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熱刺激電流曲線の復元手法と有機材料の電気伝導機構に関する研究

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Memoirs of the Osaka Institute of Technology,Series A Vol.45,No.2 (2000) pp.103

~

197

熱刺激電流曲線の復元手法と有機材料の

電気伝導機構に関する研究

上谷 芳美

工学研究科 電気電子工学専攻

(2000

9

30

日受理)

Proposal of the Reconstruction Method of Composite TSC Curves

and a Study of the Electrical Conduction Mechanisms in Organic Substances

by

Y oshimi KAMIT ANI

Major in Electronics and Electrical Engineering , Engineering Studies (Manuscript received September 30,2000)

Abstract

In order to make the charge transport mechanism in organic substances clear in details, the thermal­ ly stimulated current (TSC) method is very effective. From the TSC method, three parameters such as the energy depth of carrier trap site Et (e V), a pre-exponential parameter (or an escape frequency fac­ tor) v (s-1) and a charge carrier density nt (m-3) of discrete states relating to the charge transport mechanism can be estimated. However, accurate values of these parameters could not be generally es­ timated for various types of composite curves obtained experimentally. In such cases, some partial TSC curves have been generally observed through repeated heating and cooling processes to separate composite causes experimentally. In such cases, it was not unusual that the experimental data with no peak were obtained, and the three parameters for these data could not be estimated until now.

In this paper, I have proposed the reconstruction (RC) method for the first time. The RC method en­ ables us to estimate 3N parameters accurately through the accurate reconstruction procedures from partial curves with no peak to some single TSC curves, where N is the number of the single TSC curves concealed in data. Also I have presented some analyzed results. The proposed RC method and the auto -separation (AS) method that enables us to accurately separate composite curves obtained by one heating process into some TSC curves with single relaxation processes were applied to data ob­ tained experimentally in naphthacene -doped anthracene single crystals as a representative of organic semiconductors. Et and v values estimated from the AS method are slightly larger than that from the RC method. This result suggests that the indirect transport mechanisms via discrete state-to-state charge transfer processes is not negligible.

*

2000年8月 大阪工業大学大学院博士後期課程学位論文

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