SECTION 4: First aid measures

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 05/15/2015

05/15/2015 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product form : Mixture

Product name : Bonide Bon-Neem II Fungicide-Miticide-Insecticide Concentrate

Product code : 70051754

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Insecticide, Fungicide, Miticide

1.3. Details of the supplier of the safety data sheet Bonide Products, Inc.

6301 Sutliff Road Oriskany, NY 13424 T (315) 736-8231 www.bonide.com

1.4. Emergency telephone number

Emergency number : CHEMTREC - 1 (800) 424-9300 and/or 1 (703) 527-3887

SECTION 2: Hazards identification

Not classified

2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards No additional information available

2.4. Unknown acute toxicity (GHS-US) No data available

SECTION 3: Composition/information on ingredients

Name Product identifier % Classification (GHS-US)

Clairified Hydrophobic Extract of Neem Oil (CAS No)8002-65-1 70 Not classified

Piperonyl Butoxide (CAS No)51-03-6 2.5 Not classified

Pyrethrins (CAS No)8003-34-7 0.25 Acute Tox. 3 (Oral), H301

Acute Tox. 3 (Inhalation:vapour), H331

SECTION 4: First aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.

First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse.

First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist.

First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.

4.3. Indication of any immediate medical attention and special treatment needed No additional information available

05/15/2015 EN (English US) 2/5

SECTION 5: Firefighting measures

suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture No additional information available

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.

Emergency procedures : Ventilate area.

6.2. Environmental precautions Prevent entry to sewers and public waters.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in original container. Keep container closed when not in use.

Incompatible products : Strong bases. strong acids.

Incompatible materials : Sources of ignition.

7.3. Specific end use(s) No additional information available

SECTION 8: Exposure controls/personal protection

Pyrethrins (8003-34-7)

USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.

Respiratory protection : Wear approved mask.

Other information : When using, do not eat, drink or smoke.

SECTION 9: Physical and chemical properties

Physical state : Liquid

Appearance : Yellow to red liquid.

Color : Yellow to red.

Odor : Garlic citrus.

Odor threshold : No data available

pH : 3.37

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : No data available

Freezing point : 3 °C

Boiling point : > 200 °C

Flash point : 74 °C

Self ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : <2 mmHg @ 25 degrees C

Relative vapor density at 20 °C : No data available

Relative density : 0.98 - 0.99

Solubility : Insoluble in water.

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information No additional information available

SECTION 10: Stability and reactivity

No additional information available

10.2. Chemical stability Stable under normal conditions.

10.3. Possibility of hazardous reactions Not established.

10.4. Conditions to avoid Extremely high or low temperatures.

10.5. Incompatible materials strong acids. Strong bases.

10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

Acute toxicity : Not classified

Pyrethrins (8003-34-7)

LD50 oral rat 200 mg/kg (Rat)

LC50 inhalation rat (mg/l) 3.4 mg/l/4h (Rat) Skin corrosion/irritation : Not classified

pH: 3.37 Serious eye damage/irritation : Not classified

pH: 3.37 Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

05/15/2015 EN (English US) 4/5

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

Potential Adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

Pyrethrins (8003-34-7)

LC50 fish 1 0.049 mg/l (96 h; Lepomis macrochirus)

LC50 other aquatic organisms 1 0.011 mg/l (96 h; Gammarus sp.)

LC50 fish 2 0.009 mg/l (96 h; Ictalurus punctatus)

Threshold limit other aquatic organisms 1 0.011 mg/l (96 h; Gammarus sp.)

12.2. Persistence and degradability

Bonide Bon-Neem II Fungicide-Miticide-Insecticide Concentrate Persistence and degradability Not established.

Clairified Hydrophobic Extract of Neem Oil (8002-65-1) Persistence and degradability Not established.

Pyrethrins (8003-34-7)

Persistence and degradability Readily biodegradable in water.

12.3. Bioaccumulative potential

Bonide Bon-Neem II Fungicide-Miticide-Insecticide Concentrate Bioaccumulative potential Not established.

Clairified Hydrophobic Extract of Neem Oil (8002-65-1) Bioaccumulative potential Not established.

Pyrethrins (8003-34-7)

Log Pow 6.15 (Estimated value)

12.4. Mobility in soil

Pyrethrins (8003-34-7)

Ecology - soil Not toxic to plants. Toxic to bees.

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

No dangerous good in sense of transport regulations Additional information

Other information : No supplementary information available.

ADR

Transport document description :

Transport by sea

No additional information available Air transport

No additional information available

SECTION 15: Regulatory information

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:

CAUTION - Harmful if inhaled. Avoid breathing vapor or spray mist. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Remove and wash contaminated clothing before reuse. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.

15.1. US Federal regulations

Pyrethrins (8003-34-7)

Not listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's

List of Lists) :

1 lb

15.2. International regulations CANADA

No additional information available

EU-Regulations

No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Classification according to Directive 67/548/EEC or 1999/45/EC Not classified

15.2.2. National regulations No additional information available

15.3. US State regulations

Pyrethrins (8003-34-7)

U.S. - Massachusetts - Right To Know List

U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Other information : None.

Full text of H-phrases: see section 16:

--- Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 3

--- Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3

--- H301 Toxic if swallowed

--- H331 Toxic if inhaled

SDS US (GHS HazCom 2012) - Pesticides

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.