--- MATERIAL SAFETY DATA SHEET --- Lebanon Turf LEBANON PRO 19-3-5 25% POLY-X PRO BARRICADE .38%
--- Lebanon Pro 19-3-5 25% Poly-X PRO Barricade .38% is also MANUFACTURER'S NAME AND ADDRESS:
known as Lebanon Fertilizer w/Barricade Preemergence Weed LEBANON CHEMICAL CORPORATION Control 0.38% P.O. BOX 180
--- LEBANON, PA 17042.
PRODUCT: 22-40935 LEB PRO 19 3 5 BARRICAD.38 BG4550LB TRANSPORTATION EMERGENCY:
MSDS NO.: 2590 CALL CHEMTREC: 800-424-9300.
0002590 Leb. Fertilizer w/Barricade Preemergence Weed DISTRICT OF COLUMBIA: 202-483-7616.
Control 0.38% LEB NON-TRANSPORTATION EMERGENCY PHONE: 800-233-0628.
05/17/1994 INFORMATION PHONE: 800-233-0628.
FORMULA: Not given --- MANUFACTURER: LEBANON CHEMICAL CORP. HEALTH/SAFETY ALERT
P.O. BOX 180 --- LEBANON, PA USA 17042-0180 CAUTION. Harmful if inhaled or absorbed through the skin.
PHONE: Avoid breathing dust. Prolonged or frequently repeated EMERGENCY: 717 273-1685 skin contact may cause allergic reactions to some PHYSICAL/CHEMICAL CHARACTERISTICS: individuals. Read the product label.
BOILING POINT: NA --- MELTING POINT: NA FIRST AID PROCEDURES
FREEZING POINT: NG --- POUR POINT: NG EYE: Flush thoroughly with water for 15 minutes. Contact a SOFTENING POINT: NG physician if irritation persists.
SPECIFIC GRAVITY: NA SKIN: Wash with soap and water. Rinse thoroughly.
VAPOR PRESSURE: LT 1 MM HG. INGESTION: Drink 1 or 2 glasses of water. Induce vomiting VAPOR DENSITY: NA by touching back of throat with finger or blunt object.
PERCENT VOLATILES: NG INHALATION: Remove the person to clear air.
EVAPORATION RATE: NA IN ALL EMERGENCY SITUATIONS, CONTACT A PHYSICIAN.
pH: NG --- MOLECULAR WEIGHT: NG NOTE TO PHYSICIAN
VISCOSITY: NG --- SOLUBILITY IN WATER: Partially soluble in water. Treat symptomatically.
ODOR/APPEARANCE/OTHER CHARACTERISTICS: Yellowish --- granules, bland odor. FIRE & EXPLOSION INFORMATION
FIRE AND EXPLOSION DATA: --- CLOSED CUP FLASH PT.: NG See above for additional information.
OPEN CUP FLASH POINT: NG NFPA RATING:
FIRE POINT: NG HEALTH: 1.
AUTO IGNITION: NG FIRE: 1.
LOWER EXPLOSION LIMIT: NA REACTIVITY: 0.
UPPER EXPLOSION LIMIT: NA SPECIAL PROPERTIES: None.
SHIPPING REGULATIONS: FLASH POINT: Does not flash.
UN/NA NUMBER: NG FLAMMABILITY: Not flammable.
DOT HAZARD CLASS: Not given EXTINGUISHING MEDIA: Water spray, foam, dry chemical.
SHIPPING LABEL: Not given SPECIAL PROTECTIVE EQUIPMENT: In severe fire, wear SHIPPING NAME: Not given protective clothing and use self contained breathing PREPARED: equipment.
PREPARER'S NAME & TITLE: Not given SPECIAL FIRE FIGHTING PROCEDURES: Prevent the release of PREPARATION DATE: 1/01/0 product and contaminated water.
COMPONENT(S): PRODUCTS OF COMBUSTION: Herbicide fumes, NOx, HF, CO.
Prodiamine UNUSUAL FIRE AND EXPLOSION HAZARDS: None.
OSHA PEL: NE ppm --- ACGIH TLV: NE ppm SPILL CONTROL AND CLEANUP
STEL: NG ppm --- PERCENT OF PRODUCT: EQ .38% STEPS TO BE TAKEN: Carefully sweep up spilled material and CAS NO.: Not given put into a container and close it. Avoid breathing the Fertilizer dust.
OSHA PEL: 15 mg/m3 ABSORBENTS: None.
ACGIH TLV: 10 mg/m3 COUNTERACTANTS: None.
STEL: NG ppm INCOMPATIBLES: Oxidizing agents.
PERCENT OF PRODUCT: EQ 99.62% --- CAS NO.: Not given PRODUCT WASTE DISPOSAL
NOTE: * Base, for all components NE=Not Established. --- --- If possible, use collected material according to label Text Section(s) directions. Otherwise, dispose of it at an approved --- chemical waste facility.
PRODUCT IDENTIFICATION --- --- RECOMMENDED GENERAL PRECAUTIONS
See above for additional information. --- PRODUCT NAME: Leb. Fertilizer w/Barricade Preemergency Weed STORAGE: Store in original container.
Control 0.38%. PERSONAL PROTECTIVE EQUIPMENT: When handling this material, EPA REG. NUMBER: 961-365. avoid contact with skin and breathing dust.
INGREDIENT NAME: Barricade.
SYNONYM: Prodiamine.
CHEMICAL FAMILY: Dinitroaniline herbicide.
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--- MATERIAL SAFETY DATA SHEET --- Lebanon Turf LEBANON PRO 19-3-5 25% POLY-X PRO BARRICADE .38%
--- --- --- HEALTH HAZARD INFORMATION DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: although --- preparer and owner have taken reasonable care in the SIGNS AND SYMPTOMS OF ACUTE OVEREXPOSURE: Eye irritation, preparation of this document, we extend no warranties and possible skin sensitization. make no representation as to the accuracy or completeness ACUTE TOXICITY: of the information contained herein, and assume no ORAL (LD50): Rats-greater than 5,000 mg/kg. responsibility regarding the suitability of this DERMAL (LD50): Rats-greater than 2,000 mg/kg. information for the user's intended purposes or for the INHALATION (LD50): Greater than 1.8 mg/L (highest consequences of its use. Each user should make a concentration that could be generated did not cause determination as to the suitability of the information for animal deaths). their particular purpose(s). A request has been made to the PRIMARY ROUTES OF ENTRY: manufacturer to approve the contents of this material ORAL: No. safety data sheet. Upon receipt of any changes a new MSDS DERMAL: No. will be made available.
INHALATION: Yes. --- CARCINOGEN AS DETERMINED BY: COMPAS Code: 43390470
NTP: Not listed.
IARC: Not listed.
OSHA: Not listed.
OTHER TOXICOLOGICAL INFORMATION:
SENSITIZER: Mildly sensitizing.
SKIN IRRITATION: Non-irritating (rabbits).
EYE IRRITATION: Mildly irritating (rabbits).
TARGET ORGAN(S): None identified.
--- SPECIAL PRECAUTIONS
--- Do not store near food or feed.
Do not contaminate water sources from disposal of wash water from equipment cleaning.
--- PRODUCT INFORMATION - ACTIVE INGREDIENTS
--- See above for additional information.
--- PHYSICAL INFORMATION
--- See above for additional information.
STABILITY: Stable.
REACTIVITY: Not reactive.
DECOMPOSITION PRODUCT: None known to form at ambient conditions.
--- REGULATORY REPORTING
--- SARA SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HEALTH: Yes (irritation).
DELAYED HEALTH: No.
FIRE: No.
SUDDEN PRESSURE: No.
REACTIVITY: No.
--- SPECIAL NOTES
--- The information presented herein, while not guaranteed, was prepared by technically knowledgeable personnel and to the best of our knowledge is true and accurate. It is not intended to be all inclusive and the manner and conditions of use and handling may involve other or additional considerations.
--- ADDITIONAL/IMPORTANT INFORMATION
--- Manufacturer approval of this MSDS is pending.
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