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ABN: Para-SHOT 3.0 Page 1 of 9

Safety Data Sheet

Revision date: 05.20.2016 Date of issue: 02.04.2015

Sr. No. Title of the section Information required in this section 1. Identification of the substance & of the company

1.1

Identification of the substance or preparation

1.1.1 Trade Name :Paraquat Concentrate ABN: Para-SHOT 3.0 1.1.2 EPA Registration No.: 83529‐27

1.2 Other identification

1.2.1 Substance name: 1,1-dimethyl-4,4'-bipyridinium dichloride 1.2.2 CAS No.:1910‐42‐5

1.3

Use of the substance/

preparation

1.3.1 Recommended uses:

 Herbicide

1.3.2 Restricted uses: Not known as on date

1.4

Company/

under - taking identification

1.4.1 Company name: Sharda USA LLC

1.4.2 Contact Person : Sharon Gunning, Director, Supply Chain and Administrative Operations 1.4.3 Manufacturing site address: Universal Cooperatives, Inc.

1253 Independence Dr., Napoleon OH 43545 1.4.4 Telephone number: +91 22 5678 2800

1.4.5 Fax number : +91 22 5678 2828, +91 22 5678 2808

1.4.6 E-mail : [email protected] ; WEBSITE: http://www.shardausa.com

1.5 Emergency telephone

1.5.1 Emergency telephone number : 1(800) 222-1222 CHEMTREC PHONE: 1(800) 424-9300

1.5.2 Telephone number of USA importer: (610) 350-6930 1.5.3 Opening hours: 24 hrs

2. Hazard Identification

2.1

Classification of the substance according to Regulation

1910.1200 [GHS]

Acute Tox. 3 – Oral (H301 – Toxic if swallowed)

Acute Tox. 3 – Dermal (H311 – Toxic in contact with skin) Skin irritation 2 (H315- Causes skin irritation)

Eye irritation 2 (H319 – Causes serious eye irritation) Acute Tox. 2 – Inhalation (H330 – Fatal if inhaled) STOT SE 3 (H335 – May cause respiratory irritation)

STOT RE 1 (H372 – Cause damage to organs through prolonged or repeated exposure) Aquatic Acute 1 (H400 – Very toxic to aquatic life)

Aquatic Chronic 1 (H410- Very toxic to aquatic life with long lasting effects)

GHS08 GHS09 GHS06

2.2

Label elements : Labelling in accord with paragraph (f) of 1910.1200

2.2.1 Signal word – Danger 2.2.2 Hazard statements –

H301 – Toxic if swallowed H311 – Toxic in contact with skin H315- Causes skin irritation H319 – Causes serious eye irritation H330 – Fatal if inhaled

H335 – May cause respiratory irritation

H372 – Cause damage to organs through prolonged or repeated exposure H400 – Very toxic to aquatic life

H410 – Very toxic to aquatic life with long lasting effects 2.2.3 Hazard pictograms –

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ABN: Para-SHOT 3.0 Page 2 of 9

GHS08 GHS09 GHS06 2.2.4 Precautionary statements –

P264 – Wash face, hands and any exposed skin thoroughly after handling P260 - Do not breathe dust/fume/ gas/mist/vapours/spray.

P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P330 - Rinse mouth

P273 - Avoid release to the environment.

P391 - Collect spillage.

2.3 Other Information

Hazard Ratings : NFPA & HMIS Health: 4

Flammability: 0 Reactivity: 0

ROUTES OF ENTRY: Ingestion, Inhalation, eye, and dermal contact 3. Composition /Information on Ingredients

3.1 Composition

Chemical name : 1,1-dimethyl-4,4'-bipyridinium dichloride Molecular Formula : C12H14Cl2N2

Molecular weight : 257.16 CAS no. : 1910-42-5

% concentration : 97 % (3% water)

The only impurity permitted in paraquat is free 4,4'-bipyridyl at a maximum level of 0.25%.

3.2. Common name and synonyms

Chemical Name :Paraquat dichloride

CHEMICAL FAMILY: Pyridinium Compounds Synonyms :

 1,1'-DIMETHYL-4,4'-BIPYRIDINIUM

 1,1'-Dimethyl-4,4'-bipyridinium cation

 1,1'-DIMETHYL-4,4'-BIPYRIDINIUM DICHLORIDE

 1,1'-DIMETHYL-4,4'-BIPYRIDINIUM DICHLORIDE TRIHYDRATE

 1,1'-Dimethyl-4,4'-bipyridinium dimethosulfate

 1,1'-dimethyl-4,4'-bipyridinium ion

 ARIAL GRAMOXONE(R)

 DEXTRONE X(R)

 Dimethyl-4,4'-bipyridinium bis(methyl sulfate)

 DIMETHYLDIPYRIDYL CHLORIDE

 METHYL VIOLOGEN

 METHYL VIOLOGEN DICHLORIDE

 METHYL VIOLOGEN N-HYDRATE

 n,n'-dimethyl-4,4'-bipyridinium dichloride

3.3

Classified Impurities and stabilizing additives contributing to classification of the chemical

No major known impurity have Carcinogen, Mutagen &Reprotoxic (CMR) classification which can contribute to the Classification & Labelling of the chemical.

4. First Aid Measures

4.1 Description of first aid measures

- Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance then give artificial respiration, preferably mouth to mouth, if possible. Call a poison control center or doctor for further treatment advice.

- Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes.

- Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes.

Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye.

- Oral: Have person sip a glass of water if able to swallow. Do not induce vomiting 0

4 0

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ABN: Para-SHOT 3.0 Page 3 of 9

unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.

4.2

Important symptoms &

effects

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Immediate medical attention

Notes for the doctor:There is no specific antidote. Appropriate supportive and symptomatic treatment as indicated by the patient’s condition is recommended.

For 24-hour medical emergency assistance (human or animal) call 1-800-222-1222. For chemical emergency assistance (spill, leak, fire, or accident) call ChemTrec at 1-800-424-9300.

5. Fire Fighting Measures 5.1

suitable extinguishing media

Water, foam, dry chemical, carbon dioxide.

5.2

Special hazard arising from the chemical

Carbon oxides, Hydrogen chloride gas, nitrogen oxides (NOx) Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride gas

5.3

Special protective equipment and precautions for firefighters

Procedures for bipyridilium pesticides are as follows: Small fires: dry chemical, carbon dioxide, water spray, or foam. Large fires: water spray, fog, or foam. Move container from fire area if you can do so without risk. Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material. Poisonous gases are produced in fire. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health and fire officials and pollution control agencies. Containers may explode in fire. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position.

6. Accidental Release Measures

6.1

Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel

Protective equipment: Wear appropriate protective eyeglasses, splash goggles or chemical safety goggles and appropriate respiratory equipments. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls as appropriate to prevent skin contact.

Emergency procedures: Remove an incapacitated worker from further exposure. Keep unconscious victims warm and on their sides to avoid choking if vomiting occurs. Initiate the measures / procedures as mentioned in Section 4.

Removal of ignition sources: Disconnect electrical connection and all other sources of ignition.

Provision of sufficient ventilation: Adequate ventilation should be provided when accidental release occurs.

6.1.2 For emergency responders: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Do not touch the spilled material. Avoid the spread of the spillage by using adsorbents, if this can be done without risks. Ground all equipment containing material.

6.2

Methods and material for containment and cleaning up

(a) Cleaning techniques:If paraquat is spilled, ... ventilate area of spill. Collect spilled material in the most convenient and safe manner and deposit in sealed containers for

reclamation. Liquid containing paraquat should be absorbed in vermiculite, dry sand, earth, or a similar material.

(b) Spillage Disposal: Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment.

Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

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7. Handling and Storage

7.1 Precautions for safe handling

7.1.1. Recommendations shall be specified to:

Read label carefully before use. Avoid contact with skin, eyes or clothing. Avoid breathing dust. Remove personal protective equipment (PPE) immediately after handling this product.

Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing.

7.1.2. Advice on general occupational hygiene:

(a) not to eat, drink and smoke in work areas (b) to wash hands after use; and

(c) To remove contaminated clothing and protective equipment before entering eating areas

7.2

Conditions for safe storage, including any incompatibilities

(a) How to manage risks associated with storage :

Keep in a well-ventilated room. Well closed. Separated from food and feedstuffs. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access

(b) Other advice including: This chemical is inactivated by inert clays and anionic surfactants.

Store in tightly closed containers in a cool, well-ventilated area away from oxidizers, alkyl aryl- sulfonate wetting agents, light. Where possible, automatically pump material from drums or other storage containers to process containers. Sources of ignition such as smoking and open flames are prohibited where this chemical is handled, used, or stored. Metal containers involving the transfer of this chemical should be grounded and bonded. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical.

Wherever this chemical is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings

8. Exposure Controls / Personal Protection

8.1 Control parameters

TLV : 8 hr Time Weighted Avg (TWA): 0.5 mg/cu m; 0.1 mg/cu m (respirable fraction).

REL: TWA 0.1 mg/m3 (resp) [skin]

PEL: TWA 0.5 mg/m3 (resp) [skin]

IDLH: 1 mg/m3

OSHA Standards: Permissible Exposure Limit: Table Z-1 8-hr Time-Weighted Avg: 0.5 mg/cu m. Skin Designation. /Respirable dust

NIOSH Recommendations: 10 hr Time-Weighted avg: 0.1 mg/cu m, respirable fraction, skin.

/Paraquat dichloride 8.2 Exposure controls

8.2.1

Appropriate engineering controls

A system of general or local exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value needs to be provided. Ensure that eyewash stations and safety showers are proximal to the work-station location. Do not release to the atmosphere or water streams.

8.2.2

Individual protection measures

(a) Eye / face protection: Wear appropriate protective eyeglasses, splash goggles or chemical safety goggles and face shield.

(b) Skin protection: Wear appropriate protective clothing like impervious lab coat, apron or coveralls.

(i) Hand protection: Use compatible chemical / solvent resistant protective gloves made of suitable materials like rubber, plastic, etc.

(ii) Other: Wear appropriate boots and other footwear.

(c) Respiratory protection: In case of brief exposure or low pollution, use respiratory filter device. In case of intensive or longer exposure, use self-contained

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ABN: Para-SHOT 3.0 Page 5 of 9

respiratory protective device. Short term filter device: Filter AX. In case of emergency spills, use a NIOSH approved respirator with any N, R, P, or HE filter.

(d) General protective and hygienic measures:

• Keep away from foodstuffs, beverages and feed.

• Immediately remove all soiled and contaminated clothing.

• Wash hands before breaks and at the end of work.

• Store protective clothing separately.

9. Physical & Chemical Properties

9.1

Information on basic physical and chemical

properties

(a) Appearance: off-white powder (b) Odour:

Odorless

(c) Auto-ignition temperature: Not known (d) pH: 4.3

(e) Melting point/freezing point: >300 °C (lit.)

(f) Boiling point (760 mm Hg): Decomposes at 175-180 deg C (347-356 deg F) (g) Flash point: Not Available

(h) Vapour pressure : at 25°C: <0.0001 Pa (i) Flammability (solid, gas): Not applicable

(j) Upper/lower flammability or explosive limits: Not applicable

(k) Solubility(ies): (water) - 62g/100ml at 20°C; Practically insoluble in organic solvents (l) Partition coefficient: log Kow = -4.22 at pH 7.4

(m) Bulk Density : 1.130g/ml 9.2 Other information No relevant information available 10. Stability and Reactivity

10.1 Reactivity Paraquat Dichloride (1910-42-5) is stable in acidic media, but unstable in alkaline media.

Paraquat is corrosive to metals

10.2 Chemical stability Stable at normal temperature and pressure 10.3

Possibility of hazardous reactions

No information known

10.4 Conditions to

avoid Not known

10.5 Incompatible

materials Incompatible with strong oxidizing agents.

10.6

Hazardous decomposition products

When heated to decomposition it emits toxic fumes of nitric oxides

11. Toxicological Information

11.1

Information on toxicological effects

(a) acute toxicity:

 Oral toxicity in category 3

 Dermal toxicity in category 3

 Inhalation toxicity in category 2 (b) skin corrosion/irritation: irritant in category 2 (c) serious eye damage/irritation: irritant in category 2 (d) respiratory or skin sensitization: Not sensitizing (e) germ cell mutagenicity: no evidence in vivo assays

(f) carcinogenicity:No evidence of carcinogenicity in the rat mouse studies (g) Reproductive/ developmental toxicity: No evidence

(h) STOT-SE/RE: STOT SE – 3; STOT RE : 1

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11.2

Numerical measures of toxicity (such as acute toxicity estimates)

3-Generation Reproduction - rat: Systemic NOEL=25 ppm (1.25 mg/kg/day); Systemic LEL=75 ppm (3.75 mg/kg/day) (increased incidence of alveolar histiocytosis in the lungs);

Reproductive NOEL=150 ppm (7.5 mg/kg/day) (HDT); Reproductive LEL=none; core grade guideline (Chevron Chemical Co., 1982).

2-Year Feeding (oncogenic) - rat: Systemic NOEL=25 ppm (1.25 mg/kg/day); Systemic LEL=75 ppm (3.75 mg/kg/day) (increased incidence of opacities, cataracts and non- neoplastic lung lesions); core grade guideline for chronic toxicity, supplementary for oncogenicity (Chevron Chemical Co., 1983b).

Teratology - mouse: Maternal NOEL=1 mg/kg/day; Maternal LEL=5 mg/kg/day (14.2%

reduction in body weight); Fetotoxic NOEL=5 mg/kg/day; Fetotoxic LEL=10 mg/kg/day (HDT; partially ossified sternebrae in 26.3% of fetuses); core grade minimum; (Chevron Chemical Co., 1977b).

It has been estimated that a lethal dose in man is about 14 mL of a 40% solution of paraquat.

ADME : Paraquat was poorly absorbed after oral administration to rats, dogs and mice.

Once absorbed, paraquat was rapidly distributed to most tissues but especially to lungs and kidneys. Tissues other than lungs did not retain paraquat.

EPIDEMIOLOGY STUDIES: An epidemiology study of poisoning during 1 yr (from May 1, 1986) was done of the Galle district in rural Sri Lanka. 73% of poisoning was due to intentional self-poisoning. Paraquat was the /most common/ poisoning agent and had a high fatality rate of 68%. This rate was significantly higher than that for insecticides (p<0.001)

GENOTOXICITY: Paraquat was weakly positive in the mammalian cells (human

lymphocytes) in culture cytogenetic assay, with and without metabolic activation (S-9 mix).

Increases in chromosome damage were found in non-activated cultures exposed to the 1250 ug/mL and higher levels of paraquat. In the presence of S-9, statistically significant (P < 0.01) increases in chromosome damage were observed at 1750 ug/mL in the case of one donor and at 2500 ug/mL in the case of another donor.

Acute studies:

 Acute Exposure/ Oral LD50 (mg/kg) rats 126, guinea pigs 22, and monkeys 50. Toxicity included anorexia, adipsia, diarrhea, hyperpnea, dyspnea, tachycardia, necrosis of liver, kidney, and GI tract with primary lesions in lungs. Lung hemorrhage and edema in all dead in less than 7 days.

 LD50 Rat male oral 344 mg/kg

 LD50 Rale female oral 283 mg/kg

LD50 Turkey (White, female) dermal 375 mg/kg bw /from table 11.3

Chemical if, listed in NTP or IARC or by OSHA as Carcinogens

Paraquat was negative in reverse mutation assays in Salmonella with or without metabolic activation using hepatic homogenates (Anderson et al., 1972; Benigni et al., 1979). It was also negative in dominant lethal tests using both CDI and Swiss-Webster mice (Pasi et al., 1974) and in rat bone marrow chromosomal aberration tests.

11.4 Other information Target organs: Eyes, skin, respiratory system, heart, liver, kidneys, gastrointestinal tract 12. Ecological Information

12.1 Eco – Toxicity

 EC50; Species: Pseudokirchneriella subcapitata (Green algae); Conditions: freshwater, static;

Concentration: 1.16 uM for 48 hr; Effect: decreased population growth rate /100% purity.

 LD50; Species: Drosophila melanogaster (Fruit fly, age 5 days, wild type Oregon-R-strain) environmental exposure route 20 mM for 48 hr.

 EC50; Species: Daphnia magna (Water flea, <24 hr); Conditions: freshwater, static, 20 deg C, pH 7.8, hardness 95.8 mg/L CaCO3, alkalinity 189.3 mg/L CaCO3, dissolved oxygen 8.4 mg/L; Concentration: 4550 ug/L for 48 hr (95% confidence interval: 4100-5100 ug/L);

Effect: intoxication, immobilization /Osaquat, 27.6% AI/

 EC50; Species: Daphnia magna (Water flea, adult); Conditions: freshwater, static, 23 deg C;

Concentration: 3200 ug/L for 48 hr; Effect: intoxication, immobilization /20% Paraquat, 10%

Lissapol

 LC50; Species: Oncorhynchus mykiss (Rainbow trout, weight 0.5 g); Conditions: static bioassay without aeration, 13 deg C, pH 7.2-7.5, water hardness 40-50 mg/L as calcium carbonate and alkalinity of 30-35 mg/L; Concentration: 15 mg/L for 96 hr (95% confidence interval: 11-19 mg/L). Soluble concentrate, 2 lb (cation)/gal.

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12.2 Persistence and degradability

The biodegradation of paraquat is very slow when strongly adsorbed to clay or organic matters in soils because it becomes unavailable. When not in the absorbed-state, paraquat will

biodegrade. Some photo degradation may occur on plant leaves or soil surfaces exposed to sunlight. Field dissipation half-lives in soil are reported to range from 99-4747 days. If released into water, paraquat is expected to adsorb very strongly to suspended solids and sediment based upon the observed Koc range and observations from various studies. Volatilization from water surfaces is not expected to be an important fate process based upon this compound's estimated Henry's Law constant.

12.3 Bioaccumulative potential

An observed BCF range of 0.05-6.9 suggests bio concentration in aquatic organisms is low.

Hydrolysis and direct photolysis in water are not expected to be important environmental fate processes based upon laboratory studies. Occupational exposure to paraquat may occur through inhalation and dermal contact with this compound at workplaces where paraquat is produced or used. However, the respiratory exposure to paraquat was found to be negligible compared to dermal exposure during field spraying of the herbicide

12.4 Environmental fate (exposure)

Mobility in soil: Paraquat Dichloride (1910-42-5)

an

observed Koc range of 15,473-1,000,000 indicates that paraquat is expected to be immobile in soil (SRC). Field studies and soil column leaching studies have demonstrated that paraquat is strongly adsorbed to soil constituents and does not leach under environmental conditions. The process that may control the fate of paraquat in soil is slow biodegradation

If released to air, a vapor pressure of <7.5X10-8 mm Hg at 25 deg C indicates paraquat dichloride will exist solely in the particulate phase in the atmosphere. Particulate-phase paraquat will be removed from the atmosphere by wet or dry deposition. If released to soil, paraquat is expected to have no mobility based upon an observed Koc range of 15,473- 1,000,000. Field studies and soil column leaching studies have demonstrated that paraquat does not leach under environmental conditions. Volatilization from moist soil surfaces is not expected to be an important fate process based upon an estimated Henry's Law constant of

<4.1X10-14 atm-cu m/mole.

12.5 Other adverse effects

The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

13. Disposal Considerations

13.1

Waste treatment methods

(a) Waste treatment containers and methods:

Waste Disposal Method: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.

Container disposal – Dispose of product containers, waste containers, and residues according to label instructions and local, state, and federal health and environmental regulations.

WGK Germany: 3

(b) Sewage disposal: Sewage disposal shall be discouraged 13.2 Additional

information:

Paraquat is rapidly inactivated in soil. It is also inactivated by anionic surfactants. Therefore an effective and environmentally safe disposal method would be to mix the product with ordinary household detergent and bury the mixture in clay soil.

14. Transport Information

(Information includes RID, ADR, AND, ICAO, IMDG, IATA-DGR)

14.1. UN number : 2810 (ADR/RID; IMDG; IATA)

14.2. UN proper shipping name :Toxic liquids, organic, n.o.s. (paraquat dichloride)

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ABN: Para-SHOT 3.0 Page 8 of 9

14.3. Transport hazard class(es): 6.1 14.4. Packing group: II

14.5. Environmental hazards (e.g., Marine pollutant (Yes/No)) : Yes 14.6. Special precautions for user : Not required

14.7. Quantity specification : for single packaging’s and combination packaging’s containing inner packaging’s with Dangerous Goods > 5L for liquids or > 5kg for solids

15. Regulatory Information

15.1

Safety, health and environmental regulations/legislat ion

 Product related hazard information : The product has been classified and marked in accordance with directives on hazardous materials

 Hazard statements:

 May be fatal if swallowed.

 Fatal if inhaled.

 Corrosive.

 Causes irreversible eye damage.

 Harmful if absorbed through skin.

 Prolonged or frequently repeated contact may cause allergic reactions in some individuals.

 Signal word – DANGER

 Precautionary statements :

 Do not breathe spray mist. Wear a dust mist respirator. Do not get in eyes or on clothing. Avoid contact with skin.

 IMPORTANT: Inhalation is an unlikely route of exposure due to low vapor pressure, but mucosal irritation or nosebleeds may occur. Prolonged contact with this

concentrated product can irritate your skin.

 Other regulations: Listed /not listed within the following regulation

 TSCA (TOXIC SUBSTANCE CONTROL ACT) - listed

 EU CLP Regulation (EC) No 1272/2008 - listed

 California Prop 65 Known Carcinogens – not listed

 U.S. EPA Carcinogens – E, Unlikely 16. Other Information

16.1 Indication of changes

Section 1: Identification of the substance/mixture and of the company/undertaking Section 2: Hazard Identification - Changes in Classification and Labelling.

Section 3: Composition /Information on Ingredients Section 5: Fire-fighting measures

Section 6: Accidental Release measures Section 7: Handling and storage.

Section 8: Exposure Controls/Personal protection.

Section 9: Physical and Chemical properties.

Section 10: Stability and Reactivity.

Section 11: Toxicological Information.

Section 12: Ecological Information.

Section 14: Transport labeling Section 15: Regulatory Information

16.2 Abbreviations and acronyms

 OSHA: Occupational Safety and Health Administration

 GHS: Globally harmonized system on classification and labelling

 TWA: Time Weighted Average

 STEL: Short Term Exposure Limit

 PEL: Permissible Exposure Limits

 ACGIH: American Conference of Governmental Industrial Hygienists

 NIOSH: National Institute for Occupational Safety and Health

 TLV: Threshold Limit Value

 MARPOL: Marine pollution

 IBC Code: International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk

 IARC: International Agency for Research on Cancer

 NTP: National Toxicology Program

 CAS: Chemical Abstracts Service (division of the American Chemical Society)

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ABN: Para-SHOT 3.0 Page 9 of 9

Disclaimer: This product is a registered agricultural chemical and must therefore be used in accordance with the container label directions. The information above is believed to be accurate and represents the best information currently available to us. No representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. This SDS shall be used as a guide only. Users should make their own investigations to determine the suitability of the information for their particular purposes. Consult Sharda USA LLC. for further information.

 LC50: Lethal concentration, 50 percent

 LD50: Lethal dose, 50 percent

 IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association

 IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization

 ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"

16.3

Key literature references and sources for data

 http://www.chemicalbook.com/CASEN_1910-42-5.htm

 http://www.chemicalbook.com/ProdClassDetail/PyridiniumCompounds_0_EN.htm

 http://www.epa.gov/iris/subst/0183.htm

 http://www.scbt.com/pt/datasheet-257968.html

 http://pubchem.ncbi.nlm.nih.gov/compound/15938?from=summary#section=Experime ntal-Properties

 http://www.hazmattool.com/info.php?a=Toxic%20solids,%20organic,%20n.o.s.&b=U N2811&c=6.1

 http://en.wikipedia.org/wiki/List_of_UN_numbers_2801_to_2900

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