Revision date: 2018-08-09 Format: NA Version 1.05
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name AriaÔ Insecticide
Other means of identification
Product Code(s) 6248-A
Synonyms FLONICAMID: N-cyanomethyl-4-(trifluoromethyl)nicotinamide (IUPAC name);
N-(cyanomethyl)-4-(trifluoromethyl)-3-pyridinecarboxamide (CAS name) Active Ingredient(s) Flonicamid
Chemical Family Pyridinecarboxamide Insecticide
Recommended use of the chemical and restrictions on use
Recommended Use: Insecticide
Restrictions on Use: Use as recommended by the label.
Supplier Address
FMC Corporation 2929 Walnut Street Philadelphia, PA 19104
(215) 299-6000 (General Information)
[email protected] (E-Mail General Information) Emergency telephone number
For leak, fire, spill or accident emergencies, call:
1 800 / 424-9300 (CHEMTREC - U.S.A.) 1 703 / 741-5970 (CHEMTREC - International) 1 703 / 527-3887 (CHEMTREC - Alternate) Medical Emergencies:
1 800 / 331-3148 (ProPharma Group - U.S.A. & Canada)
1 651 / 632-6793 (ProPharma Group - All Other Countries - Collect)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity (single exposure) Category 2
GHS Label elements, including precautionary statements
Version 1.05 EMERGENCY OVERVIEW
Precautionary Statements - Prevention
P264 - Wash face, hands and any exposed skin thoroughly after handling P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P270 - Do not eat, drink or smoke when using this product
Precautionary Statements - Response
P308 + P311 - If exposed or concerned: Call a POISON CENTER or doctor
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/ attention Precautionary Statements - Storage
P405 - Store locked up
Precautionary Statements - Disposal
P501 - Dispose of contents/container according to label directions Hazards not otherwise classified (HNOC)
No hazards not otherwise classified were identified.
Other Information No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Family Pyridinecarboxamide Insecticide.
Chemical name CAS-No Weight %
Flonicamid 158062-67-0 50
Synonyms are provided in Section 1.
4. FIRST AID MEASURES
Eye Contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice.
Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for further treatment advice.
Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial Warning
Hazard Statements
H319 - Causes serious eye irritation H371 - May cause damage to organs
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Version 1.05 respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
Ingestion Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
None known.
Indication of immediate medical attention and special treatment needed, if necessary
Treatment is otherwise controlled removal of exposure followed by symptomatic and supportive care
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Carbon dioxide (CO2). Foam. Dry chemical. If necessary: Use water spray or fog; do not use straight streams.
Specific Hazards Arising from the Chemical
Avoid dust formation. Fine dust dispersed in air may ignite. Combustible material Explosion data
Sensitivity to Mechanical Impact No information available.
Sensitivity to Static Discharge No information available.
Protective equipment and precautions for firefighters
Wear self-contained breathing apparatus and protective suit. Isolate fire area. Evaluate upwind.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Isolate and post spill area. Remove all sources of ignition. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8.
Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1
"Product and Company Identification" above.
Environmental Precautions Keep people and animals away from and upwind of spill/leak. Keep material out of lakes, streams, ponds, and sewer drains.
Methods for Containment Cover powder spill with plastic sheet or tarp to minimize spreading. Use a wet sweeping compound or water to prevent dust formation. Dike far ahead of spill to collect runoff water.
Vacuum, shovel or pump waste into a drum and label contents for disposal.
Methods for cleaning up Clean and neutralize spill area, tools and equipment by washing with water and soap.
Absorb rinsate and add to the collected waste. Dispose of waste as indicated in Section 13.
7. HANDLING AND STORAGE
Handling Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal.
Reference to other sections.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep/store only in original container.
Incompatible products None known
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Version 1.05 Appropriate engineering controls
Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.
Individual protection measures, such as personal protective equipment
Eye/Face Protection If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles.
Skin and Body Protection Wear long-sleeved shirt, long pants, socks, and shoes.
Hand Protection Use protective gloves made of chemical materials such as nitrile or neoprene. Wash the outside of gloves with soap and water before reuse. Check regularly for leaks.
Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations.
Hygiene measures Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry.
General information Clean water should be available for washing in case of eye or skin contamination. Wash hands prior to eating, drinking chewing gum or using tobacco. Shower or bathe at the end of working
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Solid Granules
Physical State Dry powder
Color Light brown
Odor Mild
Odor threshold No information available
pH 6.0
Melting point/freezing point Not applicable
Boiling Point/Range No information available
Flash point Not applicable
Evaporation Rate No information available Flammability (solid, gas) No information available Flammability Limit in Air
Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available
Density 33.5 lb/cu ft (loose); 37.2 lb/cu ft (tapped) Specific gravity No information available
Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available Explosive properties No information available Oxidizing properties No information available Molecular weight No information available Bulk density No information available
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Version 1.05
10. STABILITY AND REACTIVITY
Reactivity Not applicable
Chemical Stability Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization Hazardous polymerization does not occur.
Conditions to avoid Heat, flames and sparks Incompatible materials None known.
Hazardous Decomposition ProductsThermal decomposition can lead to release of irritating gases and vapors.
11. TOXICOLOGICAL INFORMATION
Product Information
LD50 Oral > 2000 mg/kg (rat)
LD50 Dermal > 2000 mg/kg (rat) LC50 Inhalation > 5.36 mg/L 4 hr (rat) Serious eye damage/eye irritation Moderately irritating.
Skin corrosion/irritation Non-irritating.
Sensitization Non-sensitizing
Information on toxicological effects
Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic toxicity Flonicamid: Repeated contact may cause allergic reactions in very susceptible persons.
Mutagenicity Flonicamid: Not genotoxic in laboratory studies.
Carcinogenicity Flonicamid: Suggestive evidence of carcinogenicity (mouse bronchioloalveolar tumors), but not sufficient to assess human carcinogenic potential.
Neurological effects Flonicamid: Not neurotoxic.
Reproductive toxicity Flonicamid: No toxicity to reproduction in animal studies.
Developmental toxicity Flonicamid: Not teratogenic in animal studies.
STOT - single exposure May cause damage to organs. See listed target organs below.
STOT - repeated exposure Not classified.
Target organ effects Liver, kidney, Hematopoietic system Neurological effects Flonicamid: Not neurotoxic.
Aspiration hazard No information available.
Chemical name ACGIH IARC NTP OSHA
Flonicamid 158062-67-0
Group 2A
Legend:
IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans
12. ECOLOGICAL INFORMATION
Ecotoxicity
Version 1.05
Flonicamid (158062-67-0)
Active Ingredient(s) Duration Species Value Units
Flonicamid Technical 96 h LC50 Fish >100 mg/L
48 h EC50 Crustacea >100 mg/L
96 h EC50 Algae >100 mg/L
21 d NOEC Fish 10 mg/L
21 d NOEC Crustacea 3.1 mg/L
Persistence and degradability Flonicamid: Non-persistent. Does not readily hydrolyze. Readily biodegradable (meets the
>70% reduction in ≤ 28 days).
Bioaccumulation Flonicamid: The substance does not have a potential for bioconcentration.
Mobility Flonicamid: Very mobile; has potential to reach groundwater.
13. DISPOSAL CONSIDERATIONS
Waste disposal methods Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance. Proper personal protective equipment, as described in Sections 7 and 8, must be worn while handling materials for waste disposal.
Contaminated Packaging Containers must be disposed of in accordance with local, state and federal regulations.
Refer to the product label for container disposal instructions.
14. TRANSPORT INFORMATION
DOT This material is not a hazardous material as defined by U.S. Department of Transportation at 49 CFR Parts 100 through 185.
TDG Not regulated in transportation.
ICAO/IATA Not regulated in transportation.
IMDG/IMO Not regulated in transportation.
15. REGULATORY INFORMATION U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic health hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):
Chemical name CWA - Reportable Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants
CWA - Hazardous Substances Page 6 / 8
Version 1.05 Formaldehyde
50-00-0
100 lb X
Naphthalene 91-20-3
100 lb X X X
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical name Hazardous Substances RQs Extremely Hazardous Substances RQs
Formaldehyde 50-00-0
100 lb 45.4 kg
100 lb Naphthalene
91-20-3
100 lb 45.4 kg FIFRA Information
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
CAUTION
Harmful if swallowed, inhaled, or absorbed through the skin. Causes moderate eye irritation.
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
This product does not contain any substances regulated by state right-to-know regulations
International Inventories
This product does not contain any substances on the Interntational Inventories.
Mexico - Grade Moderate risk, Grade 2
Chemical name Mexico - Pollutant Release and Transfer Register - Reporting Emissions for Fabrication, Process
or Use -Threshold Quantities
Pollutant Release and Transfer Register - Reporting Emissions -
Threshold Quantities
Formaldehyde 100
2500 kg/yr
100 kg/yr
CANADA
WHMIS Statement
This product has been classified in accordance with the Hazardous Products Regulations (HPR) and the SDS contains all the information required by the HPR.
WHMIS Hazard Class D2B - Toxic materials
Version 1.05
16. OTHER INFORMATION
*Indicates a chronic health hazard.
NFPA/HMIS Ratings Legend Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0
Revision date: 2018-08-09
Reason for revision: (M)SDS sections updated Disclaimer
FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information.
Prepared By:
FMC Corporation
FMC Logo - Trademark of FMC Corporation
© 2018 FMC Corporation. All Rights Reserved.
End of Safety Data Sheet
NFPA Health Hazards 2 Flammability 1 Instability 0 Special Hazards - HMIS Health Hazards 2 Flammability 1 Physical hazard 0 Personal Protection X
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