Multi-element Analysis of River Water by Inductively Coupled Plasma Mass Spectrometry

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*Graduate School of Engineering, Doshisha University, Kyoto

**Department of Environmental Systems Science, Doshisha University, Kyoto

Telephone: +81-774-65-6687, FAX: +81-774-65-6801, E-mail: [email protected]

Multi-element Analysis of River Water by Inductively Coupled Plasma Mass Spectrometry

Yuka KATAYAMA* and Yoriko YOKOO**

(Received July 12, 2008)

We describe an analytical method on the rapid determination of 47 major and trace elements in river water samples by inductively coupled plasma mass spectrometry (SHIMADZU ICPM-8500). The calibrations obtained using standard solutions with a wide range of concentration (50 ppt – 40 ppm) showed a good correlation between the intensity and the recommended concentration. The calibration lines gave satisfactory results with precision level of less than ±10% for most elements. The analytical results of the standard reference material for fresh water (NIST-SRM 1643e) corresponded with their recommended values. The proposed method was applied to the determination of major and trace elements in tap water used in Doshisha University and Kizu river water.

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-G[YQTFU㧦ICP-MS, river water, trace element, major element

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⹜ᢱ߅ࠃ᷹߮ቯ᧦ઙ

⚿ᨐ߅ࠃ߮⠨ኤ

Elem ent Mass Abundance

Li 7 92.5

B 11 80.1

Na 23 100

Mg 24, 25 78.99, 10

Al 27 100

Si 28 92.23

P 31 100

K 39 93.26

Ca 44 2.09

Sc 45 100

Ti 48, 49 73.8, 5.5

V 51 99.75

Cr 52, 53 83.79, 9.5

Mn 55 100

Fe 54, 57 5.8, 2.2

Co 59 100

Ni 60 26.1

Cu 63, 65 69.17, 30.83

Zn 66 27.9

Ga 69,71 60.1,39.9

Ge 74 36.5

As 75 100

Se 82 9.2

Rb 85 72.17

Sr 86,87,88 9.86,7,82.58

Zr 90 51.45

Mo 95,97, 98 15.92,9.55, 24.13

Ag 107 51.84

Cd 111 12.8

In 115 95.7

Sn 118, 120 24.22, 32.59

Sb 121 57.3

Cs 133 100

Ba 137, 138 11.23

La 139 71.7

Ce 140 88.48

Pr 141 100

Nd 142,146 27.13,17.19

Sm 147,152 15,26.7

Eu 151,153 47.8,52.2

Gd 157,158 15.65,24.84

Tb 159 100

Dy 163,164 24.9,28.2

Ho 165 100

Er 166,167 33.6,22.95

Tm 169 100

Yb 172,174 21.9,31.8

Lu 175 97.41

W 184 30.67

Pb 208 52.4

U 238 99.27

Table 1. The analyzed element, mass and its isotope abundance

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Fig. 1. Calibration lines for analyzed elements. The scales on ordinate and abscissa are the mass intensity(kcps) and the recommended concentration(

Ǵ

g/L), respectively.

Li㧣 B10 Na23

Mg24 Mg25

Al-27-A Na23

Mg25

Al-27-P

Si28-A Si28-P P31

K39-A K39-A

K39-P

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Fig. 1.

㧔Continued.㧕

Ca44-A Sc45

Cr52 Cr53 Mn55

Fe54 Fe57

Ni60

Co59

Cu65 Cu63

Ca44-P

V51 Ti49

Ti48

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0 50 100 150 200 250 300 350

0 20 40 60 80 100 120

0 20 40 60 80 100 120 140

0 20 40 60 80 100 120

0 100 200 300 400 500 600 700 800

0 20 40 60 80 100 120

0 20 40 60 80 100 120 140

0 20 40 60 80 100 120

0 100 200 300 400 500

0 20 40 60 80 100 120

0 200 400 600 800 1000 1200

0 20 40 60 80 100 120

0 100 200 300 400 500 600 700

0 20 40 60 80 100 120

0 50 100 150 200

0 20 40 60 80 100 120

Fig. 1.

㧔Continued.㧕

Ga69

Ge74 As75

Ga71

Rb85

Se82

Sr87 Sr86

Sr88 Zn66

Mo95

Mo97 Mo98 Ag107

Zr90

(7)

0 50 100 150 200

0 20 40 60 80 100 120

0 100 200 300 400 500

0 20 40 60 80 100 120

0 100 200 300 400 500 600 700

0 20 40 60 80 100 120

0 100 200 300 400 500 600

0 20 40 60 80 100 120

0 200 400 600 800 1000 1200 1400 1600

0 20 40 60 80 100 120

0 50 100 150 200 250

0 20 40 60 80 100 120

0 200 400 600 800 1000 1200 1400

0 20 40 60 80 100 120

0 50 100 150 200

0 2 4 6 8 10 12

0 50 100 150 200 250

0 2 4 6 8 10 12

0 50 100 150 200 250 300

0 2 4 6 8 10 12

0 20 40 60 80 100 120

0 2 4 6 8 10 12

0 10 20 30 40 50 60

0 2 4 6 8 10 12

0 10 20 30 40 50 60

0 2 4 6 8 10 12

0 20 40 60 80 100 120

0 2 4 6 8 10 12

0 50 100 150 200

0 2 4 6 8 10 12

Fig. 1.

㧔Continued.㧕

Cd111 Sn118 Sn120

Cs133

Sb121 Ba137

Ba138 La139 Ce140

Pr141 Nd142

Eu151 Sm152

Sm147

Nd146

(8)

0 50 100 150 200 250

0 2 4 6 8 10 12

0 10 20 30 40 50 60 70

0 2 4 6 8 10 12

0 20 40 60 80 100

0 2 4 6 8 10 12

0 100 200 300 400 500

0 2 4 6 8 10 12

0 20 40 60 80 100 120

0 2 4 6 8 10 12

0 20 40 60 80 100 120 140

0 2 4 6 8 10 12

0 100 200 300 400 500

0 2 4 6 8 10 12

0 20 40 60 80 100 120 140 160

0 2 4 6 8 10 12 0

20 40 60 80 100 120

0 2 4 6 8 10 12

0 100 200 300 400 500 600

0 2 4 6 8 10 12 0

20 40 60 80 100 120

0 2 4 6 8 10 12

0 50 100 150 200

0 2 4 6 8 10 12

0 100 200 300 400 500 600

0 2 4 6 8 10 12

0 200 400 600 800 1000 1200

0 20 40 60 80 100 120

0 500 1000 1500 2000

0 20 40 60 80 100 120

㪇㪉㪇㪇㪋㪇㪇㪍㪇㪇㪏㪇㪇㪈㪇㪇㪇㪈㪉㪇㪇㪈㪋㪇㪇㪈㪍㪇㪇

㪇㪉㪇㪋㪇㪍㪇㪏㪇㪈㪇㪇㪈㪉㪇

Fig. 1.

㧔Continued.㧕

Gd157

Eu153 Gd158

Tb159 Dy163

Er166

Dy164

Ho165

Yb172

Lu175

Yb174 Tm169

Er167

U238 Pb208

W184

(9)

㪜㫃㪼㫄㪼㫅㫋㪛㪼㫋㪼㪺㫋㫀㫆㫅㩷㫃㫀㫄㫀㫋㩿μ㪾㪆㪣㪀

㪣㫀㪇㪅㪇㪈㪍

㪙㪇㪅㪈㪊㪈

㪥㪸㪉㪊㪎㪅㪌㪌㪊

㪤㪾㪉㪌㪇㪅㪉㪏㪏

㪘㫃㪇㪅㪇㪊㪍

㪪㫀㪊㪅㪍㪊㪈

㪢㪊㪐㪈㪎㪅㪈㪉㪎

㪚㪸㪋㪋㪉㪅㪎㪌㪏

㪪䌣㪇㪅㪇㪈㪋

㪫㫀㪋㪏㪇㪅㪇㪋㪌

㪫㫀㪋㪐㪇㪅㪇㪏㪉

㪭㪇㪅㪇㪈㪉

㪚㫉㪌㪉㪇㪅㪇㪇㪈

㪚㫉㪌㪊㪇㪅㪇㪎㪊

㪤㫅㪇㪅㪇㪇㪏

㪝㪼㪌㪋㪇㪅㪊㪇㪈

㪝㪼㪌㪎㪇㪅㪎㪐㪐

㪚㫆㪇㪅㪇㪇㪌

㪥㫀㪇㪅㪇㪈㪈

㪚㫌㪍㪊㪇㪅㪇㪍㪈

㪚㫌㪍㪌㪇㪅㪇㪊㪌

㪱㫅㪇㪅㪇㪋㪈

㪞㪸㪍㪐㪇㪅㪇㪇㪉

㪞㪼㪇㪅㪇㪈㪐

㪘㫊㪇㪅㪇㪉㪏

㪪㪼㪇㪅㪎㪎㪌

㪩㪹㪇㪅㪇㪈㪇

㪪㫉㪄㪏㪍㪇㪅㪇㪐㪌

㪪㫉㪄㪏㪎㪇㪅㪇㪇㪐

㪪㫉㪏㪏㪇㪅㪇㪇㪉

㪱㫉㪇㪅㪇㪇㪍

㪤㫆㪐㪌㪇㪅㪇㪉㪈

㪤㫆㪐㪎㪇㪅㪇㪈㪎

㪤㫆㪐㪏㪇㪅㪇㪈㪉

㪘㪾㪇㪅㪇㪇㪋

㪚㪻㪇㪅㪇㪉㪊

㪪㫅㪈㪈㪏㪇㪅㪇㪇㪌

㪪㫅㪈㪉㪇㪇㪅㪇㪇㪏

㪪㪹㪇㪅㪇㪇㪍

㪚㫊㪇㪅㪇㪇㪊

㪙㪸㪈㪊㪎㪇㪅㪇㪈㪌

㪙㪸㪈㪊㪏㪇㪅㪇㪇㪊

㪣㪸㪇㪅㪇㪇㪉

㪚㪼㪇㪅㪇㪇㪉

㪧㫉㪇㪅㪇㪇㪈

㪥㪻㪈㪋㪉㪇㪅㪇㪇㪋

㪥㪻㪈㪋㪍㪇㪅㪇㪇㪍

㪪㫄㪈㪋㪎㪇㪅㪇㪇㪋

㪪㫄㪈㪌㪉㪇㪅㪇㪇㪉

㪜㫌㪈㪌㪈㪇㪅㪇㪇㪊

㪜㫌㪈㪌㪊㪇㪅㪇㪇㪉

㪞㪻㪈㪌㪎㪇㪅㪇㪈㪈

㪞㪻㪈㪌㪏㪇㪅㪇㪇㪉

㪫㪹㪇㪅㪇㪇㪇

㪛㫐㪈㪍㪊㪇㪅㪇㪇㪏

㪛㫐㪈㪍㪋㪇㪅㪇㪇㪍

㪟㫆㪇㪅㪇㪇㪈

㪜㫉㪈㪍㪍㪇㪅㪇㪇㪊

㪜㫉㪈㪍㪎㪇㪅㪇㪇㪍

㪫㫄㪇㪅㪇㪇㪇

㪰㪹㪈㪎㪉㪇㪅㪇㪈㪇

㪰㪹㪈㪎㪋㪇㪅㪇㪇㪉

㪣㫌㪇㪅㪇㪇㪈

㪮㪇㪅㪇㪊㪌

㪧㪹㪇㪅㪇㪇㪉

㪬㪇㪅㪇㪈㪈

Table 2. Detection limit

*Detection limit is the concentration which gives theintensity three times the standard deviation given by MQ water.

Fig. 2. Plots of analytical precisions of measured concentrations of elements against their recommended values.

(10)

Fig. 2. (Continued.)

(11)

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5Eએᄖߩ ⒳㘃ߩᏗ࿯㘃ర⚛ߢߪޯRRD ߩỚᐲ▸࿐ߢቯ㊂߇น⢻ߢ޽ߞߚ㧚5Eߪ㧘ޯRRD ߇ቯ㊂น⢻ߥ▸࿐ߢ޽ߞߚ㧚.C߆ࠄ.W߹ߢߩర⚛

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ታ⹜ᢱߣߒߡ0+5654/Gࠍ᷹ቯߒ㧘ផᅑ୯ߣ Ყセߒߚ㧔6CDNG㧟㧕㧚ਥⷐర⚛ߪේᶧߩಽߩ ߩỚᐲ߹ߢផᅑ୯ߦㄭ޿୯ߢಽᨆߔࠆߎߣ߇ߢ߈㧘 0C㧘/I㧘%CߪේᶧߩಽߩߩỚᐲ߹ߢቯ㊂ߢ߈ ߚ㧚ᓸ㊂ర⚛ߪ㧘ቯ㊂น⢻ߣ್ᢿߒߚ▸࿐ౝߢ޽ࠇ

߫㧘⋧ኻ⺋Ꮕ㧑એౝߩቯ㊂߇ߢ߈ߚ㧚

߹ߚ㧘ᧄ⎇ⓥᦼ㑆ਛߩ⚻ᤨᄌൻࠍ0+5654/G ಽߩ Ớᐲṁᶧࠍ↪޿ߡ⏕߆߼ߚ㧚ቯ㊂น⢻ߥ

▸࿐ౝߩర⚛ߪ㧘⚻ᤨᄌൻߪዊߐߊ㧘߅ࠃߘ㧑એ

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㪥㪸㪈㪇㪍㪈㪇㪋㪉㪇㪎㪉㪈㪋㪉㪇㪎㪉㪌㪎㪉㪍㪎㪉㪌㪐㪋㪈㪈㪋㪉㪋㪋㪈㪌㪉㪇㪍㪎㪈㪐㪌㪇㪉㪇㪎㪋㪉㪊㪇㪐㪍㪉㪇㪊㪏㪇㪉㪇㪎㪋㪇

㪤㪾㪊㪐㪋㪇㪎㪎㪏㪈㪏㪇㪐㪐㪈㪇㪈㪈㪇㪇㪈㪍㪈㪈㪍㪈㪈㪍㪈㪎㪏㪊㪎㪏㪋㪏㪇㪋㪏㪎㪇㪏㪎㪏㪏㪇㪏㪇㪊㪎

㪢㪉㪉㪈㪇㪉㪊㪊㪊㪉㪇㪉㪍㪊㪏㪉㪌㪋㪉㪌㪊㪋㪈㪉㪇㪌㪈㪐㪉㪉㪇㪊㪉㪈㪍㪎㪈㪐㪏㪈㪉㪇㪊㪋

㪚㪸㪈㪋㪉㪈㪍㪉㪉㪍㪏㪊㪇㪌㪊㪉㪊㪊㪌㪊㪊㪏㪎㪋㪇㪋㪌㪐㪉㪍㪉㪍㪍㪋㪍㪊㪇㪉㪐㪊㪇㪊㪋㪊㪉㪊㪇㪊㪋㪇㪉㪈㪊㪇㪎㪌㪊㪊㪉㪊㪇㪇

㪣㫀㪇㪅㪈㪈㪊㪇㪅㪇㪏㪎㪇㪅㪈㪐㪏㪇㪅㪈㪐㪏㪇㪅㪈㪎㪋㪇㪅㪉㪋㪇㪇㪅㪉㪊㪎㪇㪅㪉㪈㪏㪇㪅㪊㪎㪇㪇㪅㪊㪍㪍㪇㪅㪊㪋㪏㪈㪅㪎㪋㪊㪈㪅㪎㪐㪏㪈㪅㪎㪋㪇㪈㪌㪅㪏㪏㪈㪐㪅㪐㪌㪈㪎㪅㪋㪇㪙㪈㪅㪌㪈㪋㪇㪅㪎㪐㪇㪈㪅㪍㪈㪎㪈㪅㪍㪌㪈㪈㪅㪌㪎㪐㪈㪅㪏㪐㪉㪈㪅㪐㪊㪌㪈㪅㪐㪎㪋㪉㪅㪐㪇㪎㪉㪅㪐㪏㪍㪊㪅㪈㪌㪏㪈㪍㪅㪌㪊㪈㪋㪅㪐㪋㪈㪌㪅㪎㪐㪈㪍㪎㪅㪍㪈㪊㪏㪅㪋㪈㪌㪎㪅㪐㪘㫃㪇㪅㪉㪌㪏㪇㪅㪎㪇㪐㪈㪅㪊㪍㪏㪈㪅㪈㪉㪏㪈㪅㪋㪈㪏㪈㪅㪋㪐㪇㪈㪅㪋㪐㪇㪈㪅㪎㪎㪊㪉㪅㪏㪉㪎㪉㪅㪍㪉㪍㪉㪅㪏㪊㪍㪈㪋㪅㪏㪏㪈㪊㪅㪌㪐㪈㪋㪅㪈㪏㪈㪉㪍㪅㪈㪈㪉㪍㪅㪈㪈㪋㪈㪅㪏㪭㪇㪅㪈㪐㪐㪇㪅㪈㪏㪐㪇㪅㪊㪍㪏㪇㪅㪊㪍㪇㪇㪅㪊㪎㪐㪇㪅㪋㪎㪌㪇㪅㪋㪎㪐㪇㪅㪋㪎㪊㪇㪅㪎㪍㪐㪇㪅㪏㪇㪊㪇㪅㪎㪌㪎㪊㪅㪎㪍㪌㪋㪅㪈㪇㪏㪊㪅㪎㪏㪍㪊㪐㪅㪏㪋㪊㪋㪅㪏㪊㪊㪎㪅㪏㪍㪚㫉㪇㪅㪈㪏㪈㪇㪅㪈㪇㪉㪇㪅㪉㪎㪏㪇㪅㪉㪌㪋㪇㪅㪉㪇㪋㪇㪅㪊㪋㪌㪇㪅㪊㪉㪎㪇㪅㪉㪌㪌㪇㪅㪌㪊㪋㪇㪅㪌㪊㪉㪇㪅㪋㪇㪏㪈㪅㪐㪎㪉㪉㪅㪍㪈㪏㪉㪅㪇㪋㪇㪉㪈㪅㪊㪎㪉㪋㪅㪌㪐㪉㪇㪅㪋㪇㪤㫅㪇㪅㪈㪎㪏㪇㪅㪈㪐㪌㪇㪅㪊㪏㪈㪇㪅㪊㪍㪍㪇㪅㪊㪐㪇㪇㪅㪋㪍㪊㪇㪅㪋㪍㪈㪇㪅㪋㪏㪎㪇㪅㪎㪎㪉㪇㪅㪎㪎㪍㪇㪅㪎㪎㪐㪊㪅㪐㪇㪐㪊㪅㪐㪐㪏㪊㪅㪏㪐㪎㪊㪎㪅㪍㪇㪊㪎㪅㪍㪇㪊㪏㪅㪐㪎㪝㪼㪈㪅㪇㪌㪌㪇㪅㪋㪐㪈㪈㪅㪈㪉㪋㪈㪅㪊㪋㪈㪇㪅㪐㪏㪈㪈㪅㪉㪇㪍㪈㪅㪉㪇㪍㪈㪅㪉㪉㪍㪈㪅㪐㪉㪎㪉㪅㪍㪉㪌㪈㪅㪐㪍㪉㪈㪉㪅㪇㪈㪈㪉㪅㪋㪈㪐㪅㪏㪈㪇㪈㪉㪎㪅㪏㪈㪎㪈㪅㪇㪐㪏㪅㪈㪇㪚㫆㪇㪅㪈㪉㪏㪇㪅㪈㪊㪌㪇㪅㪉㪌㪏㪇㪅㪉㪊㪏㪇㪅㪉㪎㪈㪇㪅㪊㪈㪈㪇㪅㪊㪇㪊㪇㪅㪊㪊㪏㪇㪅㪌㪉㪏㪇㪅㪌㪈㪍㪇㪅㪌㪋㪈㪉㪅㪍㪋㪌㪉㪅㪎㪌㪋㪉㪅㪎㪇㪍㪉㪏㪅㪐㪉㪉㪌㪅㪇㪏㪉㪎㪅㪇㪍㪥㫀㪇㪅㪉㪏㪊㪇㪅㪊㪈㪉㪇㪅㪌㪌㪐㪇㪅㪌㪎㪍㪇㪅㪍㪉㪋㪇㪅㪍㪐㪍㪇㪅㪎㪉㪌㪇㪅㪎㪏㪇㪈㪅㪈㪐㪎㪈㪅㪉㪇㪋㪈㪅㪉㪋㪏㪌㪅㪐㪇㪎㪍㪅㪊㪊㪌㪍㪅㪉㪋㪈㪍㪉㪅㪋㪉㪌㪈㪅㪐㪇㪍㪉㪅㪋㪈㪚㫌㪇㪅㪈㪈㪋㪇㪅㪈㪈㪋㪇㪅㪉㪈㪍㪇㪅㪈㪐㪏㪇㪅㪉㪉㪏㪇㪅㪉㪌㪊㪇㪅㪉㪊㪎㪇㪅㪉㪏㪌㪇㪅㪋㪌㪌㪇㪅㪋㪋㪐㪇㪅㪋㪌㪌㪉㪅㪉㪈㪌㪉㪅㪊㪇㪉㪉㪅㪉㪎㪍㪉㪉㪅㪋㪊㪈㪏㪅㪏㪋㪉㪉㪅㪎㪍㪱㫅㪇㪅㪊㪎㪋㪇㪅㪊㪐㪊㪇㪅㪎㪎㪉㪇㪅㪍㪋㪇㪇㪅㪎㪏㪌㪇㪅㪐㪋㪉㪇㪅㪏㪇㪐㪇㪅㪐㪏㪈㪈㪅㪌㪎㪌㪈㪅㪋㪋㪇㪈㪅㪌㪎㪇㪎㪅㪎㪍㪎㪎㪅㪋㪉㪐㪎㪅㪏㪌㪇㪍㪉㪅㪈㪋㪌㪍㪅㪈㪎㪎㪏㪅㪌㪇㪘㫊㪇㪅㪉㪐㪏㪇㪅㪊㪇㪉㪇㪅㪌㪐㪏㪇㪅㪌㪍㪏㪇㪅㪍㪇㪌㪇㪅㪎㪉㪇㪇㪅㪎㪉㪇㪇㪅㪎㪌㪍㪈㪅㪈㪎㪐㪈㪅㪈㪊㪊㪈㪅㪉㪇㪐㪌㪅㪏㪋㪊㪌㪅㪏㪍㪉㪍㪅㪇㪋㪌㪋㪐㪅㪇㪐㪋㪊㪅㪎㪍㪍㪇㪅㪋㪌㪩㪹㪇㪅㪇㪍㪍㪇㪅㪇㪎㪈㪇㪅㪈㪊㪏㪇㪅㪈㪉㪎㪇㪅㪈㪋㪈㪇㪅㪈㪎㪇㪇㪅㪈㪌㪐㪇㪅㪈㪎㪎㪇㪅㪉㪏㪊㪇㪅㪉㪍㪎㪇㪅㪉㪏㪊㪈㪅㪊㪏㪇㪈㪅㪋㪈㪊㪈㪅㪋㪈㪋㪈㪋㪅㪇㪌㪈㪋㪅㪇㪌㪈㪋㪅㪈㪋㪪㫉㪈㪅㪌㪍㪎㪈㪅㪍㪈㪍㪊㪅㪈㪉㪎㪊㪅㪉㪈㪎㪊㪅㪉㪊㪈㪊㪅㪏㪐㪋㪋㪅㪇㪈㪊㪋㪅㪇㪊㪐㪍㪅㪉㪋㪉㪍㪅㪋㪋㪏㪍㪅㪋㪍㪉㪊㪈㪅㪈㪌㪊㪉㪅㪉㪏㪊㪉㪅㪊㪈㫅㪅㪻㪅㫅㪅㪻㪅㪊㪉㪊㪅㪈㪤㫆㪇㪅㪌㪍㪇㪇㪅㪍㪇㪎㪈㪅㪈㪎㪈㪈㪅㪈㪋㪇㪈㪅㪉㪈㪋㪈㪅㪋㪈㪈㪈㪅㪋㪏㪊㪈㪅㪌㪈㪏㪉㪅㪋㪊㪈㪉㪅㪊㪌㪋㪉㪅㪋㪉㪏㪈㪉㪅㪉㪇㪈㪉㪅㪉㪏㪈㪉㪅㪈㪋㪈㪉㪌㪅㪌㪈㪇㪐㪅㪐㪈㪉㪈㪅㪋㪘㪾㪇㪅㪇㪇㪍㪇㪅㪇㪇㪌㪇㪅㪇㪈㪈㪇㪅㪇㪇㪇㪇㪅㪇㪈㪈㪇㪅㪇㪇㪐㪇㪅㪇㪇㪇㪇㪅㪇㪈㪊㪇㪅㪇㪈㪐㪇㪅㪇㪇㪉㪇㪅㪇㪉㪈㪇㪅㪇㪐㪏㪇㪅㪇㪏㪍㪇㪅㪈㪇㪍㪇㪅㪐㪋㪌㪇㪅㪐㪋㪌㪈㪅㪇㪍㪚㪻㪇㪅㪇㪊㪎㪇㪅㪇㪊㪊㪇㪅㪇㪍㪎㪇㪅㪇㪍㪈㪇㪅㪇㪍㪍㪇㪅㪇㪏㪉㪇㪅㪇㪍㪏㪇㪅㪇㪏㪉㪇㪅㪈㪉㪎㪇㪅㪈㪈㪇㪇㪅㪈㪊㪈㪇㪅㪌㪐㪌㪇㪅㪍㪇㪉㪇㪅㪍㪌㪎㪌㪅㪊㪊㪏㪋㪅㪎㪐㪐㪍㪅㪌㪎㪪㪹㪇㪅㪉㪏㪎㪇㪅㪉㪐㪉㪇㪅㪌㪎㪈㪇㪅㪌㪍㪌㪇㪅㪌㪏㪊㪇㪅㪍㪏㪍㪇㪅㪎㪇㪊㪇㪅㪎㪉㪐㪈㪅㪇㪐㪎㪈㪅㪈㪊㪌㪈㪅㪈㪍㪍㪌㪅㪎㪍㪐㪌㪅㪍㪋㪏㪌㪅㪏㪊㪇㪌㪈㪅㪊㪈㪋㪍㪅㪉㪍㪌㪏㪅㪊㪇㪙㪸㪉㪅㪌㪍㪉㪉㪅㪎㪉㪈㪌㪅㪊㪏㪐㪌㪅㪉㪐㪏㪌㪅㪋㪋㪉㪍㪅㪊㪊㪍㪍㪅㪌㪍㪐㪍㪅㪏㪇㪊㪈㪇㪅㪐㪐㪈㪇㪅㪋㪏㪈㪇㪅㪏㪏㪌㪍㪅㪇㪈㪌㪉㪅㪈㪉㪌㪋㪅㪋㪉㫅㪅㪻㪅㫅㪅㪻㪅㪌㪋㪋㪅㪉㪧㪹㪇㪅㪇㪌㪇㪇㪅㪇㪐㪏㪇㪅㪇㪌㪇㪇㪅㪈㪏㪊㪇㪅㪈㪐㪍㪇㪅㪇㪌㪇㪇㪅㪈㪏㪊㪇㪅㪉㪋㪌㪇㪅㪊㪌㪍㪇㪅㪉㪈㪐㪇㪅㪊㪐㪊㪈㪅㪎㪍㪏㪈㪅㪌㪍㪇㪈㪅㪐㪍㪊㪈㪐㪅㪈㪐㪈㪎㪅㪏㪇㪈㪐㪅㪍㪊㫅㪅㪻㪅㩷㪑㩷㫅㫆㫋㩷㪻㪼㫋㪼㫉㫄㫀㫅㪼㪻

㪜㫃㪼㫄㪼㫅㫋㪥㪠㪪㪫㩷㪈㪆㪉㪇㪇㪥㪠㪪㪫㩷㪈㪆㪈㪇㪇㪥㪠㪪㪫㪈㪆㪏㪇㪥㪠㪪㪫㩷㪈㪆㪌㪇㪥㪠㪪㪫㪈㪆㪈

㫋㪿㫀㫊㩷㫎㫆㫉㫂㩿μ㪾㪆㪣㪀㫋㪿㫀㫊㩷㫎㫆㫉㫂㩿μ㪾㪆㪣㪀㫋㪿㫀㫊㩷㫎㫆㫉㫂㩿μ㪾㪆㪣㪀㫋㪿㫀㫊㩷㫎㫆㫉㫂㩿μ㪾㪆㪣㪀㫋㪿㫀㫊㩷㫎㫆㫉㫂㩿μ㪾㪆㪣㪀㫋㪿㫀㫊㩷㫎㫆㫉㫂㩿μ㪾㪆㪣㪀㪥㪠㪪㪫㩷㪈㪆㪈㪇

Table 3. Analytical results of NIST-SRM 1643e.

Table 4. Elemental compositions (unit :

Ǵg/L) of tap water and Kizu river water

(12)

ౝߢౣ⃻ߢ߈ߚ㧚

ታ⹜ᢱߣߒߡ᳓㆏᳓ߣᴡᎹ᳓ߩಽᨆ⚿ᨐࠍ 6CDNG ߦ␜ߔ㧚

⚿⺰

ᴡᎹ᳓ߩỚᐲ࡟ࡌ࡞ߦ⺞⵾ߒߚᮡḰ⹜ᢱࠍಽᨆߒ㧘

⋧ኻ⺋Ꮕߣᬌ಴㒢⇇ࠍ߽ߣߦ ߩర⚛ߢᦨㆡߥ⾰

㊂ᢙ㧘ቯ㊂▸࿐ࠍ᳿߼ࠆߎߣ߇ߢ߈ߚ㧚ᴡᎹ᳓ᮡḰ

⹜ᢱߢ޽ࠆ0+5654/Gࠍ᷹ቯߒ㧘Ớᐲߦࠃߞߡ ᬌ㊂✢ࠍㆬᛯߔࠆߎߣߢRRV߆ࠄRRO࡟ࡌ࡞߹ߢ ቯ㊂ߢ߈ߚ㧚ᴡᎹ᳓ߩਥⷐర⚛ߢ޽ࠆ 0C㧘/I㧘-㧘

%CߪỚᐲ߇RRD એ਄ߢ޽ࠇ߫㧘⋧ኻ⺋Ꮕr એౝߩቯ㊂߇น⢻ߢ޽ߞߚ㧚ᓸ㊂ర⚛ߪర⚛ߢᢙ RRVߩቯ㊂߇ߢ߈㧘⒳㘃ߩᏗ࿯㘃ర⚛ߢߪ

ޯRRDߩỚᐲ▸࿐ߢቯ㊂߇น⢻ߢ޽ߞߚ㧚

ෳ⠨ᢥ₂

1) G. Faure, Principles and Applications of Geochemistry.

(Prentice Hall, New Jersey, 1998㧕, p. 600.

2) J. Gaillardet, J. Viers, B. Dupre, Trace Elements in River Waters, J. I. Drever (editer), Treatise on Geochemistry volume 5 Surface and Ground Water, Weathering, and Soils, (Elsevier, Oxford , 2005), 225-272.

3) H㧚Haraguchi㧘Y㧚Zhu㧘R㧚Hattori㧘A㧚Itoh㧘T㧚 Umemura, ”Mltielement Analysis of Commercial Mineral Waters by Resin Preconcentration and ICP-MS,” Biomed㧚 Res㧚Trace Elements㧘15(4)㧘355-357(2004)㧚

4) S㧚Ko㧘V㧚Aparin㧘Y㧚Kawabata㧘K㧚Shiraishi㧘M㧚 Yamamoto㧘M㧚Nagai㧘Y㧚Katayama, “Application of ICP-MS on Analysis of Water Quality in Zerafshan River,”

ᴕṼ⎇ⓥ㧘

15(4)㧘375-378(2006)㧚

5) ጊፒᱜᄦ㧘቟⮮᥍ᄦ“+%2⾰㊂ಽᨆᴺߦࠃࠆㇺౝᴡᎹ

᳓ਛߩṁሽᘒᓸ㊂ర⚛ߩಽᨆ”᧲੩ㇺⅣႺ⑼ቇ⎇ⓥ

ᚲᐕႎ

㧘㧔㧕

㧚

6) ଻Უᢅⴕ

⋙ୃ, ᥉෸ 㜞⚐ᐲൻᛛⴚ ╙㧝Ꮞ ಽᨆ

ᛛⴚ㧚㧔ࡈࠫ࡮࠹ࠢࡁࠪࠬ࠹ࡓ, ᧲੩, 2001㧕

, p. 1145㧚 7)

ේญ⚔ἶ

,

ኹ೨♿ᄦ

,

ฎ↰⋥♿

,

₎ᷰ⧷ਯ

,

ᓸ㊂ర⚛

ಽᨆߩታ㓙㧔ਣༀᩣᑼળ␠

,

᧲੩

,1995

㧕

, p. 301

㧚

8) N.Imai, “Multielement Analysis of Rocks with the Use of

Geological Certified Reference Material by Inductively Coupled Plasma Mass Spectrometry,” Analytical Science

㧘

6

㧘

389-395(1990)

㧚

9) A㧚Takeda㧘K㧚Kimura㧘S㧚Yamasaki, “Analysis of 57 elements in Japanese soils

㧘

with special reference to soil group and agricultural use,” Geoderma 119

㧘

291-307(2004)㧚 10)

⿒ጤ⧷ᄦ, ᨷ਄ᣂ, ⷺ↰ᰵ৻, ේญ⚔ἶ, ಽᨆൻቇ㧔ਣ

ༀᩣᑼળ␠, ᧲੩ ,2005㧕, p. 279.

11) J㧚C㧚Miller㧘J㧚N㧚Miller,

࠺࡯࠲ߩߣࠅᣇ߹ߣ߼ᣇ

(౒┙಴ ,

Multi-element Analysis of River Water by Inductively Coupled Plasma Mass Spectrometry

Multi-element Analysis of River Water by Inductively Coupled Plasma Mass Spectrometry

ࠠ࡯ࡢ࡯࠼㧦+%2/5㧘ᴡᎹ᳓㧘ᓸ㊂ర⚛㧘ਥⷐర⚛

⺃ዉ⚿วࡊ࡜࠭ࡑ⾰㊂ಽᨆ⸘ߦࠃࠆᴡᎹ᳓ਛߩర⚛ߩቯ㊂

ߪߓ߼ߦ

⹜ᢱ߅ࠃ᷹߮ቯ᧦ઙ

⚿ᨐ߅ࠃ߮⠨ኤ

⹜ᢱ߅ࠃ᷹߮ቯ᧦ઙ

⚿ᨐ߅ࠃ߮⠨ኤ

Ǵ

㧔Continued.㧕

㧔Continued.㧕

㧔Continued.㧕

㧔Continued.㧕

Ǵg/L) of tap water and Kizu river water

⚿⺰

ෳ⠨ᢥ₂

ᴕṼ⎇ⓥ㧘

᳓ਛߩṁሽᘒᓸ㊂ర⚛ߩಽᨆ”᧲੩ㇺⅣႺ⑼ቇ⎇ⓥ

ᚲᐕႎ

㧚

⋙ୃ, ᥉෸ 㜞⚐ᐲൻᛛⴚ ╙㧝Ꮞ ಽᨆ

ᛛⴚ㧚 㧔ࡈࠫ࡮࠹ࠢࡁࠪࠬ࠹ࡓ, ᧲੩, 2001㧕

ේญ⚔ἶ

ኹ೨♿ᄦ

ฎ↰⋥♿

₎ᷰ⧷ਯ

ᓸ㊂ర⚛

ಽᨆߩታ㓙㧔ਣༀᩣᑼળ␠

᧲੩

㧕

㧚

㧘

㧘

㧚

㧘

㧘

⿒ጤ⧷ᄦ, ᨷ਄ᣂ, ⷺ↰ᰵ৻, ේญ⚔ἶ, ಽᨆൻቇ㧔ਣ

ༀᩣᑼળ␠, ᧲੩ ,2005㧕, p. 279.

࠺࡯࠲ߩߣࠅᣇ߹ߣ߼ᣇ

᧲੩, 1991), p. 246.

ᛛⴚ㧚㧔ࡈࠫ࡮࠹ࠢࡁࠪࠬ࠹ࡓ, ᧲੩, 2001㧕