筑波大学大学院数理物質科学研究科 物理学専攻
初貝 安弘
量子液体とトポロジカル秩序
Quantum liquids & topological order Use of the Bulk-edge correspondence
物理科学特別講義(バルクエッジ対応の物理)
Physics of bulk-edge correspondence, Hiroshima Univ. June 27-29, 2012
バルクエッジ対応の物理:背景2
background 2Quantum Liquids without Symmetry Breaking
Quantum Liquids in Low Dimensional Quantum Systems Low Dimensionality, Quantum Fluctuations
No Symmetry Breaking
No Local Order Parameter
Various Phases & Quantum Phase Transitions Gapped Quantum Liquids in Condensed Matter
Integer & Fractional Quantum Hall States S=1 Spin chain ( Haldane Phase )
Integer spin chains (S=1,2) with dimerization Generic valence bond solid (VBS) states
Dimer models (Rokhsar-Kivelson) Half filled Kondo Lattice
How to Classify the Quantum Liquid Phases New way to think about !
Topological/quantum orders
Order & Symmetry
Magnetic Order
Disordered Ordered
Order & Symmetry
Magnetic Order
Disordered Ordered
special direction! ( symmetry broken)
Order & Symmetry
Magnetic Order
Disordered Ordered
No special direction (symmetric)
special direction! ( symmetry broken)
Order & Symmetry
Magnetic Order
Disordered Ordered
m( ⇤ ⇤ r )
⇥ r
Local magnetic structure around Local order parameter :
Ferromagnetic / Antiferromagnetic, ...
No special direction (symmetric)
special direction! ( symmetry broken)
Order & Symmetry
Magnetic Order
Disordered Ordered
m( ⇤ ⇤ r )
⇥ r
Local magnetic structure around Local order parameter :
Ferromagnetic / Antiferromagnetic, ...
m(r ) ⇥ =0 ?
⌅ m(r )m(r ) ⇧ ⇥ 0 ? ( | r r | ⇥⇤ )
Spontaneous symmetry breaking Long Range Order
No special direction (symmetric)
special direction! ( symmetry broken)
Order & Symmetry
Disordered
Quantum Disordered Gapped
Order & Symmetry
Disordered
Quantum Disordered
No Observables to Characterize
Gapped
Order & Symmetry
Disordered
Quantum Disordered
Quantum Liquids & Spin Liquids No Observables to Characterize
Gapped
Order & Symmetry
Disordered
Quantum Disordered Gapped
Quantum Liquids & Spin Liquids
Order & Symmetry
Disordered
Quantum Disordered Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap
Order & Symmetry
Disordered
Quantum Disordered Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap
No low lying excitations
Order & Symmetry
Disordered
Quantum Disordered
No Response against small perturbation
Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap
No low lying excitations
Order & Symmetry
Disordered
Quantum Disordered
No Response against small perturbation
Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap No low lying excitations
?? 打てども響かず
Order & Symmetry
Disordered
Quantum Disordered
No Response against small perturbation
Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap No low lying excitations
?? 打てども響かず
c.f. gapless modes:
acoustic phonons zero sounds
spin waves
Order & Symmetry
Disordered
Quantum Disordered
Need Novel Kind of Orders :
No Response against small perturbation
Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap No low lying excitations
?? 打てども響かず
c.f. gapless modes:
acoustic phonons zero sounds
spin waves
Order & Symmetry
Disordered
Quantum Disordered
Need Novel Kind of Orders :
No Response against small perturbation
Gapped
Quantum Liquids & Spin Liquids
Gapped: Nothing in the gap No low lying excitations
?? 打てども響かず
c.f. gapless modes:
acoustic phonons zero sounds
spin waves
Topological Order
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
E O(1)
Excitation Gap
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Gapless excitation:
E O(1)
Excitation Gap
Need some mechanism
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
E O(1)
Excitation Gap
Need some mechanism
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
breaking of continuous symmetry based on the local order parameter
E O(1)
Excitation Gap
Need some mechanism
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
Slowly varying its local order parameter : spin waves Lieb-Schultz-Mattis
breaking of continuous symmetry based on the local order parameter
E O(1)
Excitation Gap
Need some mechanism
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
Slowly varying its local order parameter : spin waves Lieb-Schultz-Mattis
breaking of continuous symmetry based on the local order parameter
E O(1)
Excitation Gap
Need some mechanism
Any kinds of Fermi surfaces
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
Appearance of Edge states
Slowly varying its local order parameter : spin waves Lieb-Schultz-Mattis
breaking of continuous symmetry based on the local order parameter
E O(1)
Excitation Gap
Need some mechanism
Any kinds of Fermi surfaces
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
Appearance of Edge states
Slowly varying its local order parameter : spin waves Lieb-Schultz-Mattis
breaking of continuous symmetry based on the local order parameter
Topological Origin
Quantum Hall Effects & Haldane spin chains
quantum/topological order
E O(1)
Excitation Gap
Need some mechanism
Any kinds of Fermi surfaces
Excitations and Local Order Parameter
Discrete Symmetry Breaking: (ex. Ising order)
Local disturbance induces a finite cost
Nambu-Goldstone mechanism Gapless excitation:
Appearance of Edge states
Slowly varying its local order parameter : spin waves Lieb-Schultz-Mattis
breaking of continuous symmetry based on the local order parameter
Topological Origin
Quantum Hall Effects & Haldane spin chains
quantum/topological order
E O(1)
Excitation Gap
Need some mechanism
Any kinds of Fermi surfaces
fermions as boundary states in high dimensions
( domain wall fermions)
How to characterize the phase
Without Symmetry Breaking Quantum Liquids are Featureless !!
Use Quantum Interference!
The RVB state by Anderson
Quantum Liquid
|Singlet Pair12 = 1
2 (| 1 2 | 1 2 )
|G =
J=Dimer Covering
cJ ij |Singlet Pairij
Dimer covering
with non orthogonal
& local states
The RVB state by Anderson
Quantum Liquid
|Singlet Pair12 = 1
2 (| 1 2 | 1 2 )
|G =
J=Dimer Covering
cJ ij |Singlet Pairij
Local Singlet Pairs :
(Fundamental Objects)
Spins disappear as a Singlet pair
Local Quantum Objects for characterization
The RVB state by Pauling
One more Quantum Liquid
|Bond12 = 1
2 (|1 + |2 ) = 1
2 (c†1 + c†2)|0
|G =
J=Dimer Covering
cJ ij |Bondij
Local Covalent Bonds : (Fundamental Objects)
Do Not use the Fermi Sea
Delocalized charge as a covalent bond
Local Quantum Objects for characterization
Tools to play with the Quantum Liquids
Local Characterization
Quantized Berry Phases as
a Topological Local Order Parameter Global Characterization
Entanglement Entropy as a Novel Tool
for the Condensed Matter Physics
Quantum Liquids Featureless !!
Closely related to the edge states
「対称性の破れ」で物質相の記述に本当に十分?
「対称性の破れ」で物質相の記述に本当に十分?
真に量子的な相
いかなる対称性の破れもない
古典的な秩序変数が存在しない
なおかつ多種多様な物質相が存在する!!
「対称性の破れ」で物質相の記述に本当に十分?
真に量子的な相
いかなる対称性の破れもない
古典的な秩序変数が存在しない
なおかつ多種多様な物質相が存在する!!
量子液体相、スピン液体
秩序変数 対称性の破れ
「対称性の破れ」で物質相の記述に本当に十分?
真に量子的な相
いかなる対称性の破れもない
古典的な秩序変数が存在しない
なおかつ多種多様な物質相が存在する!!
量子液体相、スピン液体
トポロジカル秩序
秩序変数 対称性の破れ
量子秩序
「対称性の破れ」で物質相の記述に本当に十分?
真に量子的な相
いかなる対称性の破れもない
古典的な秩序変数が存在しない
なおかつ多種多様な物質相が存在する!!
トポロジカルな量子相転移
量子液体相、スピン液体
トポロジカル秩序
秩序変数 対称性の破れ
量子秩序
量子液体相、スピン液体相とは??
量子液体相、スピン液体相とは??
整数量子ホール相、分数量子ホール相、
量子スピンホール相:トポロジカル絶縁体
フラストレートしたスピン系、ダイマー系
RVB状態、Haldane スピン系、VBS状態
近藤格子、Kitaev 模型、Levin-Wen模型
量子液体相、スピン液体相とは??
整数量子ホール相、分数量子ホール相、
量子スピンホール相:トポロジカル絶縁体 フラストレートしたスピン系、ダイマー系 RVB状態、Haldane スピン系、VBS状態 近藤格子、Kitaev 模型、Levin-Wen模型
トポロジカルな量子的秩序変数
量子液体相、スピン液体相とは??
整数量子ホール相、分数量子ホール相、
量子スピンホール相:トポロジカル絶縁体 フラストレートしたスピン系、ダイマー系 RVB状態、Haldane スピン系、VBS状態 近藤格子、Kitaev 模型、Levin-Wen模型
トポロジカルな量子的秩序変数
ベリー位相 チャーン数
エンタングルメント
エッジ状態
A way to the Quantum liquids
Example: frustration
Relax local degrees of freedom
Frustration : residual entropy spin
charge
H = X
H loc
local degeneracy
# deg.
e
cNc : const.
N : system size
⇡
# low energy modes
Quantum effects
Frustration : residual entropy spin
charge
H = X
H loc
local degeneracy
# deg.
e
cNc : const.
N : system size
⇡
# low energy modes
Quantum effects
Residual Entropy to form gapped quantum liquid
H = X
H loc
local degeneracy
Gap opening
Stabilization to relax local entropy
Quantum effects
Residual Entropy to form gapped quantum liquid
H = X
H loc
local degeneracy
Gap opening
Stabilization to relax local entropy
Quantum effects
Residual Entropy to form gapped quantum liquid
Formation of local quantum object Multimer as a generic dimer
H = X
H loc
local degeneracy
Gap opening
Stabilization to relax local entropy
Covalent molecular orbital
c.f. Tamura ’06, Matsuda-Motome ’06, Katsufuji
trimer tetramer
Quantum effects
Energy band & gap : physicist & chemist ? physicist
Sorry if I’m wrong
itinerant electrons
Energy band & gap : physicist & chemist ?
make energy band metal
physicist
Sorry if I’m wrong
itinerant electrons hopping
Energy band & gap : physicist & chemist ?
Covalent molecular orbital
make energy band metal
physicist
Sorry if I’m wrong
itinerant electrons hopping
Energy band & gap : physicist & chemist ?
Covalent molecular orbital physicist
Sorry if I’m wrong
itinerant electrons hopping
Energy band & gap : physicist & chemist ?
Covalent molecular orbital
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
Opening gap stabilize
hopping
Energy band & gap : physicist & chemist ?
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
Opening gap stabilize
chemist
form molecules first hopping
Energy band & gap : physicist & chemist ?
Covalent molecular orbital
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
Opening gap stabilize
chemist
form molecules first hopping
Energy band & gap : physicist & chemist ?
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
Opening gap stabilize
chemist
form molecules first hopping
Energy band & gap : physicist & chemist ?
Covalent molecular orbital
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
Opening gap stabilize
chemist
form molecules first hopping
Energy band & gap : physicist & chemist ?
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
make bands of molecules
stabilize
chemist
form molecules first
Dimer & Multimer non orthogonality
Energy band & gap : physicist & chemist ?
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
make bands of molecules
stabilize
chemist
form molecules first
Dimer & Multimer Adiabatic process Insulator
non orthogonality
EF
Energy band & gap : physicist & chemist ?
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
make bands of molecules
stabilize
chemist
form molecules first
Dimer & Multimer Adiabatic process Insulator
quantum objects to be respected non orthogonality
EF
Energy band & gap : physicist & chemist ?
Peierls instability
physicist
Sorry if I’m wrong
itinerant electrons
make bands of molecules
stabilize
chemist
form molecules first
Dimer & Multimer Adiabatic process Insulator
quantum objects to be respected non orthogonality
short range entanglement
EF
Residual Entropy to form gapped quantum liquid
H = X
H loc
local degeneracy
Local anti-ferromagnetism
Local charge ordering
Residual Entropy to form gapped quantum liquid
Multimer as a generic dimer
H = X
H loc
local degeneracy
Gap opening
by quantum effect Stabilization to relax
local entropy Covalent molecular orbital
Singet formation
Dimer formation
singlet pair
covalent bond
Residual Entropy to form gapped quantum liquid
Multimer as a generic dimer
H = X
H loc
local degeneracy
Gap opening
by quantum effect Stabilization to relax
local entropy Covalent molecular orbital
Singet formation
Dimer formation
singlet pair
covalent bond
RVB: Anderson
Residual Entropy to form gapped quantum liquid
Multimer as a generic dimer
H = X
H loc
local degeneracy
Gap opening
by quantum effect Stabilization to relax
local entropy Covalent molecular orbital
Singet formation
Dimer formation
singlet pair
covalent bond
RVB: Anderson
RVB: Pauling
# low energy modes
Quantum effects to relax classical frustration
Quantum & local Gapped
# deg.⇡
e
cNClassical frustration
Quantum effects
finite low energy states (topological)
Gapped quantum liquid
(boundary condition dependent) gapped
“Topological insulators” (c.f. QHE, QSHE, top.super, Haldane chain, ladders... )
Gapped quantum liquids
Still Lots of variety
Absence of fundamental symmetry breaking
No Response against small perturbation
No low lying excitations
??
gapless modes:
acoustic phonons zero sounds
spin waves
Zoo
Nambu-Goldstone
Fermi surface
massless Dirac fermions with/without doubling
Gapped quantum liquids
Something for classification Still Lots of variety
Absence of fundamental symmetry breaking
No Response against small perturbation
No low lying excitations
??
gapless modes:
acoustic phonons zero sounds
spin waves
Zoo
Nambu-Goldstone
Fermi surface
massless Dirac fermions with/without doubling
Gapped quantum liquids
Something for classification
Topological order Berry connections
Edge states & entanglement
Still Lots of variety
Absence of fundamental symmetry breaking
No Response against small perturbation
No low lying excitations
??
gapless modes:
acoustic phonons zero sounds
spin waves
Zoo
Nambu-Goldstone
Fermi surface
massless Dirac fermions with/without doubling
How to understand gapped quantum liquids ?
Bulk state
Edge state
Bulk-Edge correspondence
Bulk without boundary is boring
Characteristic localized states with edges
QHE, Spin chains, Graphene, QSHE, Andreev bound st., photonic crystals, cold atoms ...
YH’93
Quantum Liquids & Entanglement
Gapped quantum liquids featureless
bulk
Quantum Liquids & Entanglement
Divide into A & B
A B
Gapped quantum liquids featureless
bulk
Quantum Liquids & Entanglement
Divide into A & B
A B
Gapped quantum liquids featureless
bulk
How much the states are entangled
between A & B?
Quantum Liquids & Entanglement
Divide into A & B
A B
Gapped quantum liquids featureless
bulk
How much the states are entangled between A & B?
Entanglement entropy
⇢AB = | ABih AB|
⇢A = TrB ⇢AB SA = hlog ⇢Ai
Characterize the gapped quantum liquids
Quantum Liquids & Entanglement
Divide into A & B
A B
Gapped quantum liquids featureless
bulk
How much the states are entangled between A & B?
Entanglement entropy
⇢AB = | ABih AB|
⇢A = TrB ⇢AB SA = hlog ⇢Ai
Characterize the gapped quantum liquids
Edge states near the boundary between A & B
Quantum Liquids & Entanglement
Divide into A & B
A B
Gapped quantum liquids featureless
bulk
How much the states are entangled between A & B?
Entanglement entropy
⇢AB = | ABih AB|
⇢A = TrB ⇢AB SA = hlog ⇢Ai
Characterize the gapped quantum liquids
Effective edge states reflect quantum entanglement Edge states near the boundary between A & B
local deg. freedom, entanglement and edge states
In-gap edge states
# local degree of freedom How to relax local entropy
Quantum effects with boundaries
Entangled & gapped
# deg.⇡
e
cN # deg.⇡e
Ve/V0Ve : volume (length) of edges
local deg. freedom, entanglement and edge states
In-gap edge states
# local degree of freedom How to relax local entropy
Quantum effects with boundaries
Quantum entanglement EATS local degrees of freedom and makes the system gapped
Entangled & gapped
# deg.⇡
e
cN # deg.⇡e
Ve/V0Ve : volume (length) of edges
local deg. freedom, entanglement and edge states
In-gap edge states
# local degree of freedom How to relax local entropy
Quantum effects with boundaries
Quantum entanglement EATS local degrees of freedom and makes the system gapped
Entangled & gapped
# deg.⇡
e
cN # deg.⇡e
Ve/V0Ve : volume (length) of edges
Superconductivity :Anderson mechanism
NG bosons are eaten by gauge field and gapped.
local deg. freedom, entanglement and edge states
In-gap edge states
# local degree of freedom How to relax local entropy
Quantum effects with boundaries
Quantum entanglement EATS local degrees of freedom and makes the system gapped
Entangled & gapped
# deg.⇡
e
cN # deg.⇡e
Ve/V0Ve : volume (length) of edges
Superconductivity :Anderson mechanism
NG bosons are eaten by gauge field and gapped.
They revive again as edge states near the boundaries
Physics of bulk-edge correspondence, Hiroshima Univ. June 27-29, 2012