MATERIAL DATA SAFETY SHEET-Coastal AgroBusiness, Inc.___________________________________________________ 1
CHEM-OIL 83
Spray Tank Adjuvant For Pesticides
Coastal AgroBusiness, Inc.
PO Box 856 3702 Evans Street Greenville NC 27835 (252)756-1126
Emergency Phone Numbers:
Chemtrec(24 hrs): 1-800-424-9300 Coastal(Weekdays): 1-800-758-3456 IDENTITY Trade Name: Chem-Oil 83 EPA Reg. No.: Not Applicable Synonyms: Agricultural Oil, Crop Oil Chemical Name: Solvent Refined Paraffinic Distillates, Mixture of Surfactants
Common Name: Crop Oil, Agricultural Oil
Chemical Family: Petroleum Hydrocarbon, Emulsifier
Molecular Formula: Mixture Molecular Weight: Not Determined INGREDIENT
Component CAS NO. WT% PEL/TLV Solvent Refined 64741-88-4 0-24.9 5 mg/m3/5mg/m3 Heavy Paraffinic
Petroleum Oil
Solvent Refined 64741-89-5 58.1-83 5mg/m3/5mg/m3
Light Paraffinic Petroleum Oil
Emulsifier Mixture 17 NOL/NOL
Note: This product may contain trace amounts of residual ethylene oxide. See comments section for further details.
PHYSICAL AND CHEMICAL CHARACTERISTICS
Appearance and Odor: Clear, colorless to yellow liquid with slight fatty odor.
Boiling Point: Not Determined Melting Point: Not Applicable
Vapor Pressure: <0.0001mm Hg @ 20°C
Vapor Density (Air=1): 10
% Volatility (V/V): 0.7%
Octanol/H2O Partition Coef.: Not Determined
pH: Not Determined
Saturation in air (V/V): Not Determined Specific Gravity (H2O=1): 0.873 Solubility in Water: Emulsifies Viscosity: 68 SUS @ 100°F 11.6 cStokes @ 40°C
FIRE AND EXPLOSION DATA Flash Point: 316.2°F (157.9°C) Flammable Limits in Air (V/V):
Not Determined
Auto-Ignition Temperature: >650°F (343°C)
Fire Extinguishing Media: Water spray or fog, regular foam, dry chemical, CO2, sand/earth
Fire Control Tactics: Wear structural firefighters protective clothing and SCBA.
Unusual Fire and Explosion Hazards:
Can be made to burn (flash point > 200°F).
NFPA HAZARD RATING
Health Hazard: 0-No Significant Hazard Fire Hazard: 1-Slightly Combustible Reactivity: 0-Stable
Specific Hazard: None REACTIVITY DATA
Stability: Stable under normal conditions Conditions to Avoid: Excessive heat or fire
Incompatibility (Materials to Avoid):
Strong oxidizers such as hydrogen peroxide, bromine, chromic acid
Reactivity: Non-reactive
Hazardous Decomposition Products:
Combustion may produce CO, CO2, and other asphyxiants.
Hazardous Polymerization: Will not occur.
HEALTH HAZARD INFORMATION Threshold Limit Value: 5 mg/m3 Permissible Exposure Limit: 5 mg/m3 Warning Statements: CAUTION Chem-Oil 83 increases the activity of pesticides. In spraying of new varieties or highly inbred lines, a test area is recommended. Use care during periods when pesticides are more active such as very hot and humid conditions. Keep container tightly closed and DO NOT allow water to be introduced to contents of the container. Keep out of reach of children.
Signs and Symptoms of Exposure:
Excessive exposures may cause irritation to eyes, nose, throat and lungs.
Medical Conditions Generally Aggravated by Exposure: Skin disorders, respiratory, pulmonary and lung disorders.
Primary Route of Exposure: Inhalation, absorption.
Acute Toxicity Data:
1. Oral Toxicity: LD50 30+ g/kg Pulmonary aspiration hazard if swallowed and/or vomiting occurs-can enter lungs and cause damage.
2. Dermal Toxicity: Practically non- toxic if absorbed. (LD50>2000 mg/kg) Mild irritation with prolonged or repeated contact.
3. Inhalation Toxicity: Low acute toxicity. Overexposure to mist may cause eye, nose, throat, respiratory tract irritation.
4. Eye Irritation: Practically non- irritating on contact.
5. Skin Irritation/Sensitization:
Moderate/mild irritation with prolonged or repeated contact.
Chronic Toxicity Data: Not listed as a carcinogen.
Emergency and First Aid Procedures:
1. If swallowed: Do not induce vomiting. Do not give liquids. Obtain medical attention. Small amounts which accidentally enter mouth should be rinsed out until taste of it is gone.
2. If Inhaled: Move person to fresh air.
If breathing has stopped, artificial respiration should be started. Oxygen may be administered, if readily available. Seek medical attention if symptoms develop.
3. If in Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, holding eyelids apart to ensure flushing of the entire eye surface. Seek medical attention if irritation persists.
4. If on Skin: Remove contaminated clothing. Wash thoroughly with soap and water until no odor remains. If redness or swelling develops, obtain medical assistance. Wash clothing before use.
NOTE TO PHYSICIAN: This product presents a pulmonary aspiration hazard if swallowed and/or vomiting occurs-can enter lungs and cause damage.
SPECIAL PROTECTION INFORMATION
Respiratory Protection: Concentration in air determines protection needed.
Usually not needed unless product is heated or misted. Use half-mask air purifying respirator with dust/mist filters or HEPA filter cartridges to 50X the exposure limit. Protection by air purifying respirators are limited. Use positive pressure-demand full-face supplied air respirator or SCBA for exposures> 50X the exposure limit. If exposure is above IDLH, there is the possibility of an uncontrolled release or exposure levels are unknown then use a positive pressure- demand full-face supplied air respirator with escape bottle or SCBA. Use only NIOSH certified respiratory protection.
Eye Protection: Splash proof chemical goggles recommended.
Skin Protection: Protective gloves recommended when prolonged skin contact cannot be avoided. The following glove materials are acceptable: polyvinyl chloride (PVC), neoprene, nitrile, polyvinyl alcohol, viton.
Ventilation: Ventilate as needed to comply with exposure limit. Work upwind in outside batch operations.
Indoor work areas should be contained and provided with local or mechanical exhausts.
Other: If contact is unavoidable, wear chemical resistant clothing. The following materials are acceptable as protective clothing materials: polyvinyl alcohol (PVA), polyvinyl chloride (PVC), neoprene, nitril, viton, polyurethane;
launder soiled clothes.
MATERIAL DATA SAFETY SHEET-Coastal AgroBusiness, Inc.___________________________________________________ 2
SPECIAL PRECAUTIONS ANDSPILL/LEAK PROCEDURES
Handling and Storage: NFPA Class IIIB storage. Wash thoroughly after handling.
Never siphon by mouth. Do not contaminate water, food or feed by storage or disposal. Store in a cool, dry area.
Keep container tightly closed and DO NOT allow water to be introduced to contents of the container.
Steps To Be Taken In Case Material Is Released Or Spilled. Use personal protective equipment. Control and contain spill. Advise EPA; state agency if required. Absorb on inert material such as sand, soil or vermiculite: sweep up and dispose of in accordance with Federal, State and Local regulations.
Waste Disposal Methods: Follow Federal, State and Local regulations. Not a RCRA hazardous waste if uncontaminated. If material cannot be used as directed by label then RCRA criteria (ingnitability, reactivity, corrosivity, toxicity characteristics) must be determined and material must be disposed of accordingly. Do not flush to drain/storm sewer.
SHIPPING DATA (PACKAGE AND BULK)
D.O.T. Proper Shipping Name: Not Regulated
D.O.T. Hazard Classification:
Primary: Not Applicable Secondary: Not Applicable D.O.T. Labels Required: None D.O.T. Placards Required: None Poison Constituent: Not Applicable Hazardous Substance: Not Applicable Reportable Quantity (RQ):
Product: Not Applicable Ingredient: Not Applicable
Bill of Landing Description:
Agricultural sprayable product, Adjuvant, NOS (Emulsifiable Paraffinic Oil)
Transportation Emergency #:
CHEMTREC: (800)424-9300 ADDITIONAL REGULATORY INFORMATION
Sara Title III Data:
Section 311 and 312 Hazard Categories:
Immediate Health Hazard: Y Delayed Health Hazard: N Fire Hazard: N Reactive Hazard: N Sudden Pressure Release Hazard N Section 302:
EHS: None; TPQ: 10,000 lbs.
Section 313: Contains no chemical subject to SARA 313.
CERCLA Reportable Quantity: Not Applicable
National Response Center:
(800)424-8802
CHEMTREC: (800)424-9300
The information and statements herein are believed to be reliable and are given in good faith but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE.
MSDS NO.: 10410
DATE PREPARED: 02/15/86 DATE REVISED: 03/7/03 APPROVED: JMPearce
