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本研究を遂行するにあたり,機会を与えていただき,また,終始,ご指導ご鞭撻を 賜りました九州工業大学大学院 工学研究院 内藤 正路教授に心より感謝申し上げま す.本論文の執筆にあたり,数々のご助言をいただきました九州工業大学 生命体工学 研究科 花本 剛士教授に心より感謝申し上げます.

本論文の審査をご快諾いただき,また論文執筆にあたって数々のご指導を賜りまし た,九州工業大学 生命体工学研究科 宮崎 敏樹教授, 飯久保 智准教授, 工学研究院 孫 勇教授に深く感謝申し上げます.

本研究を進めるうえで,貴重なお時間を割いていただき,研究内容に関して有益な ご討論を頂き,多大なご助言ご協力を頂きました北九州工業高等専門学校 生産デザイ ン工学科 松嶋 茂憲教授,宇部工業高等専門学校 電気工学科 碇 智徳教授に厚くお礼 申し上げます.

第一原理計算を行うにあたって,技術的な面で様々なご助言をいただきました北九 州工業高等専門学校 中村 裕之教授に深く感謝いたします.また,研究活動全般で多 くのご援助を頂きました熊本大学 船津 麻美助教に感謝申し上げます.九州大学 応用 力学研究所 技術専門職員 石井 大輔様には,論文の執筆に際し,助言をいただき感謝 いたします.

研究室にてお世話になりました九州工業大学 工学部 電気電子工学科 技術職員 重 末 貴寿様,一緒に実験をしていただいた内藤研究室の枝元 太希君,坪井 直也君,

早久 和希君,宮脇 泰裕君,田久呂 遊君,山崎 誉之君,元川 陽介君,その他内藤研 究室の皆様に感謝いたします.

最後に経済的,精神的に支えて頂いた家族の皆様に感謝申し上げます.

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研究業績

1. 学術論文

(1) Junko Ishii, Yasuhiro Miyawaki, Takayuki Yamasaki, Tomonori Ikari, Masamichi Naitoh Effect of ion-beam irradiation on the epitaxial growth of graphene viathe SiC surface decomposition method

Japanese Journal of Applied Physics, 56, 085104 (2017).

(2) Junko Ishii, Shigenori Matsushima, Hiroyuki Nakamura, Tomonori Ikari, Masamichi Naitoh First-Principles Calculation Study of Epitaxial Graphene Layer on 4H-SiC (0001) Surface e-Journal of Surface Science and Nanotechnology Vol. 14,107-112 (2016).

(3) Junko Ishii, Yasuhiro Miyawaki, Naoya Tsuboi, Tomonori Ikari, Masamichi Naitoh Growth of Graphene on SiC(111) Surfaces via Ion-Beam Irradiation

e-Journal of Surface Science and Nanotechnology, Vol. 14, 121-124 (2016).

(4) Tomonori Ikari, Takuto Nakamura, Kaede Hirayama, Kousuke Muraoka, Junko Ishii, Masamichi Naitoh

Oxidation at Cs Pre-Adsorbed Si/6H-SiC(0001)-(3 × 3) Reconstructed Surfaces Studied Using Metastable-Induced Electron Spectroscopy

e-Journal of Surface Science and Nanotechnology, Vol. 14, 103-106 (2016).

(5) Tomonori Ikari , Kohei Matsuo, Shohei Uesugi, Daichi Todo, Junko Ishii, Masamichi Naitoh Electronic structure at MePc/Si(100) surface studied by Metastable-atom Induced Electron Spectroscopy

e-Journal of Surface Science and Nanotechnology, Vol. 14, 141-143 (2016).

(6) Satoshi Nishigaki, Kenji Yamada, Junko Asanari (Ishii), Masamichi Naitoh

Development of Alkali-induced Electronic States at GaAs (001) Surfaces and Their Electron-transfer Interaction with Helium Metastable Atoms

Ultramicroscopy , 73, 223-228 (1998).

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(7) Kenji Yamada, Junko Asanari (Ishii), Masamihci Naitoh, Satoshi Nishigaki

Co-adsorption of Cesium and Oxygen on GaAs (001) Surfaces Studied by Metastable Deexcitation Spectroscopy

Surface Science, 402-404, 683-686 (1998).

2 学会発表

2.1 国際会議

(1) Junko Ishii, Yasuhiro Miyawaki, Takayuki Yamasaki, Tomonori Ikari, Masamichi Naitoh Raman spectroscopy and STM studies of graphene formation on the SiC(111) surface by ion-beam irradiation

IVC-20, 2016/8/21-26, Korea.

(2) Junko Ishii

Influence of atomic vacancy on the electronic structure of graphene layer on 4H-SiC (0001) 2016 Kumamoto Symposium on Two Dimensional Nanomaterials, 2016/02/04, Kumamoto.

(3) Junko Ishii, Shigenori Matsushima, Tomonori Ikari, Masamichi Naitoh

The formation of epitaxial graphene layers on the 4H-SiC(0001) surface studied by First-principles calculation

10th International Symposium on Atomic Level Characterizations for New Materials and Devices ’15 ,2015/10/28, Matsue.

(4) Yasuhiro Miyawaki, Junko Ishii, Naoya Tsuboi, Tomonori Ikari, Msamichi Naitoh A study in the growth of graphene on the SiC(111) surface with ion beam irradiation 10th International Symposium on Atomic Level Characterizations for New Materials and Devices ’15, 2015/10/28, Matsue.

(5) Kousuke Muraoka, Takuto Nakamura, K. Umeda, Junko Ishii, Masamichi Naitoh, Tomonori Ikari

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Oxidation of cesium adsorbed SiC surface studiedby metastable atom induced electron spectroscopy

ISSS-7, 2014/11/2-6, Matsue.

(6) Kohei Matsuo, Masaki Suehiro, Koki Shimose, Fukutoshi. Kaneko, Junko Ishii, Masamichi Naitoh, Tomonori Ikari

The study of the electronic structure at CuPc adsorbed Si(100) surface by Metastable atom Induced Electron Spectroscopy

ISSS-7, 2014/11/2-6, Matsue.

(7) Naoya. Tsuboi, Kazuki. Hayahisa, Junko Ishii, Motochika. Okano, Tomonori Ikari, Motoi Nakao, Masamichi Naitoh

A Study of the Formation Process of Graphene on Silicon Carbide-on-InsulatorSubstrate ISSS-7, 2014/11/2-6, Matsue.

(8) Satoshi Nishigaki, Kenji Yamada, Junko Asanari (Ishii), Masamichi Naitoh

Development of alkali-induced electronic states at GaAs(001) surfaces and their electron-transfer interaction with helium metastable atoms

44th International Field Emission Symposium, 1997/7/10, Tsukuba.

(9) Kenji Yamada, Junko Asanari (Ishii), Masamichi Naitoh, Satoshi Nishigaki

Coadsorption of cesium and oxygen on GaAs (001) surfaces studied by metastable deexcitation spectroscopy

17th European Conference on Surface Science, 1997/9/17, Enschede.

(10) Kenji Yamada, Junko Asanari (Ishii), Masamichi Naitoh, Satoshi Nishigaki

An MDS study of variation in the local electronic structure during alkali-promoted oxygenation of GaAs (001) surfaces

4th International Symposium on Atomically Controlled Surfaces and Interfaces, Oct. 28, 1997, Tokyo.

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