. ࣑ࣝࢼ⟶≧ᨭᣢయ㸦a, b㸧࠾ࡼࡧ✀⤖ᬗሬᕸᨭᣢయ㸦c, d㸧⾲㠃ࡢSEMീ
132
6.4. ⤖ゝ
㧗ᛶ⬟࡞silicalite-1⭷ࡣࠊࢮ࢜ࣛࢺศᩓࣇ࣒ࣝࢆ⏝࠸ࡓ᪂つ࡞✀⤖ᬗሬᕸ᪉ἲ㸦film
seeding㸧ࢆ⏝࠸ࡿࡇ࡛ࠊከᏍ㉁ࡢࢩࣜ࢝ᨭᣢయୖㄪ〇ࡉࢀࡓࠋfilm seeding ࡣࠊ1ᅇࡢ
seeding ᕤ⛬࡛ᆒ୍࡛㐃⥆ⓗ࡞✀⤖ᬗᒙࢆᙧᡂࡍࡿࡇࡀྍ⬟࡛࠶ࡾࠊ㧗࠸ศ㞳ᛶ⬟ࢆ♧ࡍ
⭷ࢆ⌧ᛶ㧗ࡃㄪ〇ࡍࡿࡇࡀ࡛ࡁࡿࠋᮏ〇ἲࢆ⏝࠸࡚ㄪ〇ࡉࢀࡓ⭷ࡣࠊᚑ᮶ࡢ᪉ἲ࡛ㄪ
〇ࡉࢀࡓ⭷ẚ㍑ࡋ࡚ࠊ࢚ࢱࣀ࣮ࣝ/Ỉศ㞳ᑐࡋ࡚ࠊ㠀ᖖ㧗࠸PVᛶ⬟㸦ศ㞳ಀᩘ120ࠊ
㏱㐣ὶ᮰3.16 kg m−2 h−1㸧ࢆ♧ࡋࡓࠋࡇࡢ᪂つ࡞seedingἲࡣࠊࡉࡲࡊࡲ࡞✀㢮ࡢࢮ࢜ࣛ
ࢺࢆᨭᣢయࡢ⣽Ꮝᚄࡸ⾲㠃⢒ࡉ㛵ಀ࡞ࡃࠊᆒ୍ࡘ㐃⥆ⓗ✀⤖ᬗᒙࢆᙧᡂࡉࡏࡿࡇ
ࡀྍ⬟࡛࠶ࡿࠋࡲࡓࠊᨭᣢయୖࡢ✀⤖ᬗࡢሬᕸ㔞ࡶ࣏࣐࣮ࣜ୰ࡢࢮ࢜ࣛࢺࡢῧຍ 㔞ࡼࡾㄪᩚྍ⬟࡛࠶ࡿࠋࡑࡢࡓࡵࠊᕤᴗつᶍ࡛ࡢ⭷ྜᡂᑐࡋ࡚ࠊࡇࡢ᪉ἲࡀ⏝ࡉࢀ
ࢀࡤࠊᚑ᮶ἲẚ㍑ࡋ࡚ࠊᡭ㡰ࡀ⡆౽࡛࠶ࡾࠊ㧗࠸ศ㞳ᛶ⬟ࢆ᭷ࡍࡿࢮ࢜ࣛࢺ⭷ࢆ⌧
ᛶⰋࡃ〇㐀࡛ࡁࡿࡓࡵࠊࢮ࢜ࣛࢺ⭷ࡢ〇㐀ࢥࢫࢺࢆᖜపୗࡉࡏࡿࡇࡀᮇᚅࡉࢀ
ࡿࠋ ࡉࡽࠊࡇࡢ᪉ἲࡢ༢⣧ࡉ࠾ࡼࡧ᭷ຠᛶࢆ⪃៖ࡍࡿࠊᨭᣢయୖࡢࢮ࢜ࣛࢺ⤖ᬗ ࡢሬᕸ┠ⓗࡔࡅ࡛ࡣ࡞ࡃࠊࡉࡲࡊࡲ࡞ᅛయ⾲㠃ୖ⢏Ꮚࢆሁ✚ࡍࡿࡓࡵࡢ᪉ἲࡋ࡚ࡁ
࡞ྍ⬟ᛶࢆ᭷ࡋ࡚࠸ࡿࠋ
133
6.5. ཧ⪃ᩥ⊩
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136
➨
➨ 7 ❶ ⥲ᣓ
ᮏ◊✲࡛ࡣࠊ᭷ᶵ≀/Ỉΰྜᾮࡢศ㞳ྥࡅࡓ㧗ᛶ⬟ silicalite-1 ⭷ࡢྜᡂࢆ┠ᣦࡋࠊᨭᣢ యୖࡢ✀⤖ᬗᒙࡢ≉ᛶ࠾ࡼࡧᨭᣢయ≉ᛶࡢᙳ㡪ࡘ࠸᳨࡚ウࡍࡿࡶࠊᕤᴗⓗ࡞ᛂ⏝
ࢆ┠ᣦࡋࡓ᪂つ࡞〇⭷ἲ࠾ࡼࡧ✀⤖ᬗሬᕸ᪉ἲࡢ㛤Ⓨࢆ⾜࠸ࠊ௨ୗࡢ▱ぢࢆᚓࡓࠋ
➨2❶ silicalite-1⭷ྜᡂ࠾ࡅࡿ✀⤖ᬗࡢSi/Alẚࡢᙳ㡪
silicalite-1⭷ࡣ୍⯡ḟᡂ㛗ἲࡼࡗ࡚ㄪ〇ࡉࢀࠊᨭᣢయୖࡢ✀⤖ᬗᒙࡢ≉ᛶࡣ᭱⤊ⓗ
࡞⭷ࡢศ㞳ᛶ⬟ࢆỴࡵࡿ㔜せ࡞せ⣲࡞ࡿࡇࡀࢃࡗ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ✀⤖ᬗࡋ
࡚␗࡞ࡿSi/Alẚࢆ᭷ࡍࡿMFIᆺࢮ࢜ࣛࢺࢆ⏝࠸ࡿࡇ࡛silicalite-1⭷ࢆྜᡂࡋࠊ✀⤖ᬗ
ࡢSi/Alẚ࠾ࡼࡧሬᕸ㔞ࡀࠊ࢚ࢱࣀ࣮ࣝ/Ỉ㸦ᡂศ⣔㸧ࠊ࢚ࢱࣀ࣮ࣝ/Ỉ/ࢥࣁࢡ㓟㸦୕ᡂศ⣔㸧
ΰྜᾮࡢศ㞳࠼ࡿᙳ㡪ࢆ᳨ウࡋࡓࠋᮏ◊✲࡛ᚓࡽࢀࡓsilicalite-1⭷ࡢศ㞳ᛶ⬟ࡣࠊ✀⤖
ᬗᒙࡢ≉ᛶ㸦Si/Al ẚ࠾ࡼࡧሬᕸ㔞㸧ࡁࡃ౫Ꮡࡋࡓࠋᡂศ⣔ࡢศ㞳࠾࠸࡚ࠊศ㞳ಀ
ᩘࡢୖ㝈್ࡣ⏝࠸ࡓ✀⤖ᬗࡢAlྵ᭷㔞ࡼࡗ࡚ỴᐃࡉࢀࠊAl㔞ࡀᑡ࡞࠸㧗࠸ศ㞳ಀᩘ
ࢆ♧ࡋࡓࠋࡲࡓࠊ୕ᡂศ⣔ࡢศ㞳࠾࠸࡚ࠊ✀⤖ᬗࡋ࡚Alࢆྵࡲ࡞࠸MFIᆺࢮ࢜ࣛࢺ
ࢆ⏝࠸ࡓሙྜࠊᡂศ⣔ẚ㍑ࡋ࡚ศ㞳ಀᩘࡣࡁࡃపୗࡋࡓࠋࡋࡋࠊAlྵ᭷ࡢMFIᆺ ࢮ࢜ࣛࢺ✀⤖ᬗࢆ⏝࠸ࡓሙྜࠊศ㞳ಀᩘࡣྥୖࡋࡓࠋࡇࢀࡽࡢ⤖ᯝࡣࠊsilicalite-1⭷ࡢྜ
ᡂ⏝࠸ࡿ✀⤖ᬗࡢAl㔞ࡣྛ✀ΰྜᾮࡢศ㞳ᑐࡋ࡚ࠊ␗࡞ࡿᙳ㡪ࢆ♧ࡋࠊ✀⤖ᬗᒙ⏤᮶ ࡢࢮ࢜ࣛࢺᒙࡀࡇࢀࡽࡢᾮ┦ศ㞳ᑐࡍࡿ࡞ศ㞳ᒙ࡞ࡿࡇࡀ᫂ࡽ࡞ࡗࡓࠋࡲ
ࡓࠊᮏ◊✲࡛Alྵ᭷MFIᆺࢮ࢜ࣛࢺ✀⤖ᬗࢆ⏝࠸࡚ㄪ〇ࡉࢀࡓsilicalite-1⭷ࡣࠊ᭷ᶵ㓟 Ꮡᅾୗ࠾࠸࡚ࡶ࢚ࢱࣀ࣮ࣝࡢࡳࢆ㧗⃰ᗘ࡛ᅇ࡛ࡁࠊ᪤ሗẚ㍑ࡋඃࢀ࡚࠸ࡿࡇࢆ♧
ࡋࡓࠋ
➨3❶ silicalite-1⭷ྜᡂ࠾ࡅࡿ✀⤖ᬗሬᕸ㔞ࡢᙳ㡪
silicalite-1⭷ࡢྜᡂ࠾࠸࡚ࠊ࣑ࣝࢼᨭᣢయࢆ⏝࠸ࡓሙྜࠊỈ⇕ฎ⌮ᨭᣢయࡽAl
ࡀ⁐ฟࡋࠊ⭷୰Alࡀྲྀࡾ㎸ࡲࢀࡿࡇ࡛⭷ᒙࡢ Si/AlࡀపୗࠊࡘࡲࡾỈᛶࡀపୗࡍࡿ
ࡇࡀ▱ࡽࢀ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ⭷ྜᡂ⏝࠸ࡿ✀⤖ᬗᒙࡢ≉ᛶࡀᨭᣢయࡽࡢAlࡢ⁐
ฟᑐࡋ࡚ࡢࡼ࠺࡞ᙳ㡪ࢆ࠼ࡿࢆ᳨ウࡋࡓࠋࡑࡢ⤖ᯝࠊᨭᣢయୖࡢ✀⤖ᬗ㔞ሬᕸ ࡢቑຍࠊࡘࡲࡾᨭᣢయ⾲㠃ࢆ✀⤖ᬗᒙ࡛⦓ᐦࡘ㐃⥆ⓗそ࠺ࡇࡼࡗ࡚ࠊ⭷ᒙࡢ Si/Al ẚࡣྥୖࡋࠊỈᛶࡢ㧗࠸⭷ࡢྜᡂࡀྍ⬟࡛࠶ࡿࡇࡀࢃࡗࡓࠋࡇࡢ⤖ᯝࡼࡾࠊᨭᣢయ
ୖࡢᐦ࡛㐃⥆ⓗ࡞✀⤖ᬗᒙࡣࠊḞ㝗࡞ࡃ㐃⥆ⓗ࡞⭷ᒙࡢᙧᡂᑐࡋ࡚᭷ຠ࡞ࡔࡅ࡛࡞ࡃࠊ
137
Ỉ⇕ฎ⌮ᨭᣢయྜᡂࢤࣝࡢ᥋ゐࢆ㜵ࡄಖㆤᒙࡋ࡚ാࡁࠊᨭᣢయࡽࡢAlࡢ⁐ฟ
ࢆᢚไࡍࡿຠᯝࡶ࠶ࡿࡇࢆ♧ࡋࡓࠋ᭱㐺࡞᮲௳ୗ࡛ྜᡂࡋࡓ⭷ࡣࠊ㧗࠸Ỉᛶࢆ♧ࡋࠊ
࢚ࢱࣀ࣮ࣝ/Ỉ࠾ࡼࡧ㓑㓟/Ỉΰྜᾮࡢศ㞳ᑐࡋ࡚ࠊ㧗࠸ศ㞳ᛶ⬟ࢆ♧ࡋࠊ≉㓑㓟/Ỉศ㞳
࡛ࡣࠊ᪤ሗẚ㍑ࡋ࡚᭱ࡶ㧗࠸ศ㞳ಀᩘࢆ♧ࡋࡓࠋ
➨4❶ ࢩࣜ࢝ᨭᣢయୖࡢ㧗ᛶ⬟silicalite-1⭷ࡢྜᡂ
silicalite-1⭷ྜᡂ࠾࠸࡚ࠊ࣑ࣝࢼᨭᣢయࡢ⁐ゎࡣ⭷ᛶ⬟ࡢపୗࢆᘬࡁ㉳ࡇࡋ࡚࠸ࡓࠋ
ࡑࡇ࡛ᮏ◊✲࡛ࡣࠊ⣧ࢩ࡛ࣜ࢝ᵓᡂࡉࢀࡿ᪂つ࡞ࢩࣜ࢝ᨭᣢయࢆ⏝࠸࡚ࠊsilicalite-1⭷ࡢྜ
ᡂࢆ⾜ࡗࡓࠋࡑࡢ⤖ᯝࠊࢩࣜ࢝ᨭᣢయࢆ⏝࠸࡚ࡶsilicalite-1⭷ࡢྜᡂᡂຌࡋࡓࠋࡲࡓࠊỈ
⇕ฎ⌮ࢩࣜ࢝ᨭᣢయࡽࢩࣜ࢝ࡀ⁐ゎࡋࠊࡑࢀࡀᨭᣢయୖࡢsilicalite-1✀⤖ᬗࡢᡂ㛗
ຠᯝⓗാࡃࡇ࡛ࠊ⦓ᐦ࡞ࢮ࢜ࣛࢺศ㞳ᒙࡀᙧᡂࡍࡿࡇࡀࢃࡗࡓࠋࡉࡽࠊ⏝࠸
ࡓࢩࣜ࢝ᨭᣢయ⮬㌟ࡢ㏱㐣ᢠࡀప࠸ࡓࡵࠊᚓࡽࢀࡓ⭷ࡣ࢚ࢱࣀ࣮ࣝ/Ỉศ㞳ᑐࡋ࡚ࠊศ 㞳ᛶ࣭㏱㐣ᛶࡶඃࢀࠊ᪤ሗẚ㍑ࡋ࡚᭱ࡶ㧗࠸ᛶ⬟ࢆ♧ࡋࡓࠋࡇࡢ⤖ᯝࡼࡾࠊࢩࣜ࢝ᨭ ᣢయࡣ࢚ࢱࣀ࣮ࣝ/Ỉศ㞳ࡢࡓࡵࡢ silicalite-1 ⭷ࡢྜᡂᑐࡋ࡚ࠊ᭷ຠ࡞ᨭᣢయ࡛࠶ࡿࡇ
ࡀ᫂ࡽ࡞ࡗࡓ
➨5❶ Gel-free steam-assisted conversionἲࡼࡿsilicalite-1⭷ࡢྜᡂ
silicalite-1⭷ྜᡂࡢࢇࡣỈ⇕ྜᡂἲࢆ⏝࠸ࡓḟᡂ㛗ἲࡼࡗ࡚⾜ࢃࢀ࡚࠸ࡿࠋࡋ
ࡋࠊࡇࡢࡼ࠺࡞Ỉᛶࢤࣝࢆ⏝࠸ࡓ〇⭷ἲࡣࠊᡭ㡰ࡀ↹㞧࡛࠶ࡾࠊ〇⭷ࡿࢥࢫࢺࡀ 㧗ࡃࠊᏛ⸆ရࢆ㔞ᾘ㈝ࡋࠊᗫᲠࡍࡿ࡞⎔ቃ㈇Ⲵࡀࡁ࠸ࡇࡀၥ㢟Ⅼ࡞ࡗ࡚࠸
ࡿࠋࡑࡇ࡛ࠊᮏ◊✲࡛ࡣࠊỈᛶࢤࣝࢆ⏝࠸࡞࠸〇⭷ἲ㸦Gel-free steam-assisted conversion;
Gel-free SAC㸧ࡢ㛤Ⓨࢆヨࡳࡓࠋᮏᡭἲ࠾࠸࡚ࠊ⭷ྜᡂ⏝࠸ࡿࢩࣜ࢝ᨭᣢయࡣ༢“ᨭᣢ య”ࡋ࡚࡛ࡣ࡞ࡃࠊᨭᣢయୖࡢsilicalite-1✀⤖ᬗᒙࡢ⭷ᒙࡢᡂ㛗ᚲせ࡞“ࢩࣜ࢝౪⤥※”
ࡋ࡚ࡶ⏝ࡋࠊᚲせ᭱ᑠ㝈ࡢᏛ⸆ရࡢ⏝࡛⭷ྜᡂࢆ⾜ࡗࡓࠋࡑࡢ⤖ᯝࠊỈᛶࢤࣝࢆ
⏝࠸࡞࠸᮲௳ୗ࡛ࡶࠊᨭᣢయࡽࡢࢩࣜ࢝※ࡢ౪⤥ࡼࡾࠊ✀⤖ᬗᒙࡀᡂ㛗ࡋᐦ࡛㐃⥆ⓗ
࡞⭷ᒙࡀᙧᡂࡉࢀࠊ㧗࠸ศ㞳ᛶ⬟ࢆ᭷ࡍࡿsilicalite-1⭷ࡢྜᡂࡀྍ⬟࡛࠶ࡿࡇࡀࢃࡗࡓࠋ ᮏᡭἲࡣࠊỈᛶࢤࣝࢆ⏝ࡋ࡞࠸ࡢ࡛ࠊᡭ㡰ࡣ࡞ࡾࢩࣥࣉ࡛ࣝ࠶ࡾࠊ⌧ᛶࡀ㧗ࡃࠊ〇
⭷せࡍࡿᏛཎᩱࢆᖜ๐ῶࡋࠊࡉࡽྜᡂᚋࡢ⭷ࡶᑡ㔞ࡢỈ࡛Ὑίࡀྍ⬟࡛࠶ࡿࠋ ࡋࡓࡀࡗ࡚ࠊࢩࣜ࢝ᨭᣢయࡢ⁐ゎࢆ⏝ࡋࡓGel-free SAC ἲࡣࠊ⡆౽࡛⤒῭ⓗ࡞〇⭷ἲ࡛
࠶ࡾࠊ⎔ቃࡸࡉࡋࡃࠊ⏘ᴗࢫࢣ࣮࡛ࣝࡢsilicalite-1⭷ࡢྜᡂᑐࡋ࡚㨩ຊⓗ࡞᪉ἲ࡛࠶ࡿ
ゝ࠼ࡿࠋ
138
➨6❶ ࢮ࢜ࣛࢺศᩓࣇ࣒ࣝࢆ⏝࠸ࡓ᪂つ✀⤖ᬗሬᕸ᪉ἲࡢ㛤Ⓨ
ᚑ᮶ࡢ✀⤖ᬗሬᕸ㸦seeding㸧᪉ἲࡣࠊᨭᣢయୖࡢ✀⤖ᬗᒙࡢ≉ᛶࡀᨭᣢయࡢ⣽Ꮝᚄ࠾ࡼ
ࡧ⾲㠃⢒ࡉࠊ✀⤖ᬗࡢࢧࢬࠊᙧ≧ᕥྑࡉࢀࠊᆒ୍࡛㐃⥆ⓗ࡞✀⤖ᬗᒙࢆ1ᅇࡢseeding ᕤ⛬࡛⌧ᛶ㧗ࡃㄪ〇ࡍࡿࡇࡣ㞴ࡋࡗࡓࠋࡑࡇ࡛ᮏ◊✲࡛ࡣࠊࢮ࢜ࣛࢺศᩓࣇࣝ
࣒ࢆ⏝࠸ࡓ᪂つ࡞✀⤖ᬗሬᕸ᪉ἲ㸦film seeding㸧ࡢ㛤Ⓨࢆ⾜ࡗࡓࠋfilm seedingࡣࠊ1ᅇࡢ
seeding ᕤ⛬࡛ᨭᣢయࡢ≉ᛶࡼࡽࡎᆒ୍࡛㐃⥆ⓗ࡞✀⤖ᬗᒙࢆ⌧ᛶ㧗ࡃᙧᡂࡍࡿࡇࡀ
ྍ⬟࡛࠶ࡾࠊḟᡂ㛗ἲࡼࡗ࡚ᚓࡽࢀࡓ⭷ࡣ㧗࠸ศ㞳ᛶ⬟ࢆ♧ࡋࡓࠋࡇࡢ᪂つ࡞ seeding
ἲ࡛࠶ࡿfilm seedingࡣࠊࡉࡲࡊࡲ࡞✀㢮ࡢࢮ࢜ࣛࢺࢆᨭᣢయࡢ⣽Ꮝᚄࡸ⾲㠃⢒ࡉ㛵ಀ
࡞ࡃࠊᆒ୍ࡘ㐃⥆ⓗ✀⤖ᬗᒙࢆᙧᡂࡉࡏࡿࡇࡀྍ⬟࡛࠶ࡿࠋࡲࡓࠊᨭᣢయୖࡢ
✀⤖ᬗࡢሬᕸ㔞ࡶ࣏࣐࣮ࣜ୰ࡢࢮ࢜ࣛࢺࡢῧຍ㔞ࡼࡾㄪᩚྍ⬟࡛࠶ࡿࠋࡑࡢࡓࡵࠊ ᕤᴗつᶍ࡛ࡢ⭷ྜᡂᑐࡋ࡚ࠊࡇࡢ᪉ἲࡀ⏝ࡉࢀࢀࡤࠊᚑ᮶ἲẚ㍑ࡋ࡚ࠊᡭ㡰ࡀ⡆౽
࡛࠶ࡾࠊ㧗࠸⭷ᛶ⬟ࢆ᭷ࡍࡿࢮ࢜ࣛࢺ⭷ࢆ⌧ᛶⰋࡃ〇㐀࡛ࡁࡿࡓࡵࠊࢮ࢜ࣛࢺ⭷
ྜᡂࡢ〇㐀ࢥࢫࢺࢆᖜపୗࡉࡏࡿࡇࡀᮇᚅࡉࢀࡿࠋ ࡉࡽࠊࡇࡢ᪉ἲࡢ༢⣧ࡉ࠾ࡼ
ࡧ᭷ຠᛶࢆ⪃៖ࡍࡿࠊᨭᣢయୖࡢࢮ࢜ࣛࢺ⤖ᬗࡢሬᕸ┠ⓗࡔࡅ࡛ࡣ࡞ࡃࠊࡉࡲࡊࡲ
࡞ᅛయ⾲㠃ୖ⢏Ꮚࢆሁ✚ࡉࡏࡿࡓࡵࡢ᪉ἲࡋ࡚ࡁ࡞ྍ⬟ᛶࢆ᭷ࡋ࡚࠸ࡿࠋ
ᚋࡢᒎᮃㄢ㢟
ࢮ࢜ࣛࢺ⭷ࡢศ㞳ᛶ⬟ࠊ⇕ⓗ࣭ᏛⓗᏳᐃᛶࡣࡢ≀㉁ࡼࡾඃࢀ࡚࠸ࡿࡀࠊᕤᴗࢆ
┠ᣦࡍ࠺࠼࡛ࡣࠊ〇⭷ᡭ㡰ࡢ⡆౽ࡉ⭷ࢥࢫࢺࡢపῶࠊ⌧ᛶࡢྥୖࡀᚲせ࡞ࡿࠋୖ㏙
ࡋࡓࠊᨭᣢయࡢ⁐ゎࢆ⏝ࡋࡓGel-free SAC ἲࡼࡿ〇⭷ࡣࠊ⡆᫆ᛶࠊࢥࢫࢺ๐ῶࠊ㧗࠸
⌧ᛶࢆ᭷ࡋࠊ᪂つ࡞✀⤖ᬗሬᕸᢏ⾡࡛࠶ࡿfilm seedingࡣࠊ㧗ᛶ⬟ࢮ࢜ࣛࢺ⭷ࢆ⌧ᛶ 㧗ࡃㄪ〇ࡍࡿࡇࡀྍ⬟࡛࠶ࡾࠊࡇࢀࡽࡢ᪉ἲࡣᏛ⾡㠃ࡢࡳ࡞ࡽࡎࠊᕤᴗⓗ౯್ࡀᴟࡵ࡚
㧗࠸⪃࠼ࡽࢀࡿࠋ㏆ᖺࡢࢮ࢜ࣛࢺ⭷◊✲ࡢᛴ㏿࡞Ⓨᒎࡼࡾ⭷ᛶ⬟ࡣ㣕㌍ⓗྥୖࡋ
࡚࠸ࡿࡀࠊᕤᴗⓗ࡞ᛂ⏝ࢆぢᤣ࠼ࡓ◊✲㛵ࡋ࡚ࡣᮍࡔ༑ศ࡞ሗ࿌ࡀ࠶ࡿࡣ࠸࠼ࡎࠊ ࡇࡢศ㔝࠾࠸࡚ࡉࡽ࡞ࡿ◊✲ࡀᚲせ࡛࠶ࡿࠋࡲࡓࠊࢮ࢜ࣛࢺ⭷ࡢᐇ⏝ྥࡅ࡚ࡢ⭷
ࣉࣟࢭࢫࡢ᭱㐺࡞ࠊࡲࡔࡲࡔྲྀࡾ⤌ࡴࡁㄢ㢟ࡀከࡃࠊ⏘Ꮫᐁࡢࡼࡾ୍ᒙࡢ༠ຊయไ ࡢᙉᮇᚅࡋࡓ࠸ࠋ
silicalite-1⭷ࡢྜᡂ㛵ࡋ࡚ࡶࠊ࠸ࡃࡘࡢㄢ㢟ࡀᣲࡆࡽࢀࠊ࠼ࡤ⭷ࡢ㓄ྥᛶࡢไᚚࠊ
ᵓ㐀つᐃࢆ⏝ࡋ࡞࠸⭷ྜᡂᡭ㡰ࡢ㛤Ⓨ࡛࠶ࡿࠋ⟶≧ᨭᣢయୖㄪ〇ࡉࢀࡓsilicalite-1⭷ ࡢࢇࡣc㍈㓄ྥ⭷࡛࠶ࡾࠊMFIᆺࢮ࢜ࣛࢺࡣ㏱㐣᭷࡞ࢫࢺ࣮ࣞࢺࢳࣕࣥࢿࣝࡀ b㍈᪉ྥྥ࠸࡚࠸ࡿࡓࡵࠊb㍈㓄ྥ⭷ࢆㄪ〇࡛ࡁࢀࡤࠊศ㞳ᛶࢆ⥔ᣢࡋࡓࡲࡲ㏱㐣ᛶࢆྥ
ୖࡍࡿࡇࡀ࡛ࡁࠊ⭷ࡢࢥࢫࢺࢆᖜపῶࡍࡿࡇࡀᮇᚅ࡛ࡁࡿࠋࡲࡓࠊ㧗౯࡞ᵓ㐀つ
139
ᐃࢆ⏝࠸ࡎ〇⭷࡛ࡁࢀࡤࠊཎᮦᩱ࠾ࡼࡧ↝ᡂᕤ⛬ࡿࢥࢫࢺࡀ๐ῶ࡛ࡁࡿࡔࡅ࡛
࡞ࡃࠊ↝ᡂ㛫⏕ࡌࡿྍ⬟ᛶࡢ࠶ࡿࢡࣛࢵࢡⓎ⏕ࡢᙳ㡪ࢆ⪃៖ࡍࡿᚲせࡀ࡞ࡃ࡞ࡿࠋࡇࡢ
ࡼ࠺ࠊ᭱ࡶከࡃࡢ◊✲ࡀ⾜ࢃࢀ࡚࠸ࡿsilicalite-1⭷㛵ࡋ࡚ࡶࠊࡲࡔࡲࡔ᳨ウࡍࡿ㡯┠ࡣ ከࡃࠊࡉࡽ࡞ࡿ◊✲ࡀᚲせ࡛࠶ࡿࠋ
140 ཧ ཧ⪃
ᮏㄽᩥࡢෆᐜࡣࠊୗグࡢᙧ࡛ሗ࿌ࡉࢀ࡚࠸ࡿࠋ
ㄽᩥ࡞
[1] K. Ueno, H. Negishi, M. Miyamoto, S. Uemiya, Y. Oumi, Effect of Si/Al ratio and amount of deposited MFI-type seed crystals on the separation performance of silicalite-1 membranes for ethanol/water mixtures in the presence of succinic acid, Microporous Mesoporous Mater. 267 (2018) 1-8.
[2] K. Ueno, Y. Horiguchi, H. Negishi, M. Miyamoto, S. Uemiya, A. Takeno, Y. Sawada, Y.
Oumi, Fabrication of high-performance silicalite-1 membrane by a novel seeding method using zeolite-dispersed polymer film, Microporous Mesoporous Mater. 261 (2018) 58-62.
[3] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ㏆Ụ㟹๎, ࢩࣜ࢝ᨭᣢయୖࡢ㧗ᛶ⬟ silicalite-1 ⭷ࡢ㛤Ⓨ, ࢮ
࢜ࣛࢺ35 (2) (2018) 52-63.
[4] H. Negishi, K. Ueno, Y. Oumi, Effect of Electroosmotic Flow on the Electrophoretic Deposition of Zeolite Powder on a Porous Alumina Support, ECS Transactions, 82 (1) (2018) 13-18.
[5] K. Ueno, H. Negishi, T. Okuno, T. Saito, H. Tawarayama, S. Ishikawa, M. Miyamoto, S.
Uemiya, Y. Sawada, Y. Oumi, A simple secondary growth method for the preparation of silicalite-1 membrane on a tubular silica support via gel-free steam-assisted conversion, J.
Membr. Sci. 542 (2017) 150-158.
[6] K. Ueno, H. Negishi, T. Okuno, T. Saito, H. Tawarayama, S. Ishikawa, M. Miyamoto, S.
Uemiya, Y. Sawada, Y. Oumi, High-performance silicalite-1 membranes on porous tubular silica supports for separation of ethanol/water mixtures, Sep. Purif. Technol. 187 (2017) 343-354.
[7] K. Ueno, H. Negishi, M. Miyamoto, S. Uemiya, Y. Oumi, Effect of deposition seed crystal amount on the α-Al2O3 support and separation performance of silicalite-1 membranes for acetic acid/water mixtures, Sep. Purif. Technol. 174 (2017) 57-65.
ᅜ㝿ᏛⓎ⾲
[1] K. Ueno, Y. Horiguchi, H. Negishi, T. Okuno, H. Tawarayama, S. Ishikawa, M. Miyamoto, S. Uemiya, A. Takeno, Y. Oumi, Fabrication of high-performance silicalite-1 membrane by a novel seeding method using zeolite-dispersed polymer film, International Symposium on Zeolites and Microporous Crystals (ZMPC) 2018, PB075, Yokohama, 2018.8.8.
141
[2] H. Negishi, K. Ueno, Y. Oumi, Effect of Electroosmotic Flow on the Electrophoretic Deposition of Zeolite Powder on a Porous Alumina Support, 6th International Conference on Electrophoretic Deposition (Electrophoretic Deposition VI), Gyeongju (South Korea), 2017.10.3.
[3] K. Ueno, H. Negishi, T. Okuno, T. Saito, H. Tawarayama, S. Ishikawa, M. Miyamoto, S.
Uemiya, Y. Oumi, High separation performance silicalite-1 membranes prepared on porous tubular silica support for separation of ethanol/water mixture, 7th International FEZA conference (FEZA2017), P187, Sofia (Bulgaria), 2017.7.5.
[4] K. Ueno, H. Negishi, M. Miyamoto, S. Uemiya, Y. Oumi, Preparation of Silicalite-1 Membrane on Porous α-Al2O3 Support with Electrophoretic Deposition as a Seeding Method for Separation of Acetic Acid/water Mixture, The 10th Conference of Aseanian Membrane Society (AMS10), Nara, PO2-081, 2016.7.27.
[5] K. Ueno, A. Kuzuya, M. Miyamoto, S. Uemiya, H. Negishi, T. Ikegami, Y. Oumi, Influence of the seed crystal in the synthesis of silicalite membrane, 6th International FEZA conference, Leipzig (Germany), PA3.50, 2014.9.9.
ᅜෆᏛⓎ⾲
[1] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎,
Gel-freeḟᡂ㛗ἲࢆ⏝࠸ࡓsilicalite-1⭷ྜᡂ࠾ࡅࡿ✀⤖ᬗࡢᙳ㡪, ᪥ᮏ⭷Ꮫ➨
40ᖺ, P-9S, ᮾி, 2018.5.8.
[2] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎,
Gel-freeḟᡂ㛗ἲࢆ⏝࠸ࡓSilicalite-1 ⭷ࡢྜᡂ᮲௳ࡢ᳨ウ, ➨33ᅇࢮ࢜ࣛࢺ◊
✲Ⓨ⾲, C12, ᒱ㜧, 2017.11.30.
[3] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, Gel-free ḟᡂ㛗ἲࡼࡿ Silicalite-1 ⭷ࡢྜᡂ, ⭷ࢩ࣏ࣥࢪ࣒࢘ 2017, P13S, ᐩᒣ, 2017.11.13.
[4] ୖ㔝ᜤᖹ, ᇼཱྀ⤖௨, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, Ṋ㔝᫂⩏, ㏆Ụ㟹๎, ࢮ࢜ࣛࢺศᩓ࣏࣐࣮ࣜࣇ࣒ࣝࢆ⏝࠸ࡓ᪂つ࡞✀⤖ᬗሬᕸ ᪉ἲࡼࡿ㧗ᛶ⬟Silicalite-1⭷ࡢྜᡂ, ᏛᕤᏛ➨49ᅇ⛅Ꮨ, PA122, ྡྂᒇ, 2017.9.20.
[5] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, ࢤࣝࣇ࣮ࣜ᮲௳ୗ࡛ࡢẼ㌿ἲࡼࡿ Silicalite-1 ⭷ࡢྜᡂࡑࡢศ㞳ᛶ⬟ホ౯,
᪥ᮏ⭷Ꮫ➨39ᖺ, 2B-2, ᮾி, 2017.5.27.
[6] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎,
142
Ẽ㌿ἲࢆ⏝࠸ࡓḟྜᡂࢤࣝࣇ࣮ࣜ᮲௳ୗ࡛ࡢ Silicalite-1 ⭷ࡢྜᡂ, ᏛᕤᏛ
➨82ᅇᖺ, PD321, ᮾி, 2017.3.8.
[7] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ᩪ⸨ᓫᗈ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ,
㏆Ụ㟹๎, Silicalite-1⭷ࡢྜᡂ࠾ࡼࡧᾐ㏱Ẽ≉ᛶホ౯, ➨32ᅇࢮ࢜ࣛࢺ◊✲Ⓨ⾲
, C16⥲, ᮾி, 2016.12.2.
[8] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ዟ㔝ᣅஓ, ᩪ⸨ᓫᗈ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ,
㏆Ụ㟹๎, ከᏍ㉁⟶≧ࢩࣜ࢝ᨭᣢయୖㄪ〇ࡋࡓSilicalite-1⭷ࡢ࢚ࢱࣀ࣮ࣝ/Ỉศ㞳 ᛶ⬟, ᏛᕤᏛ➨48ᅇ⛅Ꮨ, I 107, ᚨᓥ, 2016.9.6.
[9] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, Ỉᛶ Silicalite-1 ⭷ࢆ⏝࠸ࡓ᭷
ᶵ≀/Ỉศ㞳, ᪥ᮏ⭷Ꮫ➨38ᖺ, P-16S, ᮾி, 2016.5.10.
[10] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ᩪ⸨ᓫᗈ, ಥᒣ༤, ▼ᕝ┿, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎,
Silicalite-1 ⭷ࡢྜᡂ࠾ࡅࡿከᏍ㉁ᨭᣢయ≉ᛶࡢᙳ㡪, ᏛᕤᏛ➨ 81 ᅇᖺ,
ZCA313, ྿⏣, 2016.3.15.
[11] ୖ㔝ᜤᖹ, ᰿ᓊ ⚽அ, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, ỈᛶSilicalite-1⭷ࢆ⏝࠸ࡓ㓑
㓟/Ỉศ㞳, ᏛᕤᏛ➨47ᅇ⛅Ꮨ, E308, ᮐᖠ, 2015.9.11.
[12] ୖ㔝ᜤᖹ, ᰿ᓊ ⚽அ, ụୖᚭ, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, Silicalite ⭷ᛶ⬟ཬࡰ
ࡍྜᡂ᮲௳ࡢᙳ㡪, ᏛᕤᏛ➨80ᅇᖺ, XE304, ᮾி, 2015.3.21.
[13] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ụୖᚭ, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, Silicalite-㸯⭷ࡢྜᡂ᮲
௳ࡀศ㞳ᛶ⬟࠼ࡿᙳ㡪, ↓ᶵ⭷◊✲, P-15, ᒱ㜧, 2014.10.10.
[14] ୖ㔝ᜤᖹ, ᰿ᓊ⚽அ, ụୖᚭ, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, Silicalite-1⭷ࡼࡿࣂ
࢚࢜ࢱࣀ࣮ࣝࡢศ㞳࠾ࡅࡿ᭷ᶵ㓟ࡢᙳ㡪, ᏛᕤᏛ➨ 46 ᅇ⛅Ꮨ, E118, ⚟ ᒸ, 2014.9.17.
[15] ୖ㔝ᜤᖹ, ⴱ㇂ᙲᏹ, ᰿ᓊ⚽அ, ụୖᚭ, ᐑᮏᏛ, ୖᐑᡂஅ, ㏆Ụ㟹๎, ࢩࣜ࢝ࣛ
ࢺ⭷ࡢྜᡂ࠾ࡅࡿ✀⤖ᬗࡢᙳ㡪, ➨29ᅇࢮ࢜ࣛࢺ◊✲Ⓨ⾲, C10, ྎ, 2013.
11.27