Study on Water Science ⅣႺߣஜᐽࠍ቞ࠆߚ߼ߩ᳓ߦ㑐ߔࠆ⑼ቇ⊛⎇ⓥ

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Science Journal of Kanagawa University17 : 97-98 (2006)

©Research Institute for Integrated Science, Kanagawa University

عႎ๔ᦠع 2005ᐕᐲ␹ᄹᎹᄢቇ✚วℂቇ⎇ⓥᚲഥᚑ౒ห⎇ⓥ

ⅣႺߣஜᐽࠍ቞ࠆߚ߼ߩ᳓ߦ㑐ߔࠆ⑼ቇ⊛⎇ⓥ

⷏ᧄฝሶ

1,5

㜞ᯅᴺሶ

1

⍹ሶ⾆ਈᤩ

1

ᄤ㊁ ജ

1

੗਄๺ੳ

1

ᄢ⍹ਇੑᄦ

1

ᴡ᧛ᱜ৻

2

㑐 ㇌ඳ

1

ኹᧄବᒾ

3

ፃጯ቟ᵤሶ

1

ᷰㇱᓼሶ

4

Study on Water Science

Yuko Nishimoto

1,5

, Noriko Takahashi

1

, Kiyoteru Ishiko

1

, Chikara Amano

1

, Kazuhito Inoue

1

, Fujio Oh-ishi

1

, Shoichi Kawamura

2

㧘 Kunihiro Seki

1

, Toshihiko

Teramoto

3

, Atsuko Minegishi

1

, and Tokuko Watanabe

2

1Faculty of Science, Kanagawa University, Hiratsuka, Kanagawa 259-1293, Japan

2National Institute of Radiological Sciences, Chiba, Chiba 263-0801, Japan

3Natural Environment Research Inc. Ltd. jp. Shinjuku, Tokyo 162-0801, Japan

4Aoyama Gakuin Women’s Junior College, Shibuya, Tokyo 150-8366, Japan

5To whom correspondence should be addressed. Email: y24moto@kanagawa-u.ac.jp

Abstract: In this study, we intended to clarify the effect of various treatments such as magnetic and ultraviolet light irradiation on acidic electrolyzed aqueous solutions and alkali halide aqueous solutions.

The results indicated that the available chloride concentration of acidic electrolyzed aqueous solution was decreased by these treatments. It was proved that hydroxyl radicals and bound water varied by these treatments in the alkali halide aqueous solution. It was proved that the most effective treatment in aqueous solutions relates to the salt concentration in both the acidic electrolyzed aqueous solution and the alkali halide aqueous solution.

Keywords: functional water, magnetic treatment, ultraviolet light irradiation, bound water, salt concentration

ᐨ⺰

21਎♿ߪ᳓ߩᤨઍߣ߽޿ࠊࠇߡ޿ࠆޕᧄ⎇ⓥߪㆊ෰

2 ᐕ㑆ߦᷰߞߡታᣉߒߡ߈ߚ౒ห⎇ⓥޟஜᐽߦ㑐ߔ ࠆ⎇ⓥޠߩ⊒ዷߣߒߡޔⅣႺߣஜᐽࠍ቞ࠆߚ߼ߩࠠ࡯

ࡢ࡯࠼ߢ޽ࠆ᳓ߦὶὐࠍ߅޿ߡ޿ࠆޕᧄႎ๔ߢߪⅣ Ⴚ෸߮↢૕ߦㆡวߒߚᯏ⢻᳓ߣߒߡක≮࡮ㄘᬺಽ㊁ ߢ৻ㇱታ↪ൻ߽ㅴࠎߢ޿ࠆ㔚⸃᳓෸߮⚡ᄖ✢ᾖ኿᳓ޔ

⏛᳇ಣℂ᳓ߦ㑐ߔࠆಽᨆൻቇ⊛⹏ଔࠍਛᔃߦㅀߴࠆޕ

᧚ᢱߣᣇᴺ

⹜ᢱߪ㔚⸃᳓ߩࡕ࠺࡞ṁᶧ 14)ߣߒߡޔ᦭ലႮ⚛㊂ 0.3, 1.0 mmol/Lޔ౒ሽႮ㧔NaCl, KCl, CaCl2㧕Ớᐲ 200mmol/L એਅޔpH2.5~4 ߩ㕖㔚⸃⺞⵾᳓ࠍ૶↪

ߒޔ㘶↪ࠍ⠨ᘦߒNaCl, KCl, MgCl2, CaCl2᳓ṁᶧ (1㨪100mM)ࠍ↪޿ߚޕ⏛᳇ಣℂߦߪޔ᳗ਭ⏛⍹

㧔NIKKENSURU-WATER magnet㧦Nd ⏛⍹㧦 80mT, 120mT㧕ޔ ⚡ ᄖ✢ ᾖ ኿ ߦ ߪޔUV ࡜ ࡦࡊ (SLUV-8 ࠕ࠭ࡢࡦ⵾㧘254nm㧦శḮ߆ࠄ50mmߢ 1013, 2020ǴW/cm2)ࠍ૶↪ߒߚޕ᷹ቯⵝ⟎ߪޔ

NIR(ㄭ⿒ᄖಽశశᐲ⸘)㧦Jasco V-570, ESR(㔚ሶࠬ

ࡇ ࡦ ౒ 㡆 ):X-BAND (JEOL RE2X), UV-VIS (Shimadzu Multispec1500), pH, ORP (㉄ൻㆶర㔚

૏):(CUSTOM⵾TES 1380), DO (ṁሽ㉄⚛) :(TOA DKK DOL- 40) ,ࠝ࠱ࡦ㔚ᭂ (TOA DKK OZ-20) ,

17O NMR (JEOL JNM EX 400)ࠍ૶↪ߒߚޕฦಣℂ ೨ᓟߩ᷹ቯ୯ࠍᲧセߒޔ17O NMR ᷹ቯߢߪ✭๺ᤨ

㑆(T2)ࠍ᳞߼ߚޕ

⚿ᨐߣ⸛⺰

㔚⸃᳓ߩ᦭ലႮ⚛ỚᐲߪUVᴺߦࠃࠅᬌ⸛ߒߚޕߘ ߩ⚿ᨐޔ޿ߕࠇߩ㔚⸃ഥ೷ߦ߅޿ߡ߽ಣℂߦࠃࠆ᦭

ലႮ⚛Ớᐲߩૐਅ߇ߺࠄࠇߚޕUV ᾖ኿ߢߪᾖ኿ᤨ

㑆ޔ⏛᳇ಣℂߢߪỚᐲૐਅߪ⏛႐߇ᷫዋ₸ߦ㑐ଥߒ ߡ޿ߚ߇ޔ౒ሽႮ(㔚⸃ഥ೷)CaCl2 ߇ಣℂߦࠃࠆᄌ ൻ߇ᦨᄢߢ޽ߞߚޕ߹ߚዋ㊂ߩ౒ሽႮߦࠃࠅ᦭ലႮ

⚛Ớᐲߩᷫዋ߇ᛥ߃ࠄࠇࠆߎߣ߇ࠊ߆ࠅޔᦨㆡႮỚ ᐲߩሽ࿷߇␜ໂߐࠇߚޕ

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98 Science Journal of Kanagawa University Vol. 17, 2006

߹ߚOH࡜ࠫࠞ࡞ߪ⏛᳇ಣℂߦࠃࠅᷫዋߒޔ⚡ᄖ

✢ᾖ኿ߦࠃࠅჇടߒߚޕ೎ㅜታᣉߒߚᲕ⩶ലᨐ⹜㛎 ߩ⚿ᨐߪ᦭ലႮ⚛㊂ߣ⋧㑐߇ߺࠄࠇޔCaCl2ࠍ㒰ߊ

⏛᳇ಣℂߢߪᧂಣℂߣ߶߷ห⒟ᐲޔߘࠇએᄖߪᲕ⩶

ലᨐߪૐਅߒߚޕ

᦭ലႮ⚛ࠍ฽᦭ߒߥ޿Ⴎߩߺߩ᳓ṁᶧߦ߅޿ߡߪޔ

⏛᳇ಣℂߦࠃߞߡOH࡜ࠫࠞ࡞ߩჇട߇⏕⹺ߐࠇߚޕ

߹ߚ᳓ߩ᧤❈⁁ᘒ߽ಣℂߦࠃߞߡᄌൻߒߚޕ޿ߕࠇ ߩ႐ว߽ᦨㆡႮỚᐲޔಣℂᒝᐲ෸߮ᤨ㑆ߩሽ࿷߇␜

ໂߐࠇߚޕ

⻢ㄉ

ᧄ⎇ⓥߪޔ␹ᄹᎹᄢቇ✚วℂቇ⎇ⓥᚲ౒ห⎇ⓥߣߒ ߡᐔᚑ15ᐕᐲ߆ࠄ17ᐕᐲߦ߆ߌߡታᣉߒߚ߽ߩߢ

޽ࠆޕ✚วℂቇ⎇ⓥᚲߦᗵ⻢ߔࠆޕ

ᢥ₂

1) ጤᴛ◊㇢㧘ਛ᧛⦟ሶ㧘੗਄ ໪㧘ਤ⠀෹๺㧘⷏ᧄฝ

ሶ(2004) ᒝ㉄ᕈ㔚⸃᳓ߩᲕ⩶ലᨐߦኻߔࠆpH෸߮

౒ሽႮỚᐲߩᓇ㗀㧚㒐⩶㒐㤻⹹32:301-306㧚 2) ⷏ᧄฝሶ㧘੗਄ ໪(2004) 㔚⸃᳓ߩ቟ቯᕈߦኻߔࠆ

pH߅ࠃ᷷߮ᐲߩᓇ㗀㧚ᯏ⢻᳓⎇ⓥ2:71-74㧚 3) ጤᴛ◊㇢㧘ਛ᧛⦟ሶ㧘㊀ጊ߆ߩ㧘ਤ⠀෹๺㧘⷏ᧄฝ

ሶ(2002) ᒝ㉄ᕈ㔚⸃᳓ߩ᦭ലႮ⚛᷹ቯᴺ㧚㒐⩶㒐㤻

⹹30:627-633㧚

4) ጤᴛ◊㇢㧘ਛ᧛⦟ሶ㧘ਤ⠀෹๺㧘⷏ᧄฝሶ㧚(2002) ᒝ

㉄ᕈ㔚⸃᳓ߩᲕ⩶ലᨐߦኻߔࠆ pH ߩᓇ㗀㧚㒐⩶㒐 㤻⹹30:635-643㧚

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