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(1) Helena Chemical Company 13-SEP PH Page 1 Of 4 CHEMTREC Material Safety Data Sheet Effective Date: 13-SEP-2004 Product: ELE-MAX ZIN=MAN

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Helena Chemical Company 13-SEP-2004 12:52:48 PH: 901-761-0050 Page 1 Of 4 CHEMTREC: 800-424-9300

Material Safety Data Sheet

Effective Date: 13-SEP-2004 Product: ELE-MAX ZIN=MAN

--- I. IDENTIFICATION

---

Chemical Name: Manganese+Zinc Micronutrient Chemical Family: Inorganic Fertilizers

Formula: Not applicable, formulated mixture.

Synonyms: None

CAS Number: Not applicable, formulated mixture.

EPA Number: None required

--- II. PHYSICAL DATA

--- Boiling Point: Not determined

Freezing Point: Not determined Spec Gravity: 1.784 gms/cc Vapor Pressure: Not applicable Vapor Density: Not applicable Solubility: Miscible

Volatiles: Not determined Evaporation: Not determined Melting Point: Not applicable

Appearance: Beige, odorless liquid.

--- III. INGREDIENTS

--- Material CAS Number Percent TLV Hazard

--- --- --- --- --- Proprietary blend of plant 100.00 N/E Skin & eye nutrients including nitrogen, irritant.

manganese and zinc.

GUARANTEED ANALYSIS:

Total Nitrogen (N), derived 2.00 from Urea

Manganese (Mn), derived from 16.20 manganese carbonate.

Zinc (Zn), derived from zinc 16.20 oxide.

--- IV. FIRE AND EXPLOSION HAZARD

--- Flash Point: Non-combustible

Autoignition Temp: Not determined Flammable Limit: Not applicable

Extinguishing Media: Non-combustible liquid. Use extinguishing media suitable to underlying cause of fire. Use water

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Helena Chemical Company 13-SEP-2004 12:52:48 PH: 901-761-0050 Page 2 Of 4 CHEMTREC: 800-424-9300

Material Safety Data Sheet

Effective Date: 13-SEP-2004 Product: ELE-MAX ZIN=MAN

--- spray to cool fire-exposed containers.

Special Fire Fight Proc: Wear self-contained breathing apparatus and full protective clothing.

Fire and Expl Hazard: Emits toxic fumes under fire conditions.

--- V. HEALTH HAZARD

--- Carcinogen Information: Not listed

ACUTE EFFECTS OF OVER EXPOSURE

--- Swallowing: Ingestion may result in soreness and redness of the mouth and throat. Difficulty in swallowing may result. Stomach upset may occur, including nausea, stomach cramping and vomiting.

Skin Absorption: Mild irritation may occur with skin contact.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those with ingestion

(stomach upset, nausea, etc.).

Skin contact: Mild irritation may occur with skin contact.

Eye Contact: Irritation and redness may occur with eye contact.

Chronic Effects: None currently known.

Other Hazard: None currently known.

EMERGENCY AND FIRST AID PROCEDURES

--- Swallowing: Rinse mouth with water. Do not induce vomiting.

If conscious, give 2 to 4 glasses of water to drink. Consult a physician.

Skin: Wash affected area with plenty of soap and water. If irritation persists, seek medical treatment.

Inhalation: Remove to fresh air. If irritation develops or persists, consult a physician.

Eyes: Flush eyes with water for at least 15 minutes, holding eyelids open. Seek medical treatment.

Notes to Physician: In the event of an adverse response, treatment should be directed toward control of the

symptoms and the clinical condition of the patient.

--- VI. REACTIVITY

--- Stability: Stable

Conditions to Avoid: Avoid excessive heat.

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Helena Chemical Company 13-SEP-2004 12:52:48 PH: 901-761-0050 Page 3 Of 4 CHEMTREC: 800-424-9300

Material Safety Data Sheet

Effective Date: 13-SEP-2004 Product: ELE-MAX ZIN=MAN

--- Polymerization: Will Not Occur

Conditions to Avoid: None currently known.

Incompatibility material: Avoid strong oxidizing agents and strong acids.

See Other Precautions, Section IX.

Hazardous Combustion: Emits toxic fumes under fire conditions.

--- VII. SPILL OR LEAK PROCEDURES

--- Spill or Leak Proc: If uncontaminated, collect and reuse as intended. If contaminated, absorb using an inert material, such as earth or sand. Transfer to a suitable salvage container, properly

labeled for storage and disposal.

Waste Disposal Method: This material must be disposed of according to Federal, State or Local procedures under the Resource Conservation and Recovery Act.

--- VIII. SPECIAL PROTECTION INFORMATION

--- Respiration: Avoid breathing spray mists by wearing a NIOSH- approved dust/mist respirator.

Ventilation: Good general ventilation should be sufficient.

Gloves: Impervious.

Eyes: Chemical workers' goggles or face shield.

Other: Eyewash station, impervious apron and footwear.

--- IX. SPECIAL PRECAUTIONS

--- Special precaution: Keep out of reach of children. Do not store with food, feed or other material to be used or consumed by humans or animals. Do not

contaminate water supplies, lakes, streams or ponds with this material.

Other precaution: Must not be used with straight Ammonium Nitrate fertilizer or any fertilizer containing

ammonium nitrate which may have self-sustaining decomposition properties.

--- X. SHIPPING INFORMATION

--- Shipping name: Not regulated by DOT, IATA or IMDG.

Hazard Class: None Identification No: None

Labels Required: None required

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Helena Chemical Company 13-SEP-2004 12:52:48 PH: 901-761-0050 Page 4 Of 4 CHEMTREC: 800-424-9300

Material Safety Data Sheet

Effective Date: 13-SEP-2004 Product: ELE-MAX ZIN=MAN

--- Placarding: None

Freight Class: Compound, Fertilizer (Manufactured Fertilizer), Liquid, NOIBN (NMFC Item 68140, Sub 6, Class 70)

Chemical Name Equivalent R.Q.

--- --- Not applicable Not applicable

--- XI. GENERAL PRODUCT INFORMATION

--- National Fire Protection Association Rating:

(Rating level: 4-Extreme, 3-High, 2-Moderate, 1-Slight, 0-Minimum Health: 1 Fire: 1 Reactivity: 0

S.A.R.A. Title III Hazard Classification: (Yes/No)

Immediate (Acute) Health: Y Delayed (Chronic) Health: N Sudden Release of pressure: N Fire: N Reactive: N

--- Mail inquiries to: 225 Schilling Blvd., Suite 300 Collierville, TN 38017 Helena Chemical Company believes that the data contained herein is factual.

This data is not to be taken as a warranty or representation of legal responsibility. It is offered solely for your consideration, investigation and verification.

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