Material Safety Data Sheet
Section 1 – Chemical Product and Company Identification
Product Name: DUOMAX
Synonyms: Cyanamid, Hydrogen Cyanamide
Company Identification: Green Trees & Plants II, LLC.
P. O. Box 2394, GA 30188
Emergency call: 800-858-7378 Fax: (770) 627-5864 Date: 4/15/ 2008
UN No.: 1760
Section 2 – Composition, information of ingredient
Pure Solution
MSDS Name Hazardous ingredients Percent CAS No.
Cyanamid
Orthophosphoric acid
Cyanamid 51-52.5%
Acid
50% in water
<2%
420-04-2 7664-38-2
Section 3 – Hazards identification
Hazardous classifications: 8.3 other corrosives.
Exposure hazards: Inhalation, swallowing, skin contact
May cause strong irritation to mucous membrane in eyes and some body parts like eyes. Cyanamid has deliquescence character, which can irritate people’s skin like caustic alkali. After four or five days, some eczema dermatitis that will cause both large reaction and a lot of pain will appear on ordinary skin.
Targeting organs No record
Eyes Liquid may cause strong irritation and may cause serious eye inflammation.
Skin May cause serious irritation and may cause injury to skin.
Potential health effects
Ingestion May cause digestive system inflammation if ingested.
Inhalation Liquid may cause strong irritation to the respiratory system.
Chronic No record.
Environmental hazards No record
Potential risk of explosion Violent exothermic reaction if exposed to fire or temperatures exceeding the melting point, or polymerization with acids and bases.
Section 4 – First Aid Measures
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes after removing contaminated clothing and shoes.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Inhalation: Remove to the place with fresh air immediately. If no breath, give artificial respiration, if breathing is difficult, give oxygen. Get medical aid. If conscious, give 2- 4 cups of milk.
Section 5 – Fire Fighting Measure
General information As in any fire, high temperatures and oxidizers may cause acute decomposition or produce large heat from polymerization reaction and can cause explosion and fire. As in water, acid, alkali and other active materials may produce large heat and lead to explosion. May cause burn to body or erode other metal material. As solid in fire, may produce heavy and poisonous gas.
Generation of Hazardous materials.
Oxide Azotes, CO, CO2, N2.
Extinguishing media: Use water spray, dry powder or sand, carbon dioxide, or appropriate foam.
Special fire fighting procedures:
Fireman should wear positive pressed freely breathing devices, complete fire protection clothes and shoes. Use water to cool exposed containers to extinguish fire.
Section 6 – Accidental Release Measures
Emergency measures
Cut off from power source and put into appropriate container, cannot be washed into drainpipe by water which may lead them into river.
Avoiding inhalation and kindly note that people should wear positive pressed freely breath device and keep them away from the body.
Provide ventilation.
Spills/ leaks Dike and control spill. Absorb with inert material. Sweep or shovel into suitable containers with lids for disposal. Any waste must be removed to an appropriate waste disposal area.
Section 7 – Handling and Storage
Handling: Use protective clothing. Wash thoroughly after handling. Remove contaminated clothing and wash before reusing. Use adequate ventilation.
Avoid direct contact with eyes, skin and clothing. Avoid ingestion and inhalation. Wear full face mask and eye protection. Handle in accordance with good industrial hygiene and safety practice.
Storage: Keep container closed when not in use. Store in a cool, dry area (under 68F) and keep away from incompatible substances.
Section 8 – Contact Controls and Personal Protection
Max allowed concentration: No Data Way of measurement: No Data
Engineering Control: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep risk of explosion low.
Personal Protection
Respirators: Use NIOSH-approved respirator in accordance with health/safety regulations.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles.
Body: Wear appropriate chemical resistant overalls and rubber boots and rubber gloves. Avoid any skin exposure.
Hands: Wear appropriate gloves.
Other conditions to avoid: No smoking, eating or drinking during handling. Change to clean clothes after washing. Avoid alcoholic beverages 24 hours before and after handling this product.
Section 9 – Physical and Chemical Properties
Appearance and Physical State: Dark blue liquid, without odor
Ph value: 4-6
Solidifying point: 45 C*
Boiling point: 114 C*
Comparative concentration (water: 1): 1.07 Quantity of heat in burning (KJ/mol): 718
Density (Kpa): 1.07 g (cm3) (at 57 C*)
Critical pressure (Mpa): No data
Critical temperature: No data
Flash point (C): 100 C
Burning temperature (C): No data
Explosion : No data
Solubility: Soluble in water and alcohol
Main usage: Intermediate for medicines, pesticides, N-fertilizer
Section 10 – Stability and Reactivity
Chemical Stability: Unstable at temperatures over 68 F. Stable under 41 F Assortment to Avoid: Strong oxidizing agents, acids, bases, combustible materials.
Conditions to avoid: Avoid overheating, exposure to direct sunlight, temperatures above 104 F.
Hazardous decomposition Products:
Nitrogen Oxides, Carbon Dioxide, Ammonia.
Hazardous Polymerization: Produce heat or may cause explosion or fire when polymerizes to Dicyandiamide.
Section 11 – Toxicological Information
Acute poison: Mouse oral:
Field Mouse oral:
Field Mouse skin:
Rabbit oral:
Rabbit skin:
LD50 = 388 mg/kg LD50 =125 mg/kg LD50 = 84 mg/kg LD50 = 150 mg/kg LD50 = 590 mg/kg Sub-Acute and chronic poison: Damage to the skin: degrease, dry, chap, dermatitis Allergy: Irritation to skin and may cause allergy.
Irritation: No record
The cause leading to abnormality: No record The cause leading to cancer: No record
Procreation: Have record about procreation influence to body.
The cause leading to disability: No data
Section 12 – Ecological Data
Eco-toxicity: No data available
Eco-decomposition: Decomposes into carbamide in short time.
Other: No data available
Section 13 – Disposal Considerations
Chemical waste classification: Hazardous waste material Waste disposal methods:
Container disposal :
Review all local, state and federal regulations concerning health and pollution for appropriate disposal procedures.
Triple rinse then offer for recycling or proper disposal in a sanitary landfill. Do not reuse empty drums.
Section 14 – Transport Information
Class No: 8
UN No: UN 1760
Transporting mark: Corrosive Liquid, N.O.S. (Cyanamid)
Packing Group: Group III
Packing in: 55 gallon plastic drums and 5 gal. plastic containers Storage: Store in a cool place, keeping away from heat and light.
Section 15 – Regulatory Data
1. List of hazardous goods (GB12268-90): Not listed for this kind of chemical product.
2. The classification of common hazardous goods (GB13690-1992): Not listed for this kind of chemical product.
3. According to GB1369-9, this product has a flammable solid classification of 4.3 (other corrosion classification of 8.3)
Section 16 – Additional information
This information is furnished without warranty, representation of any kind except that this information is accurate to the best of GTP II, LLC knowledge, or is obtained from sources believed by GTP II to be accurate. No warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from its use thereof. GTP II assumes no responsibility for injuries proximately caused by use of the Material if reasonable safety procedures are not followed as stipulated in the Data Sheet. Additionally, GTP II, LLC assumes no responsibility for injuries proximately caused by abnormal use of the Material even if reasonable safety procedures are followed. Buyer
assumes the risk in its use of the material.
MSDS Rev. Date: 4/15/2008 by Quality Control Department Data Supervision Department: Technical Department
AV1.6.09
