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Abstract

TADERA IKUGAWA DAWARA

Hot springs research in- stitute of Kanagawa Prefecture, Iryuda , Odawara, Kanagawa , Japan.

J. Hot Spring Sci.

Origin of deep hot spring waters in Kanagawa Prefecture is investigated based on compositions of major ions and oxygen-hydrogen isotope ratio. It is found that they are classified into three groups. Hot spring waters of group , which are seen in the coastal area, are considered to be originated from mixing of seawater and meteoric water. Their isotope ratios indicate that contribution of the latter is small. Hot spring waters of group , for their formation fossil seawater is probably involved, are divided into two subgroups based on the ratio of calcium ion in total cation. Hot spring waters of subgroup -A are characterized by the feature that calcium concentration is higher than that expected from the gypsum precipitation model. It is supposed that a cation exchange occurs be- tween the sodium ion in the rock and the calcium ion in the water. Those hot springs are seen in the central and southwestern parts of the Prefecture. On the other hand, hot spring waters of subgroup -B show lower calcium concentration than that expected, that is, a reverse cation exchange that causes dissolution of calcium-carbonate is considered to have taken place in the course of their formation. They are distributed in the northeast- ern part of the Prefecture. Hot spring waters of group which exist around Tanzawa Mountains are considered to consist of groundwater recharged by rainwater. It is sup- posed that major chemical ingredients are supplied not by the present or fossil seawater, but by the contents in the stratum where the hot waters yield. This assumption is sup- ported by the geology of the stratum and the groundwater flow inferred from the water levels, as well as by geographical distribution of the isotope ratios.

Key words : deep hot spring, fossil seawater, cation exchange reaction, groundwater flow

Kazuhiro I , Joji K and Kei O

Origin of Deep Hot Spring Waters in Kanagawa Prefecture, Japan

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culated and analyzed concentrations of mag- Relationship between di erences of cal-

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oceanic crust from the isotopic composition of pore water. J. Geophys. Res., (B ), Dansgaard, W. ( ) : Stable Isotopes in precipitation. Tellus, , .

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Lawrence, J.R. and Gieskes, J.M. ( ) : Constrains on water transport and alternation in the

Matsuo, S., Kusakabe, M., Niwano, M., Hirano, T., Oki, Y. ( ) : Origin of thermal waters from the Hakone geothermal system, Japan. Geochem. J., , .

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Mizota, C. and Kusakabe, M. ( ) : Spatial distribution of D- O values of surface and shal- low groundwaters from Japan, south Korea and east China. Geochem. J., , . Mizukami M., Sakai S., Matsubaya O. ( ) : Na-Ca-Cl-SO -type submarine formation waters

at the Seikan Undersea Tunnel, Japan. Chemical and isotopic documentation and its in- terpretation. Geochim. Cosmochim. Acta, , .

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Fig. Geology of the strata which yield hot spring waters (after Kikugawa )
Fig. Relationship between concentrations of
Fig. Oxygen-Hydrogen isotope compositions in hot spring waters. Color of circles show di erence of the groups, and their size represents concentration of chloride ion.
+6

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