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川崎製鉄技報 KAWASAKI STEEL GIHO

Vol.17 (1985) No.3

高純度高Cr フェライト系ステンレス鋼

Ultra-low C and N High Chromium Ferritic Stainless Steels

吉岡 啓一(Keiichi Yoshioka) 鈴木 重治(Shigeharu Suzuki) 木下 昇(Noboru Kinoshita) 平野 忠男(Tadao Hirano) 広瀬 洋一(Youichi Hirose) 黒沢 政男(Masao Kurosawa) 要旨 : 高純度高Cr フェライト系ステンレス鋼,SR 26-1,S 30-2 および SR 26-4 は経済的な精錬 技術である当社の SS-VOD プロセスにより量産されている。これらの鋼の化学成分的特徴 は,じん性と耐食性の確保のためにC および N を極低量まで低減し,また溶接部の鋭敏化 防止のためにNb を添加した点にあり,応力腐食割れを生じないことおよび耐食性に優れて いることから,熱交換器および各種プラント材料に用いられる。特にMo の多い S 30-2, SR 26-4 では AL6X,ハスチロイ C などに匹敵し,熱交チューブ,カ性ソーダおよび酢酸プ ラントなどに使用されてきている。ただし,溶接施工での溶接金属へのC,N の汚染を防止 するために十分な管理が必要である。 Synopsis :

Ultra-low C and N high chromium ferritic stainless steels, SR 26-1, S 30-2 and SR 26-4, have been produced by cost-saving steel making process called the "SS-VOD process". The chemical compositions of the steels are characterized by reducing C and N contents to extremely low levels to improve toughness and corrosion resistance, and by addition of Nb to prevent intergranular corrosion of weldments. Being free of stress corrosion cracking and superior in corrosion resistance, the steels have been used as materials for heat exchangers and various chemical plants. Especially, S 30-2 and SR 26-4 steels having 2-4% Mo exhibit excellent corrosion resistance on the same level as those of AL-6X and Hastelloy C, and have been applied to heat exchangers for caustic soda plants and rectification towers for acetic acid plants. To obtain weldments having good properties as mentioned above, however, some appropriate measures in welding is necessary.

(c)JFE Steel Corporation, 2003

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