ᚑᨐ䈱㆐ᚑᐲ

3ߟߩࠨࡉ࠹࡯ࡑߣ߽ߦᐔᚑ17ᐕᐲߩ໧㗴ὐߦኻಣߒ㧘ᣂߚߥ⸃ᨆᚻᴺ߿᷹ቯ ᣇᴺࠍ⷗಴ߒߚߣߣ߽ߦ㧘ᅷᒰߥ⸃ᨆ⚿ᨐ߿᷹ቯ࠺࡯࠲ࠍჇ߿ߔߎߣ߇ߢ߈ߚޕ

ᶏᐩ㔚᳇តᩏߣ޿߁ᣂߚߥ⸘᷹ᣇᴺߦߟ޿ߡ߽౎ઍᶏߦㆡ↪ߢ߈㧘೨ᐕᐲએ਄

ߦ㊀ⷐߥ⍮⷗߇ᓧࠄࠇߚޕߎࠇࠄߩⷰὐ߆ࠄߪ㧘೨ㅀߩᐔᚑ18ᐕᐲߩ⋡⊛࡮⋡

ᮡߦ㑐ߒߡ߶߷㆐ᚑߢ߈ߚߣ⠨߃ࠆޕߒ߆ߒߥ߇ࠄ㧘ᶏ㕙᷷ᐲએᄖߩⅣႺ࿃ሶ ߦᵈ⋡ߒߚⴡᤊ↹௝⸃ᨆߦ㑐ߒߡߪਇචಽߢ޽ࠅ㧘ᰴᐕᐲ߳ߩ⛮⛯⺖㗴ߣߥߞߚޕ 4.㩷 H19ᐕᐲ䈱⋡⊛䊶⋡ᮡ

4. 1. ⴡᤊ䊥䊝䊷䊃䉶䊮䉲䊮䉫

࡮ⴡᤊ↹௝⸃ᨆߦࠃߞߡ⴫ጀ‛⾰ߩᄌൻ߇࿾ਅ᳓૏ߦ෸߷ߔᓇ㗀㧘߅ࠃ߮࿾ਅ

᳓ᵹേࡄ࠲࡯ࡦߩᤨ㑆⊛ᄌൻࠍ᣿ࠄ߆ߦߔࠆޕ

࡮ᐓẟ⹜ᢱߩ෻኿ࠬࡍࠢ࠻࡞᷹ቯ߆ࠄᓧࠄࠇߚ⚿ᨐࠍ↪޿㧘LANDSAT ↹௝߿

Terra/ASTER↹௝࠺࡯࠲ߩ⸃ᨆࠍㅴዷߐߖ㧘ᐓẟၸⓍ‛ߩ࿾⾰ⅣႺߩᤨ㑆⊛࡮

ⓨ㑆⊛ᄌൻࠍ᣿ࠄ߆ߦߔࠆޕ

࡮ᶏ᳓߿ᴡᎹ᳓ߦ߅ߌࠆઍ⴫⊛ߥⅣႺ࿃ሶߩᤨⓨ㑆ಽᏓࠍ㧘ⴡᤊ↹௝߆ࠄ♖ᐲ

⦟ߊ᛽಴ߢ߈ࠆᚻᴺࠍ⠨᩺ߔࠆޕ 4. 2. ᢙℂ䊝䊂䊦

࡮ᄙᄌ㊂࿾⃿⛔⸘ቇߦࠃߞߡ࿾ਅ᳓૏ߩᤨ㑆⊛ᄌൻࠍ⹦⚦ߦ᣿ࠄ߆ߦߔࠆߣߣ

߽ߦ㧘ࠗࡦࡃ࡯࡚ࠫࡦ⸃ᨆࠍ↪޿ߡㅘ᳓ଥᢙߩಽᏓࠍ᳞߼㧘⃻࿾⸘᷹߆ࠄߘ ߩᅷᒰᕈࠍᬌ⸽ߔࠆޕ

࡮ㅘ᳓ᕈߦ㑐ㅪߔࠆ࿾⾰૕ߩ᭴ㅧߩⓨ㑆ࡕ࠺࡝ࡦࠣࠍㅴዷߐߖ㧘ߎࠇߦ㋶‛ಽ Ꮣ߿ᄌ⾰Ꮺࠍ㊀ߨวࠊߖࠆߎߣߢ‛⾰⒖ⴕߩࡄ࠲࡯ࡦ߿ᤨ㑆⊛ᄌൻࠍ⠨ᘦߢ ߈ࠆࠃ߁ߦߔࠆޕ

4. 3. ࿾⏛᳇䋭࿾㔚ᵹ⸘᷹

࡮MTᴺߦࠃࠅᾢᧄᐔ㊁๟ㄝߩ࿾ਅ᭴ㅧផቯࠍㅴ߼㧘ᶩ㙃ၞ߆ࠄᵹ಴ၞ߹ߢߩ࿾

ਅ᳓♽ߦ߅޿ߡ㧘․ߦᢿጀߩሽ࿷ߩᓇ㗀ࠍ᣿ࠄ߆ߦߔࠆޕߐࠄߦ㧘ᶏᐩ㔚᳇

តᩏߩ᷹✢ࠍㅊടߒ㧘ᶏᐩߦḝ᳓ߔࠆ࿾ਅ᳓ߩ⚻〝ࠍᲧᛶ᛫ಽᏓ߆ࠄ⹦⚦ߦ ផቯߔࠆߣߣ߽ߦ㧘Ყᛶ᛫ಽᏓߩ♖ᐲࠍะ਄ߐߖࠆߚ߼ߦ᷹ቯ࠺࡯࠲ߩࠗࡦ ࡃ࡯࡚ࠫࡦ⸃ᨆᴺࠍᡷ⦟ߔࠆޕ

5.㩷 H18ᐕᐲ䈱⎇ⓥ⾌ขᓧ⁁ᴫ

࡮⑼ቇ⎇ⓥ⾌ ၮ⋚⎇ⓥB㧔ઍ⴫㧕㧦6,400ජ౞

࡮ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴ వⴕၮ␆Ꮏቇ⎇ⓥ㧔ઍ⴫㧕㧦3,000ජ౞

࡮䋨⽷䋩ᣣᧄ㋶ᬺᝄ⥝ળ⹜㛎⎇ⓥ㧔ઍ⴫㧕㧦700ජ౞

࡮ᾢᧄᄢቇᎿቇㇱ⑼ቇ⎇ⓥഥᚑ ࿾ၞㅪ៤㧔ઍ⴫㧕㧦1,000ජ౞

࡮ነ㒝㊄㧦᳃㑆ડᬺ࡮䋨␠䋩⾗Ḯ࡮⚛᧚ቇળࠃࠅ㧘⸘3,650ජ౞

࡮౒ห⎇ⓥ⾌㧦࿖┙ᭂ࿾⎇࡮੩ㇺᄢቇ㒐ἴ⎇㧔ಽᜂ㧕㧘⸘250ජ౞

6. H18ᐕᐲ䈱⎇ⓥ⊒⴫䇮․⸵⁁ᴫ

䋨1䋩 ේ⪺⺰ᢥ䈮䉋䉎⊒⴫

࡮࿖ౝ⹹㧔๺ᢥ㧕

↰᧛✍ሶ࡮ዊᳰస᣿࡮ዊᨋ⨃᮸࡮↰ਛஜ〝 䋨2007䋩 ⴡᤊ↹௝࠺࡯࠲ࠍ↪޿ߚ࿾

⴫ ‛ ᕈ ផ ቯ ߦ ߅ ߌ ࠆ ᄢ ᳇ ᓇ 㗀 ߩ ᬌ ⸛ ߣ ផ ቯ ♖ ᐲ ะ ਄ ߩ ৻ ឭ ᩺ 㧙

LANDSAT TM ᾲ⿒ᄖ࠺࡯࠲ߦࠃࠆᶏ㕙᷷ᐲផቯߩࠤ࡯ࠬࠬ࠲࠺ࠖ㧙,

ᖱႎ࿾⾰, vol. 18, no. 1, p. 15-28.

࡮࿖㓙⹹㧔᰷ᢥ㧕

Koike, K. and Ichikawa, Y. 䋨2006䋩 Spatial Correlation Structures of Fracture Systems for Identifying a Scaling Law and Modeling Fracture Distributions, Computers &

Geosciences, vol. 32, no. 8, p. 1079-1095 䋨doi:10.1016/j.cageo.2006.02.013䋩. Koike, K. and Matsuda, S. 䋨2006䋩 New Indices for Characterizing Spatial Models of

Ore Deposits by the Use of a Sensitivity Vector and Influence Factor, Mathematical Geology, vol. 38, no. 5, p. 541-564 䋨doi:10.1007/s11004-006-9030-3䋩.

Masoud, A. and Koike, K. 䋨2006䋩 Tectonic Architecture through LANDSAT-7 ETM+/SRTM DEM-Derived Lineaments and Relationship to the Hydrogeologic Setting in Siwa Region, NW Egypt, Journal of African Earth Sciences vol. 45, nos. 4/5, p. 467-477 䋨doi:10.1016/j.jafrearsci.2006.04.005䋩.

Nara, Y., Koike, K., Yoneda, T, and Kaneko, K. 䋨2006䋩 Relation between Subcritical Crack Growth Behavior and Crack Paths in Granite, International Journal of Rock Mechanics and Mining Sciences, vol. 43, no. 8, p. 1256-1261 䋨doi:10.1016/j.ijrmms.2006.03.016䋩.

Liu, C. and Koike, K. 䋨2007䋩 Extending Multivariate Space-time Geostatistics for Environmental Data Analysis, Mathematical Geology, vol. 39, no. 3 䋨doi:10.1007/s11004-007-9085-2007䋩䋨in press䋩

ޣ࿖㓙ળ⼏ࡊࡠࠪ࡯࠺ࠖࡦࠣޤ

Omura, M., Kobayashi, S., Koike, K., and Tomiyama, N. 䋨2006㧕 D-InSAR monitoring

of ground deformations in a geothermal area in Kyushu, Japan, Proceedings of the 3rd IAG Symposium on Geodesy for Geotechnical and Structural Engineering and 12th FIG Symposium on Deformation Measurements, Baden, Austria, CD-ROM: ISBN 3-9501492-3-6.

Koike, K., Suetsugu, K., Yoshinaga, T., and Liu, C. 䋨2006䋩 : Spatial heterogeneity of radon concentrations in top soils along an active fault zone, Proceedings of XIth International Congress for Mathematical Geology 䋨IAMG’06䋩: Quantitative Geology from Multiple Sources, Liège, Belgium, Sept. 3-8, S02-04 䋨p. 1-5䋩, CD-Rom press.

Liu, C., Koike, K., and Sanga, T. 䋨2006䋩 Geostatistical simulation of rock fractures distribution by considering directional elements, Proceedings of IAMG’06, S06-15 䋨p. 1-4䋩, CD-Rom press.

Koike, K. 䋨2006䋩 How can we model correctly invisible geologic structures and properties from small pieces of geological information?, Proceedings of 9th International Symposium on Mineral Exploration 䋨ISME IX䋩䋨Koike, K., Notosiswoyo, S., Kouda, R., and Sulistianto, B., eds.㩷 䋩, Sept. 19-21, 2006, Institut Teknologi Bandung, p. 1-8.

Heriawan, M. N. and Koike, K. 䋨2006䋩 Transition probability geostatistics for spatial variability of coal sequences and qualities, Proceedings of ISME IX, p. 23-30.

Suetsugu, K., Yoshinaga, T., and Koike, K. 䋨2006䋩 Radon in terrestrial gas as useful indicator for characterizing fault activity and geothermal reservoir, Proceedings of ISME IX, p. 229-235.

Saepuloh, A., Koike, K., Omura, M., and Iguchi, M. 䋨2006䋩 The application of Pi-SAR polarimetric data to detect surface condition of an active volcano, Proceedings of ISME IX, p. 236-241.

Ayshamgu, W. and Koike, K. 䋨2006䋩 Satellite remote sensing for characterizing progress of desertification in the northern Tarim Basin, China, Proceedings of 4th International Workshop on Earth Science and Technology, Fukuoka, Japan, p.

15-20.

Liu, C., Koike, K., and Sanga, T. 䋨2006䋩 Three dimensional simulation of rock fractures by geostatistical method with consideration of directional elements, Proceedings of 4th International Workshop on Earth Science and Technology, Fukuoka, Japan, p. 29-36.

Moukana, J. A. and Koike, K. 䋨2006䋩 Detailed mapping of spatio-temporal variability of shallow groundwater levels using multivariate cokriging, Proceedings of 4th International Workshop on Earth Science and Technology, Fukuoka, Japan, p.

169-174.

Teng, Y., Suetsugu, K., Yoshinaga, T., and Koike, K. 䋨2006䋩 Fault zone characterization in geothermal field by 3D geologic modeling and radon prospecting, Proceedings of 4th International Workshop on Earth Science and Technology, Fukuoka, Japan, p. 175-180.

Saepuloh, A., Koike, K., and Omura, M. 䋨2006䋩 Clarification of flow areas of volcanic materials accompanied by the historical eruption of Mt. Merapi, Indonesia using RADARSAT SAR images, Proceedings of 4th International Workshop on Earth Science and Technology, Fukuoka, Japan, p. 181-186.

Teng, Y. and Koike, K. 䋨2006䋩 Permeability estimation in geothermal area by inversion analysis of 3D temperature distribution using well-logging data, Proceedings of 4th International Workshop on Earth Science and Technology, Fukuoka, Japan, p. 187-192.

Koike, K., Tominaga, H., Kaneko, H., Yoshinaga, T., Shimada, J., Inoue, M., Takaoka, H., and Asaue H. 䋨2006䋩 Evaluation of submarine groundwater discharge by resistivity survey on the sea bottom floor of Ariake and Yatsushiro seas, Japan, Proceedings of International Symposium on “Interrelations betwwn seawater and groundwater in the coastal zone and their effect on the environmental nutrient load toward the sea”, Kumamoto Univ., Japan, p. 72-77.

䋨2䋩 ේ⪺⺰ᢥએᄖ䈮䉋䉎⊒⴫

㤗ᬀਭผ࡮ዊᳰస᣿࡮ศ᳗ ᔀ࡮㜞ୖિ৻ 䋨2006䋩 Ꮣ↰Ꮉ㧙ᣣᄹਭᢿጀᏪߩᷓㇱ Ყᛶ᛫᭴ㅧߣᓸዊ࿾㔡ḮಽᏓߣߩ㑐ㅪᕈ, ᖱႎ࿾⾰, vol. 17, no. 2, p.

90-91.

Heriawan, M. H. and Koike, K. 䋨2006䋩 Spatially correlating coal quality with seam structure in a multilayer coal deposit, ᖱႎ࿾⾰, vol. 17, no. 2, p. 96-97.

ዊᳰస᣿࡮ਛᵤ⇐㓉ผ࡮↰᧛✍ሶ࡮ศ᳗ ᔀ࡮ጊ↰ᢥᒾ 䋨2006䋩 ࡝ࡕ࡯࠻࠮ࡦࠪ

ࡦࠣߦࠃࠆᐓẟߩ࿾⾰⊛ಽ㘃, ᖱႎ࿾⾰, vol. 17, no. 2, p. 106-107.

Liu, C., Koike, K., and Sanga, T. 䋨2006䋩 Geostatistical simulation considering directional elements with application to rock fracture distribution, ᖱႎ࿾⾰,

vol. 17, no. 2, p. 110-111.

Saepuloh, A., Koike, K., Omura, M., and Iguchi, M. 䋨2006䋩 Image processing of Pi-SAR polarimetric data for detecting geomorphologic and structural features of an active volcano, ᖱႎ࿾⾰, vol. 17, no. 2, p. 134-135.

ዊᳰస᣿ 䋨2006䋩 ࿾࿤ⅣႺࠗࡦࡈࠜࡑ࠹ࠖࠢࠬߦᔅⷐߥⓨ㑆ࡕ࠺࡝ࡦࠣᴺ, ⾗ Ḯ࡮⚛᧚2006 䋨⑔ጟ㧕ડ↹⊒⴫࡮৻⥸⊒⴫ 䋨C㧕䋨D䋩 ⻠Ṷ⾗ᢱ㧘p. 81-84.

䋨3䋩 ቇળ⊒⴫

ᧃᰴஜᄥ࡮ศ᳗ ᔀ࡮ዊᳰస᣿ 䋨2006䋩 ᵴᢿጀᏪ⴫ጀߢߩ᡼኿ᕈᩭ⒳Ớᐲߩਇဋ

⾰ಽᏓߣߘߩⷐ࿃, ⾗Ḯ࡮⚛᧚ቇળ਻Ꮊᡰㇱᐔᚑ 18 ᐕᤐቄ଀ળ⻠Ṷⷐᣦ 㓸, p. 46-48.

㊄ሶᄢ᮸࡮౷᳗⧷ᒾ࡮ศ᳗ ᔀ࡮ዊᳰస᣿࡮㤗ᬀਭผ 䋨2006䋩 ᣣᄹਭᢿጀߩᷓㇱ Ყᛶ᛫ࡕ࠺࡝ࡦࠣߣ࿾⾰᭴ㅧផቯ, ⾗Ḯ࡮⚛᧚ቇળ਻Ꮊᡰㇱᐔᚑ 18 ᐕᤐ ቄ଀ળ⻠Ṷⷐᣦ㓸, p. 49-51.

ዊᨋ⨃᮸࡮ᄢୖ ඳ࡮ᄢ᧛ ⺈࡮ዊᳰస᣿࡮ᯅᧄ ቇ࡮ᄢਭ଻ୃᐔ 䋨2006䋩 ENVISAT ⴡᤊߩHH஍ᵄSARߦࠃࠆᐓᷤಣℂ㧘ᐔᚑ18ᐕᐲ᧲੩ᄢቇ࿾㔡⎇ⓥᚲ౒

ห೑↪⎇ⓥ㓸ળޟᣂ਎ઍߩᐓᷤSARޠࡊࡠࠣ࡜ࡓ࡮ⷐᣦ㧘18: p. 1-2.

Saepuloh, A., Koike, K., Omura, M., and Iguchi, M. 䋨2006䋩 Extracting topographic change pattern with Mt. Merapi eruption and the Yogyakarta Earthquake in Indonesia by RADARSAT D-InSAR, ENVISATⴡᤊߩHH஍ᵄSARߦࠃࠆ ᐓᷤಣℂ㧘ᐔᚑ18ᐕᐲ᧲੩ᄢቇ࿾㔡⎇ⓥᚲ౒ห೑↪⎇ⓥ㓸ળޟᣂ਎ઍߩ ᐓᷤSARޠࡊࡠࠣ࡜ࡓ࡮ⷐᣦ㧘21: p. 1-2.

㤗ᬀਭผ࡮ዊᳰస᣿࡮ศ᳗ ᔀ࡮㜞ୖિ৻ 䋨2006䋩 Ꮣ↰Ꮉ㧙ᣣᄹਭᢿጀᏪߩᷓㇱ Ყᛶ᛫᭴ㅧߣᓸዊ࿾㔡ḮಽᏓߣߩ㑐ㅪᕈ, ᣣᧄᔕ↪࿾⾰ቇળᐔᚑ 18 ᐕᐲ

⎇ⓥ⊒⴫ળ⻠Ṷ⺰ᢥ㓸, p. 329-330.

౷᳗⧷ᒾ࡮ዊᳰస᣿࡮᎑↰ ⚐࡮੗਄ ⺈࡮㜞ጟ⑲᦮࡮㤗ᬀਭผ 䋨2006䋩 ᦜ⥶ဳ

Ყᛶ᛫ᴺߦࠃࠆ᦭᣿ᶏߩᶏᐩ⴫ጀ࿾⾰ಽᏓߩࠗࡔ࡯ࠫࡦࠣ, ᣣᧄᔕ↪࿾

⾰ቇળᐔᚑ18ᐕᐲ⎇ⓥ⊒⴫ળ⻠Ṷ⺰ᢥ㓸, p. 527-528.

ዊᳰస᣿࡮☍ ੔࡮Masoud, A. 䋨2007䋩 ࿾⾰ᖱႎߩ⛔วߦࠃࠆᢿጀߩᐢၞ⊛ㅘ᳓

ᕈߩផቯ, ⾗Ḯ࡮⚛᧚ቇળᤐቄᄢળ⻠Ṷ㓸㧔I㧕⾗Ḯ✬, ડ↹㧙1-2.

Liu, C., Koike, K., and Sanga, T. 䋨2007䋩 Three dimensional simulation method of rock fractures using geostatistics with a case study of granitic area, ⾗Ḯ࡮⚛᧚ቇળ ᤐቄᄢળ⻠Ṷ㓸㧔I㧕⾗Ḯ✬, ડ↹㧙3-4.

ᐔᚑᐕᐲ⎇ⓥᚑᨐႎ๔

⎇ⓥ⺖㗴ฬ㧦㜞ㅦߦ㊄ዻࠗࠝࡦࠍ᝝㓸ߔࠆ❫⛽⁁ࠠ࡟࡯࠻♽ๆ⌕೷ߩ㐿⊒ߣᔕ↪

Ꮏቇㇱ‛⾰↢๮ൻቇ⑼࡮ၔ ᤘౖ

⎇ⓥ⋡⊛࡮⋡ᮡ

*ᐕᐲޯ㧝ᐕᐲߦ߅ߌࠆ⋡⊛࡮⋡ᮡ

ࠠ࡟࡯࠻᮸⢽ߪฦ⒳㊄ዻࠗࠝࡦߩㆬᛯ⊛᝝㓸ߦᐢ▸ߦ૶↪ߐࠇߡ޿ࠆ߇ޔᎿ

ᬺ⊛ⷙᮨߩಽ㔌ߦ↪޿ࠆ☸⁁ࠠ࡟࡯࠻᮸⢽ߪࠞ࡜ࡓᴺߢ↪޿ࠆ႐วߩ࿶៊ࠍዊ ߐߊߔࠆߚ߼ޔ☸ᓘ߇OOߣᄢ߈ߊࠗࠝࡦๆ⌕ㅦᐲ߇ㆃ޿ޕࠠ࡟࡯࠻᮸⢽

ߩࠗࠝࡦๆ⌕ኈ㊂ޔࠗࠝࡦㆬᛯᕈߥߤߩᐔⴧ⺰⊛ᕈ⾰ߦߟ޿ߡߪ߶߷ቢᚑߩၞ

ߦ㆐ߒߡ޿ࠆ߇ޔㅦᐲ⺰⊛․ᕈߦߪᡷༀߔߴ߈૛࿾߇ᄙ޿ޕ

ᧄ⎇ⓥߢߪ᦭ኂ㊄ዻࠗࠝࡦߩๆ⌕ㅦᐲ߇ޔ੹ᣣᎿᬺ⊛ⷙᮨߢ૶↪ߐࠇߡ޿ࠆ

☸⁁᮸⢽ࠃࠅ߽୚એ਄㜞ㅦߢ޽ࠅޔ߆ߟࠞ࡜ࡓᴺߦ߅ߌࠆ࿶៊߽ዊߐ޿ੑቭ

⢻ᕈࠠ࡟࡯࠻❫⛽ߩ㐿⊒ࠍ⋡ᮡߣߒߡ޿ࠆޕㄦㅦߥๆ⌕ㅦᐲࠍ᦭ߔࠆࠠ࡟࡯࠻

❫⛽ߪᏗ⭯ߥ᦭ኂ㊄ዻࠗࠝࡦߢᳪᨴߐࠇߚ⤘ᄢߥ㊂ߩ᳓ߩㄦㅦᵺൻߦᔕ↪ߢ߈ ࠆ߶߆ޔ㊄ዻࠗࠝࡦߩ࿁෼࡮Ớ❗ߦⷐߔࠆᤨ㑆ߩ⍴❗ߦ߽⾗ߔࠆߣߎࠈ߽ᄢ߈

޿ޕߐࠄߦޔ㊄ዻࠗࠝࡦಽᨆߦ߅ߌࠆ㜞ㅦ೨ᲑỚ❗ߦࠃࠆ㜞ᗵᐲൻߦ߽᦭↪ߢ

޽ࠆߣᦼᓙߢ߈ࠆޕ

*ᐲߩ⋡⊛࡮⋡ᮡ

ᦨㄭޔ᳓↢↢‛ߩ

଻ోࠍ࿑ࠆߎߣࠍ⋡

⊛ߒߡਅ᳓㆏ᴺᣉⴕ

઎߇৻ㇱᡷᱜߐࠇޔ

․ቯ੐ᬺ႐߆ࠄਅ᳓

㆏ߦឃ㒰ߐࠇࠆਅ᳓

ਛߩޟ੝㋦߅ࠃ߮ߘ ߩൻว‛ޠߩឃ಴ၮ Ḱ ߇5 mg/L߆ ࠄ2 mg/Lߦᒝൻߐࠇߚޕ ߎߩߎߣࠍ⠨ᘦߒߡޔ ᧄᐕᐲߪᏗ⭯ߥ੝㋦

n

CMS electron beam

m

n-1

Cl DMF Cl KPI

N O O K

PPPE-g-CMS

m

n-1

N O O

FPI

H2SO4

m

n-1

N O O SO₃H

NH2NH2 H2O EtOH

m

n-1

NH₂

SO3H H3PO3 CH₂O

HCl

m

n-1

NH ^P O

OH OH SO₃H

FPIS FNS FNPS

DMSO

PPPE

Scheme 1 Preparation route for a bifunctional chelating fiber FNPS containing aminomethylphosphonate and sulfonate

Table 1 Results of chemical analysis of the fiber FNPS Nitrogen

content

Phosphorus content

Sulfur content

Acid capacity 㧔mmol/g㧕 㧔mmol/g㧕 㧔mmol/g㧕 㧔mmol/g㧕 1.5㧔0.1㧕^a㧕 2.8㧔0.1㧕^a㧕 1.0㧔0.1㧕^a㧕 6.0㧔0.3㧕^a㧕

a㧕Figures in parentheses are standard deviations.

ࠗࠝࡦᳪᨴ᳓ߩㄦㅦᵺൻ߇น⢻ߣᦼᓙߢ߈ࠆࠕࡒࡁࡔ࠴࡞ࡎࠬࡎࡦ㉄ߣࠬ࡞ࡎ ࡦ㉄ࠍ᦭ߔࠆੑቭ⢻ᕈࠠ࡟࡯࠻❫⛽FNPSߩวᚑᴺ㧔Scheme 1㧕ࠍ⏕┙ߔࠆߣߣ

߽ߦޔߘߩࠞ࡜ࡓᴺߦ߅ߌࠆ੝㋦ࠗࠝࡦๆ⌕․ᕈࠍ⹏ଔߒߚޕ

ᐔᚑᐕᐲߩ⎇ⓥᚑᨐ

Ԙࠕࡒࡁࡔ࠴࡞ࡎࠬࡎࡦ㉄ߣࠬ࡞ࡎࡦ㉄ࠍቭ⢻ၮߣߔࠆੑቭ⢻ᕈࠠ࡟࡯࠻❫⛽

ߩวᚑ

ࠬ࡞ࡎࡦ㉄ߩዉ౉ߦࠢࡠࡠࠬ࡞ࡎࡦ㉄ߣ⎫㉄ߩ޿ߕࠇࠍ↪޿ࠆ߆ߦߟ޿ߡߩ

⹜ⴕ㍲⺋⊛ᬌ⸛ࠍ㊀ߨߡޔ5EJGOGߦ␜ߒߚวᚑ⚻〝ࠍ⏕┙ߒߚޕ߹ߕޔ㔚ሶ

✢㧔/G8M)[㧕ࠍᾖ኿ߒߚࡐ࡝ࠛ࠴࡟ࡦߢⵍⷒߐࠇߚࡐ࡝ࡊࡠࡇ࡟ࡦ❫

⛽㧔222'FGPKGT㧕ࠍࠢࡠࡠࡔ࠴࡞ࠬ࠴࡟ࡦ㧔%/5㧕ߩ&/51ṁᶧ㧔YV㧕 ߣ^Q%ߢ㧣ᤨ㑆෻ᔕߐߖߡၮ૕❫⛽222'ߣ߶߷ห㊀㊂ߩ%/5߇ࠣ࡜ࡈ࠻㊀วߐࠇ ߚ❫⛽222'I%/5ࠍวᚑߒߚޕ222'I%/5ࠍࡈ࠲࡞ࠗࡒ࠼ࠞ࡝࠙ࡓߩ&/(ṁᶧߣ

෻ᔕߐߖߡ❫⛽(2+ࠍᓧߚޕᰴߦޔ❫⛽(2+ߣ⎫㉄㧔㧕ࠍ^Q%ߢ㧢ᤨ㑆෻ᔕߐ ߖߡࠬ࡞ࡎࡦ㉄ࠍዉ౉ߒߡ❫⛽(2+5ࠍᓧߚޕ⠴࿶⹜㛎▤ਛߢ❫⛽(2+5ߣᛴ᳓ࡅ

࠼࡜ࠫࡦߩ㧑ࠛ࠲ࡁ࡯࡞ṁᶧࠍ^Q%ߢᤨ㑆෻ᔕߐߖߡࡈ࠲࡞ࠗࡒ࠼ㇱ૏ࠍട

᳓ಽ⸃ߒߡ╙৻ࠕࡒࡁၮ߳ߣᄌ឵ߒߚ❫⛽(05ࠍᓧߚޕ❫⛽(05ࠍႮ㉄ሽ࿷ਅޔ

੝࡝ࡦ㉄ߣࡄ࡜ࡎ࡞ࡓࠕ࡞࠺ࡅ࠼ߣ෻ᔕߐߖޔ╙৻ࠕࡒࡁၮࠍࠕࡒࡁࡔ࠴࡞ࡎ

ࠬࡎࡦ㉄ၮ߳ߣォ឵ߒ⋡⊛ߩੑቭ⢻ᕈ❫⛽(025ࠍᓧߚޕ

วᚑߩฦᲑ㓏ߦ߅ߌࠆቭ⢻ၮߩዉ౉߹ߚߪォ឵ߪ(6+4ࠬࡍࠢ࠻࡞ߩ᷹ቯߦ ࠃࠅ⏕⹺ߒߚޕ6CDNGߦቭ⢻ၮዉ౉෻ᔕࠍ㧢࿁෻ᓳߒߡᓧߚ❫⛽(025ߩൻቇಽ ᨆߩ⚿ᨐࠍⷐ⚂ߒߚޕฦ᷹ቯ୯ߩᮡḰ஍Ꮕߪᢙ㧑⒟ᐲߢ޽ࠅޔᧄ⎇ⓥߢឭ᩺ߒ ߚวᚑᴺߩౣ⃻ᕈߪ⦟ᅢߢ޽ࠆߎߣ߇ಽ߆ࠆޕ

❫⛽(025߇5EJGOGߦ␜ߒߚ᭴ㅧࠍ᦭ߒߡ޿ࠆߥࠄ߫㉄ኈ㊂ߪ࡝ࡦ฽㊂ߩ㧞

୚ߣ⎫㤛฽㊂ߣߩ๺ߢ޽ࠆOGSIߣߥࠆߴ߈ߢ޽ࠆޕߒ߆ߒታ᷹୯ߪ⸘▚୯ ࠃࠅ߿߿ዊߐ޿ޕߎࠇߪ৻ㇱߩ⓸⚛ේሶߦ㧞୘ߩࠕࡒࡁࡔ࠴࡞ࡎࠬࡎࡦ㉄߇ዉ

౉ߐࠇߡ޿ࠆߩߢޔ ࠕࡒࡁࡔ࠴࡞ࡎࠬ

ࡎࡦ㉄ၮߩߔߴߡ ߇ℂᗐ⊛㔚᳇⊛ਛ ᕈ⒳ߣߥߞߡ޿ߥ

޿ߚ߼ߣផኤߒߡ

޿ࠆޕ

ԙ❫⛽(025ߩࠞ࡜ࡓᴺߦ߅ߌࠆ੝㋦ࠗࠝࡦๆ⌕․ᕈ

(KIWTG#ߪޔO.ߩḨẢ❫⛽(025ࠍలႯߒߚࠞ࡜ࡓߦ/⎣㉄੝㋦ṁ ᶧ㧔R*ߪ⎣㉄ߦߡߦ⺞ᢛ㧕ࠍ⒳ޘߩㅦᐲߢㅢᶧߒߚ႐วߩ੝㋦ࠗࠝࡦߩ⎕ㆊ ᦛ✢ࠍ␜ߔޕߎߎߢޔ%%_Qߪࠞ࡜ࡓᵹ಴ᶧਛߩ੝㋦Ớᐲ㧔%㧕ߣଏ⛎ᶧਛߩ੝㋦

Ớᐲ㧔%_Q㧕ߩᲧࠍ␜ߔޕ58ߪ5RCEG8GNQEKV[㧔ⓨ㑆ㅦᐲ㧕ࠍ␜ߒޔO.Jߢ␜ߐࠇ ࠆㅢᶧㅦᐲࠍࠞ࡜ࡓਛߩ❫⛽ᐥ૕Ⓧߢ㒰ߒߚㅢᶧㅦᐲ㧔න૏ߪJ㧕ࠍ⴫ߔޕ (KIWTG#ࠃࠅⓨ㑆ㅦᐲJ߹ߢߪ⎕ㆊᦛ✢ߩᒻ⁁߇߶ߣࠎߤㅢᶧㅦᐲߦଐ ሽߒߡ߅ࠄߕޔੑቭ⢻ᕈ❫⛽(025߇ᒝ㉄ᕈߢ޽ࠆR*ߦ߅޿ߡ߽ᭂ߼ߡㄦㅦߦ

੝㋦ࠗࠝࡦࠍๆ⌕ߒߡ޿ࠆߎߣ߇ࠊ߆ࠆޕ

ᴡᎹ᳓ߩR*ߪਛᕈߦㄭ޿ߩߢ/ߩ⎣㉄੝㋦᳓ṁᶧ㧔R*㧕ࠍޔⓨ㑆ㅦ ᐲJߥࠄ߮ߦJߢㅢᶧߒߚ႐วߩ⚿ᨐࠍ(KIWTG$ߦ␜ߔޕߎߩ႐ว

߽੝㋦ࠗࠝࡦߩ⎕ㆊᦛ✢ߩᒻ⁁ߪ߶ߣࠎߤㅢᶧㅦᐲߦଐሽߒߡ޿ߥ޿ޕ

%%_Q߇ߣߥࠆ߹ߢߦๆ⌕ߐࠇߚ㊄ዻࠗࠝࡦߩ❫⛽න૏㊀㊂޽ߚࠅߩๆ⌕

㊂ࠍ㧑⎕ㆊኈ㊂ߣ⒓ߔࠆ߇ޔ޿ߕࠇߩR*ߩ߅޿ߡ߽⎕ㆊኈ㊂ߪㅢᶧㅦᐲ ߩჇടߣߣ߽ߦ⧯ᐓᷫዋߔࠆ௑ะ߇ߺࠄࠇߚޕ⎕ㆊኈ㊂ߪޔR*ߩ႐ว ߢ̄OOQNIߢ޽ࠅޔR*ߩ႐วߢ̄OOQNIߢ޽ߞߚޕ ߥ߅ޔ❫⛽ߦๆ⌕ߐࠇߚ੝㋦ࠗࠝࡦߪ㧝/Ⴎ㉄ߦࠃࠅቯ㊂⊛ߦṁ㔌ߐࠇޔ❫⛽ߩ

෻ᓳ૶↪߽น⢻ߢ޽ߞߚޕᧄႎ๔ߢㅀߴࠆ⚿ᨐߪ㧝ᧄߩࠞ࡜ࡓࠍ↪޿ߡޔๆ⌕ޔ ṁ㔌ߥࠄ߮ߦౣ↢ᠲ૞ࠍ෻ᓳߒߡᓧߚ⚿ᨐߢ޽ࠆޕ

0 0.2 0.4 0.6 0.8 1

0 10 20 30 40 50 60 70 80 SV=50h^-1

SV=100h^-1 SV=200h^-1 SV=1000h^-1 C/C 0

Feed volume (mL/mL-F)

A

0 0.2 0.4 0.6 0.8 1

0 20 40 60 80 100 120

SV 1000h^-1 SV 2000h^-1 C/C 0

Feed volume (mL/mL-F)

B

Figure 1 Column-mode uptake of Zn㧔II㧕 from feeds containing 0.010 M of zinc nitrate.

pH of feeds: A 2.0 and B 5.4. Column: 2 mL of wet FNPS in hydrogen ion form. Flow rates of feeds in space velocity 㧔SV㧕 are shown in each inset.

Table 2 Effect of concentration of Zn䋨II㧕in feeds on 5 % breakthrough capacity

Concentration of Zn䋨II㧕 in feed

5 % Breakthrough point

5 % Breakthrough capacity 㧔mg/L㧕 㧔mL/L-F㧕 㧔mmol/g㧕

6.5 2360 1.3 6.5 2360 1.3 65 188 1.0 65 189 1.0 650 16.9 0.93 650 15.9 0.88 Ԛ੝㋦ࠗࠝࡦߩᏗ⭯ṁᶧ߆ࠄߩๆ⌕

੝ ㋦ ߩ ⷙ ೙ ୯ ߇ OI. ߆ ࠄ OI. ߦ ᒝ ൻߐࠇߚߩߢޔZ /㧔OI.㧕⒟

ᐲߩ੝㋦ࠗࠝࡦࠍ฽

᦭ߔࠆ᳓ߩᵺൻࠍᬌ

⸛ߒߚޕߎߩᬌ⸛ߦ߅

޿ߡߪޔࠞ࡜ࡓ߳ߩଏ

⛎ ᶧ ߩ ㅢ ᶧ ㅦ ᐲ ࠍ Jߣ৻ቯߦߒߚޕ ଏ⛎ᶧਛߩ⎣㉄੝㋦

ߩ Ớ ᐲ ࠍ ߅ࠃ߮

/ߣᄌ߃ߡ੝㋦ࠗࠝࡦߩ⎕ㆊኈ㊂ࠍ᳞߼ߚޕ⚿ᨐࠍ6CDNGߦⷐ⚂ߔࠆޕ

⎕ㆊὐߪଏ⛎ᶧਛߩ੝㋦ࠗࠝࡦỚᐲߩᷫዋߣߣ߽ߦ⧯ᐓߢߪ޽ࠆ߇Ⴧടߒߡ޿

ࠆޕOI.ߩ੝㋦ࠗࠝࡦ᳓ṁᶧࠍ↪޿ߚ႐วޔ⎕ㆊὐߪO.O.(ߢ

޽ࠆ߇ޔߎࠇߪࠞ࡜ࡓౝߩ❫⛽૕Ⓧߩ୚ߩ੝㋦ᳪᨴ᳓ߩᵺൻ߇น⢻ߢ޽ࠆ ߎߣࠍᗧ๧ߒߡ޿ࠆޕ

ᣣᧄߩᴡᎹߦ߅ߌࠆਥⷐߥ㓁ࠗࠝࡦߪࠞ࡞ࠪ࠙ࡓߣࡑࠣࡀࠪ࠙ࡓࠗࠝࡦߢ޽

ࠆޕᴡᎹ᳓߇੝㋦ࠗࠝࡦߢᳪᨴߐࠇߚ႐วࠍᗐቯߒޔߎߎߢߪᣣᧄߩਥⷐߥᴡ Ꮉ᳓ߣห࡟ࡌ࡞ߩࠞ࡞ࠪ࠙ࡓࠗࠝࡦ߹ߚߪࡑࠣࡀࠪ࠙ࡓࠗࠝࡦ߇౒ሽߔࠆ႐ว ߩᅹኂലᨐߦߟ޿ߡᬌ⸛ߒߚޕߘߩ⚿ᨐࠍ6CDNGߦ␜ߔޕࠞ࡞ࠪ࠙ࡓࠗࠝࡦ౒

ሽਅߢߪޔ<P䋨II㧕ߩ⎕ㆊὐߪ⚂O.O.(೨ᓟ߹ߢૐਅߔࠆ߇ޔࡑࠣࡀࠪ

࠙ࡓࠗࠝࡦߩᅹኂߪࠞ࡞ࠪ࠙ࡓࠗࠝࡦࠃࠅዋߥ޿ޕ߹ߚޔ੝㋦ߩឃ಴ⷙ೙୯ߢ

޽ࠆOI.߹ߢߩ⎕ㆊὐߪࠞ࡞ࠪ࠙ࡓࠗࠝࡦ౒ሽਅߢ߽O.O.(⒟ᐲߢ

޽ࠅޔࡑࠣࡀࠪ࠙ࡓࠗࠝࡦ౒ሽਅߦ߅ߌࠆOI.ߩ⎕ㆊὐߪO.O.(એ

਄ߣߥߞߚޕᧄ⎇ⓥߢ㐿⊒ߒߚ❫⛽ߪޔJߩ㜞ㅦㅢᶧ᧦ઙਅߢ߽ޔ߶ߣࠎ ߤߺࠆߴ߈ࠞ࡜ࡓ࿶៊ࠍ઻ࠊߥ޿ߣߩ․ᓽࠍ᦭ߒߡ޿ࠆޕ

એ਄ࠃࠅޔᧄ⎇ⓥߢ㐿⊒ߒߚੑቭ⢻❫⛽(025ߪᢙOI.⒟ᐲߩ੝㋦ࠗࠝࡦߢᳪ ᨴߐࠇߚ᳓ߩ㜞ㅦᵺൻߦ᦭↪ߢ޽ࠆߣᦼᓙߢ߈ࠆޕ଀߃߫ޔOߩ(025ࠍలႯߒ ߚࠞ࡜ࡓࠍ↪޿ࠇ߫ᢙRROߩ੝㋦ࠗࠝࡦߢᳪᨴߐࠇߚᴡᎹ᳓Vࠍᤨ㑆ߢᵺ ൻน⢻ߣᦼᓙߐࠇࠆޕ

ᚑᨐߩ㆐ᚑᐲ

ᒰೋ⸘↹ࠍ㆐ᚑߢ߈ߚޕ੹ᐕᐲߪޔJ߹ߢߪ⎕ㆊኈ㊂߇߶ߣࠎߤૐਅߒ ߥ޿ߣߩ㊀ⷐߥ⍮⷗ࠍᓧߚޕ⋡⊛߇⇣ߥࠆߩߢߎߩႎ๔ᦠߢߪ⸒෸ߒߡ޿ߥ޿

߇ޔ㌃䋨II㧕ߩๆ⌕ߦ߅޿ߡߪޔⓨ㑆ㅦᐲJ^㧝߹ߢㅢᶧߒߚ႐วߦߟ޿ߡ߽

ࠞ࡜ࡓ࿶៊߽ዊߐߊޔ⎕ㆊኈ㊂ߪ⧯ᐓᷫዋߔࠆ⒟ᐲߢ޽ࠆߣߩ⚿ᨐࠍᓧߡ޿ࠆޕ

឵⸒ߔࠆߣᓥ᧪ߩ᮸⢽లႯࠞ࡜ࡓߢߪᣣ߆߆ࠆㅢᶧๆ⌕ᠲ૞ࠍ௖߆㧝ᣣߢ ቢੌߢ߈ࠆߎߣࠍᗧ๧ߔࠆޕ

੹ᐕᐲߩ໧㗴ߥߤ ․ߦߥߒޕ

᧪ᐕᐲߩ⋡⊛࡮⋡ᮡ

ᰴᐕᐲߪ(025ߩᔕ↪㕙ߩ᜛ᄢߦ㑐ߔࠆᬌ⸛ߣᣂߚߦ᳓ਛߩ⎣㉄ࠗࠝࡦࠍㄦㅦ ߦๆ⌕ߔࠆ❫⛽⁁ๆ⌕೷ߩ㐿⊒߽ⴕ߁ޕ

㧚ᐔᚑᐕᐲߩ⎇ⓥ⾌ขᓧ⁁ᴫ

ਃ੗㊄ዻ㋶ᬺᩣᑼળ␠ߣߩ౒ห⎇ⓥᐕਁ౞Ớෘ㊄ዻႮṁᶧਛ ߩᓸ㊂ࡈ࠶ൻ‛ࠗࠝࡦߩ㒰෰ࠍ⋡⊛ߣߔࠆ㜞ᯏ⢻ㆬᛯๆ⌕೷ߩ㐿⊒ߦ㑐ߔ ࠆ⎇ⓥ

⽷࿅ᴺੱ㋕㍑ᬺⅣႺ଻ోᛛⴚ㐿⊒ၮ㊄ᐕਁ౞੝㋦ࠗࠝࡦࠍ㜞 ㅦߢๆ⌕ߔࠆੑቭ⢻ᕈࠠ࡟࡯࠻❫⛽ߦࠃࠆ੝㋦ᳪᨴ᳓ߩᵺൻ

Table 3 Effect of calcium and magnesium ions on uptake of zinc ion Composition of

feed^a㧕

5 % Breakthrough point of Zn䋨II㧕

5 % Breakthrough capacity for Zn䋨II㧕

2 mg/L Breakthrough point

㧔mg/L㧕 㧔mL/mL-F㧕 㧔mmol/g㧕 㧔mL/mL-F㧕

Zn䋨II㧕 6.5, Ca 10.5

945 0.62 ca 2000

1030 0.71 ca. 2000

Zn䋨II㧕 6.5, Mg 2.9

1480 0.82 More than 2000

1500 0.84 More than 2000

a㧕Flow rate of feeds was 1000 h^-1 in space velocity.

㧚ᐔᚑᐕᐲߩ⎇ⓥ⊒⴫ޔ․⸵⁁ᴫ 㧔㧕ේ⪺⺰ᢥߦࠃࠆ⊒⴫

Ԙ࿖ౝ⹹㧔๺ᢥ㧕

㧕ጟ↰ஜᴦޔἑฎౖ᣿ޔ₹↰ᱜ↵ޔၔ ᤘౖޔ❫⛽⁁ੑቭ⢻ᕈࡎࠬࡎࡦ㉄̆ࠬ

࡞ࡎࡦ㉄♽㓁ࠗࠝࡦ੤឵૕ߩ㐿⊒ߣᔕ↪ޔ,#'#4GXKGYR㧔㧕

࿖ౝ⹹㧔⧷ᢥ㧕

2㧕 Akinori Jyo, Yoshikazu Shibata, Masao Tamada, Noriaki Seko, and Akio Katakai, Development of Bifunctional Chelating Fibers with High Performance in Metal Ion Adsorption Kinetics, JAEA-Review 2006-043 p.43 䋨2007䋩.

3㧕 Akinori Jyo, Yuko Hamabe, and Yasuyuki Hirashima, Metal Ion Selectivity of Bifunctional Resin Containing Aminomethylphosphonate and Suflonate, The Proceeding of International Symposium on Ion Exchange in Korea 䋨2006䋩 and 22^nd Annual Meeting of JAIE, pp. 9-10䋨2006䋩.

4㧕 Manabu Sugimoto, Yuko Hamabe, and Akinori Jyo, Electronic Structure Study on Metal Ion Selectivity of Phosphoric and Sulfonic Acid Ion Exchange Resins, The Proceeding of International Symposium on Ion Exchange in Korea 䋨2006䋩 and 22^nd Annual Meeting of JAIE, pp. 61-62䋨2006䋩.

5㧕 Kei Tomiyasu, Shigeki Ikeda, Akinori Jyo, Tetsuya Yamaki, and Masaru Yoshida, Phosphonic Acid Type Cation Exchange Membrane Prepared by Gamma-ray Induced Graft Polymerization, The Proceeding of International Symposium on Ion Exchange in Korea 䋨2006䋩 and 22^nd Annual Meeting of JAIE, pp. 91 -92䋨2006䋩.

ԙ࿖㓙⹹㧔᰷ᢥ㧕 ߥߒ

㧔㧕ේ⪺⺰ᢥએᄖߦࠃࠆ⊒⴫

ߥߒ

㧔㧕ญ㗡⊒⴫

1䋩 Akinori Jyo, Yoshikazu Shibata, Yuki Fujii, MasaoTamada, and Akio Katakai, Bifunctional Chelating Fiber Containing Aminomethylphosphonate and Sulfonate.

233^rd American Chemical Society National Meeting, I&EC 183, March 25-29, 2007.

Chicago, IL, U.S.A.

2䋩 Akinori Jyo, Yuko Hamabe, and Yasuyuki Hirashima, Metal Ion Selectivity of Bifunctional Resin Containing Aminomethylphosphonate and Suflonate, International Symposium on Ion Exchange in Korea 䋨2006䋩 and 22^nd Annual Meeting of JAIE, October 19 – 20, 2006, Yonsei University, Seoul, Korea.

3䋩 Manabu Sugimoto, Yuko Hamabe, and Akinori Jyo, Electronic Structure Study on Metal Ion Selectivity of Phosphoric and Sulfonic Acid Ion Exchange Resins, International Symposium on Ion Exchange in Korea 䋨2006䋩 and 22^nd Annual Meeting of JAIE, October 19 – 20, 2006, Yonsei University, Seoul, Korea.

4䋩 Kei Tomiyasu, Shigeki Ikeda, Akinori Jyo, Tetsuya Yamaki, and Masaru Yoshida, Phosphonic Acid Type Cation Exchange Membrane Prepared by Gamma-ray Induced Graft Polymerization, International Symposium on Ion Exchange in Korea 䋨2006䋩 and 22^nd Annual Meeting of JAIE, October 19 – 20, 2006, Yonsei University, Seoul, Korea.

5䋩 Akinori Jyo, Yuko Hamabe, and Yasuyiki Hirashima, Synthesis and Properties of Bifucntional Chelating Resin Containing Aminomethylsulfonate and Sulfonate. 12^th International Conference on Polymers and Organic Chemsitry 2006, July 2-7, 2006, Okazaki Conference Center.

6䋩 Kazumi Nagata, Tomomi Fukunaga, Kenji Okada, Akinori Jyo, Masao Tamada, and Toshihiro Ihara, Polymer Supported Active Esters for Preparation of Functional Amides, 12^th International Conference on Polymers and Organic Chemsitry 2006, July 2-7, 2006, Okazaki Conference Center.

7䋩 Md. Rabiul Awual, Shinya Urata, Akinori Jyo, Masao Tamada, and Akio Katakai, Anion Exchange Fibers for Rapid and Selective Removal of Arsenate Species in Water, 12^th International Conference on Polymers and Organic Chemistry 2006, July 2-7, 2006, Okazaki Conference Center.

8䋩 ၔ ᤘౖޔ₹↰ᱜ↵ޔ㜞ㅦߦ㊄ዻࠍๆ⌕ߔࠆ᝝㓸೷ߩ㐿⊒㧔᜗ᓙ⻠Ṷ䋩ޔ╙

㧝࿁㜞⎿㊂ሶᔕ↪⎇ⓥࠪࡦࡐࠫ࠙ࡓޔ̆ࠗࠝࡦࡆ࡯ࡓޔ㔚ሶ✢ޔࠟࡦࡑ✢ࠍ↪

޿ߚ᧚ᢱޔࡃࠗࠝޔⅣႺ⎇ⓥ̆ޔ2006ᐕ6᦬22-23ᣣޔ㜞⎿ࠪ࠹ࠖࠡࡖ࡜࡝࡯

ࠦࠕࡎ࡯࡞

9䋩 ጟ↰ஜᴦޔἑฎౖ᣿ޔ₹↰ᱜ↵ޔၔ ᤘౖޔࡎࠬࡎࡦ㉄㧙ࠬ࡞ࡎࡦ㉄ဳੑቭ

⢻ᕈๆ⌕೷ߩวᚑߣߘߩ⹏ଔޔ╙㧝࿁㜞⎿㊂ሶᔕ↪⎇ⓥࠪࡦࡐࠫ࠙ࡓޔ̆ࠗࠝ

ࡦࡆ࡯ࡓޔ㔚ሶ✢ޔࠟࡦࡑ✢ࠍ↪޿ߚ᧚ᢱޔࡃࠗࠝޔⅣႺ⎇ⓥ̆ޔ2006ᐕ6᦬

22-23ᣣޔ㜞⎿ࠪ࠹ࠖࠡࡖ࡜࡝࡯ࠦࠕࡎ࡯࡞

10䋩 ᳰ਄ ᢥ㧘᧻ᶆඳቁ㧘੗ේᢅඳ㧘ၔ ᤘౖ㧘₹↰ᱜ↵㧘 ⽴⑺㓶, ᳓㉄ၮ ߣࠗࡒࡁੑ㈶㉄ࠍ᦭ߔࠆࠠ࡟࡯࠻❫⛽ߩ㊄ዻࠗࠝࡦಽ㔌߳ߩᔕ↪

ᣣᧄಽᨆൻቇળ╙55ᐕળ, 2006ᐕ9᦬22ᣣ, ᄢ㒋ᄢቇ⼾ਛࠠࡖࡦࡄࠬ.

11䋩 ᩊ↰⦟๺㧘᧻ᶆඳቁ㧘੗ේᢅඳ㧘ၔ ᤘౖ㧘₹↰ᱜ↵㧘 ⽴ ⑺㓶ޔࠬ࡞

ࡎࡦ㉄ߣࠕࡒࡁࡔ࠴࡞ࠬ࡞ࡎࡦ㉄ࠍ᦭ߔࠆੑቭ⢻ᕈࠠ࡟࡯࠻❫⛽ߩ੝㋦ࠗࠝࡦ ๆ⌕․ᕈ

ᣣᧄಽᨆൻቇળ╙55ᐕળ, 2006ᐕ9᦬22ᣣ, ᄢ㒋ᄢቇ⼾ਛࠠࡖࡦࡄࠬ.

12䋩 ᫪ጟ૓੺㧘᧻ᶆඳቁ㧘੗ේᢅඳ㧘ၔ ᤘౖ㧘₹↰ᱜ↵㧘 ⽴⑺㓶㧘ࠬ࡞ࡎ ࡦ㉄ߣࠗࡒࡁੑ㈶㉄ࠍ᦭ߔࠆੑቭ⢻ᕈࠠ࡟࡯࠻❫⛽ߩ㊄ዻࠗࠝࡦๆ⣕⌕․ᕈ ᣣᧄಽᨆൻቇળ╙55ᐕળ, 2006ᐕ9᦬22ᣣ, ᄢ㒋ᄢቇ⼾ਛࠠࡖࡦࡄࠬ.

13䋩 ⑺㊁⟤Ⓞ, ᧻ᶆඳቁ, ੗ේᢅඳ, ၔ ᤘౖ

ࠬ࡞ࡎࡦ㉄ߣࠗࡒࡁੑ㈶㉄ࠍ᦭ߔࠆੑቭ⢻ᕈࠠ࡟࡯࠻᮸⢽ߩ㊄ዻࠗࠝࡦಽ㔌߳

ߩᔕ↪

ᣣᧄಽᨆൻቇળ╙55ᐕળ, 2006ᐕ9᦬22ᣣ, ᄢ㒋ᄢቇ⼾ਛࠠࡖࡦࡄࠬ.

ᐔᚑᐕᐲ⎇ⓥᚑᨐႎ๔

⎇ⓥ⺖㗴ฬ㧦㊀㊄ዻ♽ⅣႺᳪᨴ‛⾰ߩήኂൻߣ⾗Ḯ࡝ࠨࠗࠢ࡞

ᚲዻ࡮᳁ฬ㧦ᄢቇ㒮⥄ὼ⑼ቇ⎇ⓥ⑼࡮ᴡේᱜᵏ

⎇ⓥ⋡⊛࡮⋡ᮡ

*ᐕᐲޯ㧝ᐕᐲߦ߅ߌࠆ⋡⊛࡮⋡ᮡ

᳓ⅣႺᳪᨴ‛⾰ߩേᘒ⹏ଔ⎇ⓥߩ৻Ⅳߣߒߡޔᓸ㊂ⅣႺᳪᨴ‛⾰ߩቯ㊂ޔਥ ߣߒߡ㊀㊄ዻߩ᜼േߦ㑐ߔࠆ⎇ⓥࠍⴕ߁ޕߔߥࠊߜޔ᳓ਛߩ᦭ኂ㊄ዻర⚛߅ࠃ

߮᦭ኂήᯏ㒶ࠗࠝࡦߩቯ㊂ߣ࿕ቯߥࠄ߮ߦ㒰෰ޔᑄ᫈‛߆ࠄߩ᦭ኂ㊄ዻర⚛ߩ

᳓߳ߩṁ಴㒐ᱛޔᑄ᫈‛ߦ฽߹ࠇࠆ㊄ዻర⚛ߩಽ㔌࡮࿁෼ߣήኂൻࠍ⋡⊛ߣߒ ߡ⎇ⓥࠍⴕ߁ޕ

*ᐕᐲߩ⋡⊛࡮⋡ᮡ

ⅣႺᳪᨴ‛⾰ߢ޽ࠆ㊀㊄ዻ߇ᴡᎹ߿ᶏߦᵹ౉ߔࠆߣᷓೞߥⅣႺ໧㗴ࠍᒁ߈⿠

ߎߔߚ߼ޔ㊀㊄ዻࠍ฽߻ᑄ᫈‛ߪ෩㊀ߦ▤ℂߐࠇߡ޿ࠆޕ߹ߚᦨㄭߢߪޔᦨ⚳

ಣಽ႐ߩㅼㄼߣᓴⅣဳ␠ળ᭴▽ߩⷰὐ߆ࠄޔᑄ᫈‛ߩ᦭ല೑↪߇᳞߼ࠄࠇߡ޿

ࠆޕᧄ⎇ⓥߢߪޔߐ߹ߑ߹ߥᑄ᫈‛߆ࠄ᦭ଔ㊄ዻࠍ࿁෼ߒޔᑄ᫈‛ࠍήኂൻߔ ࠆߚ߼ߩࡊࡠ࠮ࠬߦߟ޿ߡᬌ⸛ࠍട߃ߡ޿ࠆޕ೨ᐕᐲ߹ߢߪޔ৻⥸ᑄ᫈‛ࠍ὾

ළߒߚᤨߦ⊒↢ߔࠆ㘧Ἧߥࠄ߮ߦ὾ළἯࠍṁⲢಣℂߒߚ㓙ߦ⊒↢ߔࠆṁⲢ㘧Ἧ ࠍήኂൻߔࠆߣหᤨߦޔ᦭ଔ㊄ዻࠍ࿁෼ߔࠆߚ߼ߩ㉄ߦࠃࠆᶐ಴ࡊࡠ࠮ࠬߣᶐ

಴⾆ᶧ߆ࠄߩᴉᲚಽ㔌ᴺߦࠃࠆ㊄ዻ࿁෼ߦ㑐ߔࠆ⎇ⓥࠍⴕߞߚޕᧄᐕᐲߪޔ㋕

ࠬࠢ࡜࠶ࡊࠍౣṁ⸃ߒߡ࡝ࠨࠗࠢ࡞ߔࠆᤨߦ⊒↢ߔࠆޟ㔚᳇Ἱ࠳ࠬ࠻ޠ߆ࠄḨ ᑼಣℂߦࠃߞߡ᦭ଔ㊄ዻࠍ࿁෼ߒޔ࠳ࠬ࠻ࠍήኂൻߔࠆߚ߼ߩ㉄ߦࠃࠆᶐ಴ߣ ᴉᲚಽ㔌ᴺߦࠃࠆ㊄ዻߩ࿁෼ࡊࡠ࠮ࠬߦߟ޿ߡᬌ⸛ࠍട߃ߚޕ

ᐔᚑᐕᐲߩ⎇ⓥᚑᨐ Ԙ⹜ᢱ

⴫㧝ߦޔᧄ⎇ⓥߦ↪޿ߚ㔚᳇Ἱ࠳ࠬ࠻ߩ⚵ᚑࠍ␜ߔޕ⹜ᢱߩ㔚᳇Ἱ࠳ࠬ࠻ߦ ߪ੝㋦߇ 㨪㧑฽߹ࠇߡ߅ࠅޔߎࠇߪචಽߦ੝㋦ߩ࿁෼ኻ⽎ߦߥࠆຠ૏ߢ޽

ࠆޕ߹ߚޔหᤨߦ㋦߽ 㨪㧑฽߹ࠇߡ޿ࠆߚ߼ޔߎߩಣℂ߇໧㗴ߣߥࠆޕ

੹࿁ߩ⎇ⓥߢߪޔߎࠇࠄߩ㔚᳇Ἱ࠳ࠬ࠻ߦ฽߹ࠇࠆ੝㋦ޔ㋦߅ࠃ߮㋕ߩ᜼േߦ ߟ޿ߡᬌ⸛ࠍട߃ߚޕ

࿑㧝ߦߪޔFWUV$ ߩ : ✢࿁᛬⚿ᨐࠍ␜ߔޕઁߩ࠳ࠬ࠻ߩ : ✢࿁᛬⚿ᨐ߽ห᭽ߢ

޽ࠅޔ㔚᳇Ἱ࠳ࠬ࠻ߪࠫࡦࠢࡈࠚ࡜ࠗ࠻߇ਥ૕ߢ޽ࠆߎߣ߇ಽ߆ࠆޕઁߩࡇ࡯

ࠢߪⷰኤߐࠇߥ߆ߞߚ߇ޔ㔚᳇Ἱ࠳ࠬ࠻ਛߩ㊄ዻర⚛ߪޔߘߩᄙߊ߇㉄ൻ‛ߩ ᒻߢሽ࿷ߒߡ޿ࠆߎߣ߇⍮ࠄࠇߡ޿ࠆޕ

Zn Pb Fe Al Co Mn Ni

dust A 12.53 0.384 32.4 0.51 0.025 2.04 0.17

dust B 13.48 0.686 37 0.41 0.019 3.12 0.12

dust C 9.2 0.636 39.4 0.41 0.017 2.8 0.21

Mg Si Ca Cr S Cl F

dust A 1.28 1.61 6.59 0.6 0.44 0.82 4.12

dust B 1.12 1.28 6.21 0.55 0.42 0.53 3.74

dust C 1.16 1.2 7.02 0.76 0.43 0.51 3.71

Zn Pb Fe Al Co Mn Ni

dust A 12.53 0.384 32.4 0.51 0.025 2.04 0.17

dust B 13.48 0.686 37 0.41 0.019 3.12 0.12

dust C 9.2 0.636 39.4 0.41 0.017 2.8 0.21

Mg Si Ca Cr S Cl F

dust A 1.28 1.61 6.59 0.6 0.44 0.82 4.12

dust B 1.12 1.28 6.21 0.55 0.42 0.53 3.74

dust C 1.16 1.2 7.02 0.76 0.43 0.51 3.71

Intensity (arb. unit)

2ǰ(degrees)

Cu Kα

ZnO䊶Fe₂O₃

20 30 40 50 60 70 80

Intensity (arb. unit)Intensity (arb. unit)

2ǰ(degrees)

Cu Kα

ZnO䊶Fe₂O₃

20 30 40 50 60 70 80

ԙ㉄ᶐ಴

࿑㧞ߦޔFWUV$ ࠍ⎣㉄ᶐ಴ߒߚߣ߈ߩ⎣㉄Ớᐲߣฦర⚛ߩᶐ಴₸ߣߩ㑐ଥࠍ␜

ߔޕ⎣㉄ᶐ಴ߢߪޔߔߴߡߩర⚛߇Ყセ⊛㜞޿ഀวߢᶐ಴ߐࠇߚޕ

࿑㧟ߦߪޔหߓ࠳ࠬ࠻ࠍ⎫㉄ᶐ಴ߒߚߣ߈ߩ⎫㉄Ớᐲߣฦర⚛ߩᶐ಴₸ߣߩ㑐 ଥࠍ␜ߒߚޕ⎣㉄ᶐ಴ߢߪ㋦ߩᶐ಴₸߇ઁߩర⚛ࠃࠅ߽㜞߆ߞߚ߇ޔ⎫㉄ᶐ಴

ߢߪ⎣㉄ᶐ಴ߣߪ⇣ߥࠅޔ㋦ߩᶐ಴߇ૐߊᛥ߃ࠄࠇߚޕߎࠇߪޔ⎫㉄ࠍ↪޿ࠆ ߣޔ㋦߇ṁ⸃ᐲߩዊߐߥ⎫㉄㋦ߦߥࠆߚ߼ߣ⠨߃ࠄࠇࠆޕ

࿑㧝 FGUV$ ߩ : ✢࿁᛬⚿ᨐ

⴫ ⹜ᢱߩൻቇಽᨆ⚵ᚑ

0 20 40 60 80 100

10 30 50 70 90

Zn Pb Fe

0 20 40 60 80 100

10 30 50 70 90

Zn Pb Fe 0

20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

Zn Pb Fe

0 20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

Zn Pb Fe

࿑㧞FWUV$ ࠍ⎣㉄ᶐ಴ߒߚߣ߈ߩ⎣㉄࿑㧟FWUV$ ࠍ⎫㉄ᶐ಴ߒߚߣ߈ ߩ⎫㉄Ớᐲߣฦర⚛ߩᶐ಴₸ߣߩ㑐ଥỚᐲߣฦర⚛ߩᶐ಴₸ߣ ߩ㑐ଥ

࿑㧠ߦޔFWUV$ ࠍ⎣㉄ᶐ಴ߒߚߣ߈ߩᶐ಴᷷ᐲߣฦర⚛ߩᶐ಴₸ߣߩ㑐ଥࠍ␜

HNO3 concentration 㧔mol/l㧕 H2SO4 concentration 㧔mol/l㧕

Leaching temperature Leaching temperature

Leaching percentage (%) Leaching percentage (%)Leaching percentage (%)

Leaching percentage (%)

࿑㧠FWUV$ ࠍ⎣㉄ᶐ಴ߒߚߣ߈ߩᶐ಴

᷷ᐲߣฦర⚛ߩᶐ಴₸ߣߩ㑐ଥ

࿑㧡FWUV$ ࠍ⎫㉄ᶐ಴ߒߚߣ߈ߩᶐ಴

᷷ᐲߣฦర⚛ߩᶐ಴₸ߣߩ㑐ଥ

Leaching percentage (%)

0 20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

䏇䏘䏖䏗䎃䎤 䏇䏘䏖䏗䎃䎥 䏇䏘䏖䏗䎃䎦

HNO₃concentration

Leaching percentage (%)

0 20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

䏇䏘䏖䏗䎃䎤 䏇䏘䏖䏗䎃䎥 䏇䏘䏖䏗䎃䎦

HNO₃concentration

Leaching percentage (%)

0 20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

䏇䏘䏖䏗䎃䎤 䏇 䏘䏖䏗䎃䎥 䏇 䏘䏖䏗䎃䎦

H₂SO₄concentration

Leaching percentage (%)

0 20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

䏇䏘䏖䏗䎃䎤 䏇 䏘䏖䏗䎃䎥 䏇 䏘䏖䏗䎃䎦

Leaching percentage (%)

0 20 40 60 80 100

0 0.5 1 1.5 2 2.5 3 3.5

䏇䏘䏖䏗䎃䎤 䏇 䏘䏖䏗䎃䎥 䏇 䏘䏖䏗䎃䎦

H₂SO₄concentration

ߔޕ߹ߚޔ࿑㧡ߦߪޔหߓ࠳ࠬ࠻ࠍ⎫㉄ᶐ಴ߒߚߣ߈ߩᶐ಴᷷ᐲߣฦర⚛ߩᶐ

಴₸ߣߩ㑐ଥࠍ␜ߒߚޕߤߜࠄߩ㉄ߦ߅޿ߡ߽ޔ੝㋦ߣ㋕ߩᶐ಴₸ߦ෸߷ߔᶐ

಴᷷ᐲߩᓇ㗀ߪᄢ߈ߊޔ․ߦ⎫㉄ᶐ಴ߦ߅ߌࠆ㋕ߩᶐ಴₸ߪޔቶ᷷ߢߪ 㧑⒟

ᐲߢ޽ߞߚ߽ߩ߇ޔ͠ߢߪ⚂ 㧑ߦ㆐ߒߚޕ⎣㉄ᶐ಴ߦ߅ߌࠆ㋦ߩᶐ಴₸ߦ

෸߷ߔᶐ಴᷷ᐲߩᓇ㗀ߪ߶ߣࠎߤߥߊޔ⎣㉄ᶐ಴ߢߪޔቶ᷷ߢ߽㋦ߪ߶ߣࠎߤ ᶐ಴ߐࠇߚޕ৻ᣇޔ⎫㉄ᶐ಴ߢߪޔ㜞᷷ߦ߅޿ߡ߽㋦ߪ߶ߣࠎߤᶐ಴ߐࠇߥ߆ ߞߚޕ

⎣㉄ᶐ಴ߢߪ㋦߇ఝవ⊛ߦᶐ಴ߐࠇޔ⎫㉄ᶐ಴ߢߪ㋦߇ᶐ಴ߐࠇߥ޿ߎߣ߆ ࠄޔ㔚᳇Ἱ࠳ࠬ࠻߆ࠄ㋦ࠍ㒰෰ߒߡήኂൻߔࠆߚ߼ߦߪޔ⎣㉄ᶐ಴߇᦭ലߢ޽

ࠆߣ⠨߃ࠄࠇࠆޕ৻ᣇޔ᦭ଔ㊄ዻߩ࿁෼ߩὐߢߪޔ⹜⮎ߩଔᩰ߇቟ߊޔ߆ߟㆬ

ᛯᶐ಴߇น⢻ߥ⎫㉄ᶐ಴ߩᣇ߇᦭೑ߢ޽ࠆߣ⠨߃ࠄࠇࠆޕߚߛߒޔ⎫㉄ᶐ಴ߩ ႐วߪޔ฽㋦ᱷᷲࠍಣℂߔࠆᔅⷐ߇↢ߓࠆޕߐࠄߦޔ㋦ߩᶐ಴᜼േ߇੝㋦߿㋕

ߣ⇣ߥߞߡ޿ࠆߎߣ߆ࠄޔ࠳ࠬ࠻ਛߩ㋦ߪޔ੝㋦߿㋕ߣߪ೎⋧ࠍᒻᚑߒߡ޿ࠆ ߣ⠨߃ࠄࠇࠆޕ߹ߚޔ㋕߇޽߹ࠅᶐ಴ߐࠇߥ޿᧦ઙߢ߽੝㋦߇޽ࠆ⒟ᐲᶐ಴ߐ ࠇߡ޿ࠆߎߣ߆ࠄޔ੝㋦ߩ⚂ 㧑ߪࠫࡦࠢࡈࠚ࡜ࠗ࠻ߢߪߥߊޔ㉄ߦṁߌ߿ߔ

޿☻㉄ൻ੝㋦ߣߒߡሽ࿷ߒߡ޿ࠆߣផኤߐࠇࠆޕ޿ߕࠇߦߒߡ߽ޔ੝㋦ߩᶐ಴

ࠍቢోߦⴕ߁ߚ߼ߦߪޔࠫࡦࠢࡈࠚ࡜ࠗ࠻߇ಽ⸃ߔࠆᶐ಴᧦ઙߦߒߥߌࠇ߫ߥ ࠄߥ޿ߎߣ߇ಽ߆ߞߚޕ

Ԛ࠳ࠬ࠻⚵ᚑߦࠃࠆᶐ಴᜼േߩ㆑޿

࿑㧢⚵ᚑߩ⇣ߥࠆ࠳ࠬ࠻ߦ߅ߌࠆ⎣㉄

ᶐ಴ᤨߩ⎫㉄Ớᐲߣ੝㋦ߩᶐ಴₸

࿑㧣⚵ᚑߩ⇣ߥࠆ࠳ࠬ࠻ߦ߅ߌࠆ⎫㉄

ᶐ಴ᤨߩ⎣㉄Ớᐲߣ੝㋦ߩᶐ಴₸

0 20 40 60 80 100

0 1 2 3 4 5 6 7

Zn Fe

0 20 40 60 80 100

0 1 2 3 4 5 6 7

Zn Pb Fe

࿑㧢ߦ⚵ᚑߩ⇣ߥࠆ࠳ࠬ࠻ࠍ⎣㉄ᶐ಴ߒߚߣ߈ߩޔ⎣㉄Ớᐲߣ੝㋦ߩᶐ಴₸

ߣߩ㑐ଥࠍ␜ߔޕ߹ߚޔ࿑㧣ߦߪޔ⚵ᚑߩ⇣ߥࠆ࠳ࠬ࠻ࠍ⎫㉄ᶐ಴ߒߚߣ߈ߩޔ

⎫㉄Ớᐲߣ੝㋦ߩᶐ಴₸ߣߩ㑐ଥࠍ␜ߒߚޕ޿ߕࠇߩ႐ว߽ޔ੝㋦ߩᶐ಴₸ߩ

࠳ࠬ࠻⚵ᚑߦࠃࠆ㆑޿ߪ޽߹ࠅ⷗ࠄࠇߥ߆ߞߚޕ߹ߚޔઁߩ㊄ዻర⚛ߩᶐ಴᜼

േߦߟ޿ߡ߽ޔ࠳ࠬ࠻ߩ⒳㘃ߦࠃࠆ㆑޿ߪ߶ߣࠎߤ⷗ࠄࠇߕޔᧄᴺߪ⚵ᚑߩ⇣

ߥࠆ࠳ࠬ࠻ߦ߽ㆡᔕน⢻ߢ޽ࠆߣᕁࠊࠇࠆޕ

ԛᴉᲚಽ㔌

࿑㧤ߦޔFWUV$ ࠍ⎣㉄ᶐ಴ߒߡᓧࠄࠇߚ⾆ᶧࠍ὇㉄ࠞ࡞ࠪ࠙ࡓߢ R* ⺞ᢛߒߚ ߣ߈ߩޔṁᶧߩ R* ߣฦర⚛ߩᱷሽ₸ࠍ␜ߔޕ὇㉄ࠞ࡞ࠪ࠙ࡓߢṁᶧߩ R* ࠍ਄

ߍߡ޿ߊߣޔవߕ㋕߇ᴉᲚߒᆎ߼ޔ㋕ߪ R* ⚂ ߢṁᶧਛ߆ࠄ߶߷ቢోߦᴉᲚ 㒰෰ߐࠇߚޕ㋦ߩᴉᲚߪ R* ⚂㧟߆ࠄᆎ߹ࠅޔR* ⚂ ߢޔ߶ߣࠎߤߩ㋦߇ᴉᲚ ߒߚޕ㋕ߣ㋦߇ṁᶧਛ߆ࠄᴉᲚ㒰෰ߐࠇࠆ R* ߢ߽ޔ⚂ 㧑ߩ੝㋦߇ṁᶧਛߦᱷ ሽߒߡ޿ߚޕ

࿑㧥ߦߪޔFWUV$ ࠍ⎫㉄ᶐ಴ߒߡᓧࠄࠇߚ⾆ᶧࠍ᳓㉄ൻ࠽࠻࡝࠙ࡓߢ R* ⺞ᢛ ߒߚߣ߈ߩޔṁᶧߩ R* ߣฦర⚛ߩᱷሽ₸ࠍ␜ߔޕߎߎߢ㋦ߩ᜼േࠍ␜ߒߡ޿ߥ

޿ߩߪޔ⎫㉄ᶐ಴ߢߪ⾆ᶧਛߦ㋦߇߶ߣࠎߤ฽߹ࠇߡ޿ߥ޿ߚ߼ߢ޽ࠆޕ߹ߚޔ

⎫㉄ᶐ಴⾆ᶧߩ R* ⺞ᢛߦ὇㉄ࠞ࡞ࠪ࠙ࡓࠍ૶ࠊߥ߆ߞߚℂ↱ߪޔ὇㉄ࠞ࡞ࠪ࠙

ࡓࠍ R* ⺞ᢛߦ↪޿ࠆߣ⍹⤉߇↢ᚑߒޔ࿕ᶧಽ㔌߇࿎㔍ߦߥࠆߚ߼ߢ޽ࠆޕ⎫㉄

ᶐ಴⾆ᶧߩ R* ࠍ᳓㉄ൻ࠽࠻࡝࠙ࡓߢ਄ߍߡ޿ߊߣޔవߕ㋕߇ᴉᲚߒᆎ߼ޔ㋕ߪ R* ⚂ ߢṁᶧਛ߆ࠄ߶߷ቢోߦᴉᲚ㒰෰ߐࠇߚޕߎߩ R* ߢޔ੝㋦ߩ⚂ 㧑 ߇ṁᶧਛߦᱷሽߒߡ޿ߚޕ

ߎࠇࠄߩ⚿ᨐ߆ࠄޔ㉄ᶐ಴ߣᴉᲚಽ㔌ࠍ↪޿ߡޔ㔚᳇Ἱ࠳ࠬ࠻߆ࠄ㊄ዻర⚛

ࠍ࿁෼ߔࠆߎߣ߇ߢ߈ࠆߣ್ᢿߐࠇࠆޕ

pH

Extant percentage (%) Extant percentage (%)

pH

ᚑᨐߩ㆐ᚑᐲ

੹ᐕᐲߪޔ㔚᳇Ἱ࠳ࠬ࠻߆ࠄߩ㊄ዻ࿁෼ߦᚑഞߒߚߚ߼ޔ⋡ᮡߪචಽ㆐ᚑߢ ߈ߚߣ⠨߃ߡ޿ࠆޕ

੹ᐕᐲߩ໧㗴ߥߤ ․ߦߥߒޕ

᧪ᐕᐲߩ⋡⊛࡮⋡ᮡ

᧪ᐕᐲߪޔ੝㋦Ḩᑼ⵾㍰ߢ⊒↢ߔࠆᵺᶧṗ߆ࠄߩࠦࡃ࡞࠻ߩ࿁෼ߦߟ޿ߡᬌ

⸛ߒޔ৻ㅪߩᑄ᫈‛߆ࠄߩ㊄ዻ࿁෼ߣήኂൻߦ㑐ߔࠆ⎇ⓥࠍⴕ߁੍ቯߢ޽ࠆޕ

㧚ᐔᚑᐕᐲߩ⎇ⓥ⾌ขᓧ⁁ᴫ ߥߒ

㧚ᐔᚑᐕᐲߩ⎇ⓥ⊒⴫ޔ․⸵⁁ᴫ 㧔㧕ේ⪺⺰ᢥߦࠃࠆ⊒⴫

Ԙ ࿖ౝ⹹㧔๺ᢥ㧕

Ꮧ⎫㉄ᶐ಴̆ṁᇦ᛽಴ߦࠃࠆᷙวࡔ࠶ࠠࠬ࡜࠶ࠫ߆ࠄߩ᦭ଔ㊄ዻߩಽ㔌㧦ᴡ

ේᱜᵏޔ⼾⑔⑲ᓼޔJ of MMIJޔ╙123Ꮞޔ╙1ภޔ45-49㗁㧔2007㧕

ԙ࿖㓙⹹㧔᰷ᢥ㧕

Effect of Dense Layer Formation on Dissolution Rate of MgO-C Refractory in Molten Slag㧦Hiroyuki SUNAYAMA and Masayasu KAWAHARA㧘 Advances in Science and Technology㧘Vol. 45㧘pp. 162-165㧔2006㧕 Oxidation Rate of Magenesia-Carbon Refractory with Aluminum Additive

Hiroyuki SUNAYAMA and Masayasu KAWAHARA㧘Materials Science Forum㧘Vol㧚 522㧘pp. 603-607㧔2006㧕

㧔㧕ේ⪺⺰ᢥએᄖߦࠃࠆ⊒⴫

ߥߒ

㧔㧕ญ㗡⊒⴫

㧝㧚Mg-Zn-Y ว㊄ߩ⌀ⓨ⫳⇐ߦࠃࠆ࡝ࠨࠗࠢ࡞ߣYߩ࿁෼㧦ᴡේ ᱜᵏޔ╙18࿁

㜞ᕈ⢻Mgว㊄ഃᚑടᎿ⎇ⓥળޟࡑࠣࡀࠪ࠙ࡓว㊄ߩ⠴㘩ᕈߣ࡝ࠨࠗࠢ࡞ޠޔ

pp. 35-37㧔2006㧕 ઁ

ᐔᚑ ᐕᐲ ᜚ὐ $ ࿖㓙ࠪࡦࡐࠫ࠙ࡓႎ๔

⋡⊛

᦭᣿ᶏ߿౎ઍᶏ╬ߩౝḧᕈᶏၞߦ߅ߌࠆንᩕ㙃ൻේ࿃ߩ৻ߟߣߒߡޔ๟ㄝ㒽

ၞ߆ࠄߩ࿾ਅ᳓ࠍ⚻↱ߣߒߚⅣႺ‛⾰⽶⩄ߩ⚻〝߇਎⇇⊛ߦᵈ⋡ߐࠇࠆࠃ߁ߦ ߥߞߡ߈ߡ޿ࠆޕ* ᐕᐲߩ᜚ὐ $ ࿖㓙ࠪࡦࡐࠫ࠙ࡓߢߪᶏጯ෸߮ᶏᐩਅߦ߅ߌ ࠆ࿾ਅ᳓ߩታᘒߣߘࠇࠄࠍᛠីߔࠆߚ߼ߩฦ⒳ᚻᴺޔ߅ࠃ߮ᩕ㙃Ⴎ⽶⩄ߩታᘒ ߦ㑐ߒߡޔ࿖ౝᄖߩኾ㐷ኅߦࠃࠆኒᐲߩỚ޿⸛⼏ࠍⴕ߁ߎߣࠍ⋡⊛ߣߒߡታᣉ ߒߚޕ᜗⡜੍ቯ⠪ߩᄢඨߪޔ᜚ὐ㧔㧮㧕ߩࡔࡦࡃ࡯ᢎቭߢ޽ࠆ᎑↰ߩ⑼⎇⾌ၮ

⋚㧔#㧕㧔* ⚳ੌ㧕ߩ᭴ᚑࡔࡦࡃ࡯ߢ޽ߞߚ࿖ౝ㑐ㅪᄢቇߩ⎇ⓥ⠪߅ࠃ߮ᶏᄖߩ 㑐ㅪ⎇ⓥ⠪ߢ޽ࠅޔߎࠇߦട߃ߡዊᳰᢎ᝼߅ࠃ߮ߘߩ㑐ㅪ࿖ᄖ⎇ⓥ⠪ࠍวࠊߖ ߡ㐿௅ߒߚޕ

ࡊࡠࠣ࡜ࡓ

ᾢᧄᄢቇ᜚ὐᒻᚑࠣ࡞࡯ࡊ㧔B㧕ޡ᳓ⅣႺᳪᨴ‛⾰ߩേᘒ⹏ଔ⎇ⓥޢ࡮࿖㓙ࠪࡦ ࡐࠫ࠙ࡓ

ޡ㒽᳓̆ᶏ᳓ࠗࡦ࠲࡯࡜࡚ࠢࠪࡦ㗔ၞߩታᘒߣ࿾ਅ᳓ࠍ⚻↱ߒߚᶏၞ߳ߩⅣႺ

⽶⩄ޢ

International Symposium on “Interrelations between seawater and groundwater in the coastal zone and their effect on the environmental nutrient load toward the sea”

ᣣᤨ㧦ᐔᚑ ᐕ ᦬ ᣣ㧔㊄㧕 ᤨ㨪 ᤨ

႐ᚲ㧦ᾢᧄᄢቇᎿቇㇱ ๟ᐕ⸥ᔨ㙚㧔ᾢᧄᏒ㤥㜬 ᾢᧄᄢቇ㤥㜬ධࠠ

ࡖࡦࡄࠬ㧕

ਥ௅㧦ᾢᧄᄢቇޔᾢᧄᄢቇ᜚ὐᒻᚑࠣ࡞࡯ࡊ㧔B㧕ޡ᳓ⅣႺᳪᨴ‛⾰ߩേᘒ⹏ଔ

⎇ⓥޢ

౒௅㧦ᾢᧄᄢቇᄢቇ㒮ޡ㝯ജ޽ࠆᄢቇ㒮ࠗ࠾ࠪࠕ࠹ࠖࡉޢ․೎ᢎ⢒㩖㩩㩥㩂㩨㩡㩛 ᓟេ㧦ᣣᧄ࿾ਅ᳓ቇળޔᣣᧄ᳓ᢥ⑼ቇળޔᣣᧄᔕ↪࿾⾰ቇળ਻Ꮊᡰㇱ㧔਻Ꮊᔕ

↪࿾⾰ቇળ㧕

ෳട⾌㧦ήᢱ

㧦㧙㧦 ฃઃޔෳട⊓㍳

㧦 㐿ળߩㄉ ቟ㇱ⌀৻㧔2TQH5#DGᾢᧄᄢቇᢎ᝼࡮᜚ὐࠣ࡞࡯ࡊ ઍ⴫㧕

㧦 ᱑ㄫߩ⸒⪲ ⷏ጊᔘ↵㧔8KEG2TGUKFGPV2TQH60KUJK[COCᾢᧄ ᄢቇ࡮೽ቇ㐳㧕

ޝ࠮࠶࡚ࠪࡦ ޞ㧔มળ㧦ዊᳰస᣿2TQH--QKMG㧕

㧦㧦 Importance of the Submarine Groundwater discharge㧔SGD㧕 and the evaluation of the SGD evident by using Natural Rn content㧔ᶏᐩ࿾

ਅ᳓ḝ಴⃻⽎ߩ㊀ⷐᕈߣ࡜࠼ࡦࠍ↪޿ߚḝ᳓⃻⽎ߩ⹏ଔ㧕 㧔MG[PQVGURCTMGT㧕 ࡈࡠ࡝࠳Ꮊ┙ᄢቇ 2TQH9$WTPGVV 㧦㧦 Submarine groundwater discharge in Japanese coastal area㧔ᚒ߇࿖

ߦ߅ߌࠆᶏᐩ࿾ਅ᳓ḝ᳓⃻⽎ߩታᘒᛠី㧕✚ว࿾⃿ⅣႺቇ⎇

ⓥᚲ ഥᢎ᝼ ⼱ญ⌀ੱ

㧦㧦 Regional groundwater flow system study in the pyroclastic aquifer

including SGD㧔Ἣጊጤ♽ᵹၞߦ߅ߌࠆᐢၞ࿾ਅ᳓ᵹേߣᶏᐩ

࿾ਅ᳓ḝ಴ߩቯ㊂⊛⹏ଔ㧕ᾢᧄᄢቇ ᢎ᝼ ᎑↰ ⚐

ᤤ㘩 㧔㧦㧦㧕ࡐࠬ࠲࡯⊒⴫Ԙ

ޝ࠮࠶࡚ࠪࡦ ޞ㧔มળ㧦⼱ญ⌀ੱ2TQH/6CPKIWEJK㧕

㧦㧦 Evidence and the flow regime of the submarine fresh groundwater in the Yatsushiro bay, Japan㧔ᶏᐩਅߩ᷆᳓ᕈ࿾ਅ᳓᜼േߩታᘒ㧕

᧲੩ᄢቇ ഥᢎ᝼ ᓼ᳗᦮␽

㧦㧦Nutrient load through SGD to the Seto inland sea—case study at a small granite island̆㧔ἑᚭౝᶏዊፉߦ߅ߌࠆᶏᐩ࿾ਅ᳓⚻↱ߩ ᶏၞ߳ߩᩕ㙃Ⴎ⽶⩄ߩታᘒ㧕 ᐢፉᄢቇ ഥᢎ᝼ ዊ㊁ኹ⌀

৻

㧦 㧦 Environmental and Ecological Consequences of Submarine Groundwater Discharge 㧔SGD㧕 in the Coastal Ocean㧔㖧ඨፉᴪጯ

ၞߦ߅ߌࠆᶏᐩḝ಴⃻⽎ߩⅣႺ↢ᘒቇ⊛⹏ଔ㧕㧔Invited foreign

speaker㧕࠰࠙࡞ᄢቇ #UU2TQH)-KO

%QHHGGDTGCM㧔㧦㨪㧦㧕 ࡐࠬ࠲࡯⊒⴫ԙ ޝ࠮࠶࡚ࠪࡦ ޞ㧔มળ㧦ᓼ᳗᦮␽2TQH66QMWPCIC㧕

㧦㧙㧦 Modeling of Suspended Sediment Transport in Estuary of Mahakam, East Kalimantan – Indonesia㧔᧲ࡏ࡞ࡀࠝޔࡑࡂࠞࡓᴪጯၞߦ߅ߌ ࠆᶋㆆ‛⾰ャㅍࡕ࠺࡞㧕

㧔Invited foreign speaker㧕ࡃࡦ࠼ࡦᎿ⑼ᄢቇ &T0KPKPI5CTK 0KPIUKJ

㧦㧦 Evaluation of Submarine groundwater discharge by using resistively survey on the sea bottom floor of Ariake sea, Japan㧔᦭᣿ᶏߦ߅ߌࠆ Ყᛶ᛫តᩏࠍ↪޿ߚᶏᐩḝ಴⃻⽎ߩ⹏ଔ㧕 ᾢᧄᄢቇ ᢎ᝼

ዊᳰస᣿

Panel 㧔Wrap-up㧕 Discussion㧔✚ว⸛⼏㧕㧔㧦㧦㧕Moderator: Prof. J.

Shimada 㧔ㅴⴕ᎑↰ ⚐㧕

㧦 㐽ળߩㄉ ฎᎹᙗᴦ㧔2TQH-(WTWMCYCᾢᧄᄢቇᢎ᝼࡮᜚ὐࠣ࡞࡯

ࡊ೽ઍ⴫㧕 ᙣⷫળ 㧦 ޝᬮળ㙚ޞ

ෳട⁁ᴫ

ቇౝෳട⠪㧦 ฬ

ቇᄖෳട⠪㧦 ฬ㧔ᾢᧄ⋵ౝ㧦 ฬޔ⋵ᄖ㧦 ฬ㧕 ว⸘㧦 ฬ

SGD ࿖㓙ࠪࡦࡐࠫ࠙ࡓ᳿▚ 2006.12.27 ᎑↰ ⚐

౉㊄

㝯ജ޽ࠆᄢቇ㒮ࠗ࠾ࠪࠕ࠹ࠖࡉ⚻⾌㧔ᣏ⾌࡮⻢㊄㧕 㧝㧝㧜ਁ౞

ห਄ 㧔࿖㓙ࠪࡦࡐࠫ࠙ࡓេഥ㧕 㧡㧜ਁ౞

ᾢᧄ㩄㩧㩗㩨㩧㩆㨸㩧ࡆࡘ࡯ࡠ࡯ 㧝㧜ਁ౞

ว⸘㧝㧣㧜ਁ౞

ᡰ಴

ࡐࠬ࠲࡯ශ೚㧔ࡎ࡯ࡊශ೚㧕㧔10/2㧕 㧣㧝,㧠㧜㧜౞

Proceedings ශ೚㧔ࡎ࡯ࡊශ೚ޔ200ㇱ㧕㧔12/20㧕 㧟㧢㧡,㧠㧜㧜౞

ᮮᢿ᐀࡮┙ߡ⋴᧼㧔ࡎ࡯ࡊශ೚㧕㧔12/22㧕 㧢㧞,㧜㧜㧜౞

ዊ⸘㧠㧥㧤,㧤㧜㧜౞

ᄖ࿖ੱᣏ⾌㧔Prof. Burnett㧕 㧠㧜㧝,㧞㧥㧡౞

㧔Prof. Kim㧕 㧤㧝,㧢㧜㧤౞

㧔Dr.Nining㧕 㧝㧣㧝,㧜㧟㧠౞

ᣣᧄੱᣏ⾌㧔᭎▚㧕 㧞㧞㧜,㧜㧜㧜౞

ᄖ࿖ੱ⻠Ṷ⻢㊄㧔㧬㧠ਁ౞㧕 㧟ੱ 㧝㧞㧜,㧜㧜㧜౞

ᣣᧄੱ⻠Ṷ⻢㊄㧔㧬㧞ਁ౞㧕 㧟ੱ 㧢㧜,㧜㧜㧜౞

ዊ⸘㧝,㧜㧡㧟,㧥㧟㧣౞

ࡐࠬ࠲࡯㒮↢ኋᴱ⾌㧔⍮๮ၴ㧕 㧬4600 㧟ฬ 㧝㧟,㧤㧜㧜౞

ห਄㧔ᣏ⾌⵬ഥ㧕 㧔੩ㇺޔᐢፉޔඳᄙ㧕 㧡㧡,㧜㧜㧜౞

ห਄ᙣⷫળ⾌㧔฽߻ᄖ࿖ੱᙣⷫળ⾌㧟ฬಽ㧕 㧞㧡,㧝㧟㧠౞

ᄖ࿖ੱᤤ㘩ᑯᒰઍ㧔㧟ฬޔ฽߻߅⨥ઍ㧝㧜ฬಽ㧕 㧠,㧝㧜㧜౞

ዊ⸘㧥㧤,㧜㧟㧠౞

ߘߩઁ 㧠㧥,㧞㧞㧥౞

ว⸘ 㧣㧜㧜,㧜㧜㧜౞

ᚑᨐ

ᧄࠪࡦࡐࠫ࠙ࡓࠍㅢߒߡޔ᜚ὐ $ ߢⴕࠊࠇߡ޿ࠆ⎇ⓥߩታᘒ߇ቇౝߦᶐㅘߔ ࠆߣ౒ߦޔෳട⠪߅ࠃ߮㑐ㅪ⎇ⓥ⠪㑆ߦ࿾ਅ᳓ࠍᇦ੺ߣߒߚᩕ㙃Ⴎߩᶏၞ߳ߩ

⽶⩄ߩ౒ㅢ᭎ᔨ߇ᒻᚑߐࠇߚ⚿ᨐޔ੹ᓟߩ౒ห⎇ⓥߩน⢻ᕈ߇಴ߡ߈ߚޕ߹ߚޔ ߎߩ⒳ߩ࿖㓙ࠪࡦࡐࠫ࠙ࡓࠍቇౝߢታᣉߔࠆߎߣߢޔ㑐ㅪ⎇ⓥቶߩቇ↢࡮㒮↢

ߩ⎇ⓥ࡮ᢎ⢒਄ߩ࡟ࡌ࡞ࠕ࠶ࡊߦᄢ߈ߊ⽸₂ߒߚޕ㧔᎑↰ ⚐㧕

ドキュメント内 水環境汚染物質の動態評価研究拠点の構築[平成18 年度報告書] (ページ 123-147)