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బ⸨ ᙪ
*1 ㈓ᵴ࡞㔞㈓ⶶࡉࢀࡓᏛ≀㉁ࡣ㸪⇕ࡋࡸࡍࡃ⮬↛Ⓨⅆࡸᭀ㉮ᛂࢆ⏕ࡌࡿྍ⬟ᛶࡀ࠶ࡾ㸪㈓ᵴࡢ ಖᏲ࣭ゎయసᴗ㸪ෆ㒊Ꮡᅾࡋࡓṧ´࡞ࡀ⮬↛Ⓨⅆࡸᭀ㉮ᛂࢆ㉳ࡇࡋࡓࡇࡼࡿ⪃࠼ࡽࢀࡿ⅏ᐖࡶ ᑡᩘ࡞ࡀࡽⓎ⏕ࡋ࡚࠸ࡿ㸬ࡑࡢࡼ࠺࡞ṧ´ࡣ」ᩘࡢᛂࡸከẁࡢᛂࡀ⏕ࡌࡿࡶࡢࡀከࡃ㸪ᚑ᮶ࡢ༴㝤ᛶホ౯ࡢ ヨ㦂ἲ࡛ࡣホ౯ࡀ㞴ࡋ࠸ࡶࡢࡀከ࠸㸬ࡑࡇ࡛㸪᪂ᆺࡢ㧗ᛶ⬟ᆺ⇕ศᯒ⨨࡛࠶ࡿ♧ᕪᆺ᩿⇕⇕㔞ィࢆᑟධࡋ㸪ࡑ ࡢᛶ⬟ࢆホ౯ࡍࡿࡶ㸪Ꮫ≀㉁ࡢ⮬↛Ⓨⅆᛶࡢホ౯ࡢ㐺⏝ᛶࢆ᳨ウࡋࡓ㸬 ࣮࣮࢟࣡ࢻ ᭀ㉮ᛂ㸪⮬↛Ⓨⅆ㸪㈓ᵴෆṧ´㸪♧ᕪᆺ᩿⇕⇕㔞ィ 1 ࡣࡌࡵ ㈓ᵴ࡞࠼ࡽࢀࡓ㔞ࡢᏛ≀㉁ࡣ㸪ࡑࡢ୰࡛Ⓨ ⇕ᛂࡀ⏕ࡌࡿ㸪⇕ࡋࡸࡍ࠸ࡇࡽ≀㉁ࡀ⮬↛Ⓨ ⅆࡋࡓࡾ㸪ᛂࡀ⇕ᭀ㉮ࡍࡿྍ⬟ᛶࡀ࠶ࡿ㸬㈓ᵴࡢಖᏲ ࡸゎయసᴗ࠸ࡗࡓ㠀ᐃᖖసᴗ࡛ࡣ㸪㔜ᶵ㸪㟁Ẽ ᕤල㸪࢞ࢫ⁐᩿タഛ࡞㸪⾪ᧁⅆⰼࡸ〄ⅆ࡞ࡢ╔ⅆ※ ࡀⓎ⏕ࡋࡸࡍ࠸⎔ቃ࠶ࡿࡇࡽ㸪ྍ⇞ᛶ࢞ࢫࡶࡋࡃ ࡣẼࡢ╔ⅆࡼࡿ⇿Ⓨⅆ⅏⅏ᐖࡀከ࠸㸬୍᪉㸪⅏ᐖᩘ ࡋ࡚ࡣᑡ࡞࠸ࡶࡢࡢ㸪㈓ᵴෆࡢṧ´ࡢ㝖ཤసᴗ୰㸪 ṧ´ࡢ⮬ᕫ㔜ྜᛂࡀⓎ⏕ࡋࡓࡇࡀཎᅉᛮࢃࢀࡿ⅏ ᐖ1)ࡸ㸪㈓ⶶࡉࢀ࡚࠸ࡓᗫἜ㢮ࡸࢫࣛࢵࢪ㢮ࡀ⮬↛Ⓨⅆ ࢆ㉳ࡇࡋࡓࡇࡀཎᅉᛮࢃࢀࡿ⅏ᐖ2)ࡀᏑᅾࡋ࡚࠸ࡿ㸬 ≀㉁ࡢ╔ⅆᛶࡘ࠸࡚ࡣࡑࡢホ౯᪉ἲࡣࡰ☜❧ࡋ࡚ ࠸ࡿ3)㸬ࡲࡓ㸪ᛂᛶ≀㉁ࡢᭀ㉮ᛂ㛵ࡍࡿ༴㝤ᛶࢆ ホ౯ࡍࡿ᪉ἲࡶ᪤Ꮡᅾࡋ㸪ᙜ◊✲ᡤ࡛ࡶ ᐃࢹ࣮ࢱࢆ බ㛤ࡋ࡚࠸ࡿ4,5)㸬ࡋࡋ㸪㈓ᵴෆṧᏑࡋ࡚࠸ࡿ≀㉁ࡢ ࡼ࠺㸪」ᩘࡢᛂࡸከẁࡢᛂࡀ⏕ࡌࡿࡶࡢ࡛ࡣ㸪ᚑ ᮶ࡢヨ㦂ἲ࡛ࡣ ᐃ⤖ᯝࡢ⿵ṇࡀᅔ㞴࡛࠶ࡿࡇࡽ㸪 ༴㝤ᛶࡢホ౯ࡀ㞴ࡋ࠸࠸࠺ၥ㢟ࡀ࠶ࡿ㸬ࡲࡓ㸪≀㉁ࡢ ⮬↛Ⓨⅆᛶࢆホ౯ࡍࡿ᪉ἲࡶ㸪ᙜ◊✲ᡤ࡛⮬↛Ⓨⅆヨ㦂 ⨨ࡀ㛤Ⓨࡉࢀ6)㸪ᩘࠎࡢ⮬↛Ⓨⅆ㛵ࡍࡿ◊✲ࡀ⾜ࢃ ࢀ࡚ࡁ࡚࠸ࡿ7-9)㸬ࡋࡋ㸪ᚑ᮶ࡢヨ㦂ἲ࡛ࡣ㸪1 ᅇࡢ ᐃ㛗㛫ࢆせࡍࡿࡶ㸪」ᩘࡢ ᗘ࡛ࡢ ᗘୖ᪼ ࡢ᭷↓ࢆ☜ㄆࡍࡿࡓࡵከᩘࡢ ᐃࢆせࡍࡿࡓࡵ㸪⢭ᗘ ࢆⴠࡉࡎ㸪ࡘ㎿㏿⮬↛Ⓨⅆᛶࢆホ౯࡛ࡁࡿ᪉ἲ ࡀᮃࡲࢀ࡚࠸ࡿ㸬 ࡇࢀࡽࡢၥ㢟ⅬࡢゎỴࡢ୍ࡘࡢ᪉ἲࡣ㸪ᚤᑠ࡞Ⓨ⇕ ࡽከẁ㝵ࡢᛂࡼࡿᭀ㉮ᛂࢆࡇࢀࡲ࡛ࡼࡾ⢭ᗘⰋࡃ ホ౯ࡍࡿᡭἲࢆ☜❧ࡍࡿࡇ࡛࠶ࡾ㸪ࡑࡢࡓࡵ᪂ᆺࡢ 㧗ᛶ⬟ᆺ⇕ศᯒ⨨ࢆᑟධࡋ㸪ࡑࡢ㐺⏝ᛶࡢ᳨ウࢆ⾜ࡗ ࡚ࡁࡓ㸬ࡇࡇ࡛ࡣ㸪ࡲࡎ᪂ᆺࡢ㧗ᛶ⬟ᆺ⇕ศᯒ⨨ࡢᛶ ⬟ࢆホ౯ࡍࡿࡓࡵ㸪⇕ຊᏛⓗࢹ࣮ࢱࡸᛂᶵᵓࡀ᪤▱ ࡢ≀㉁ࢆ⏝࠸࡚ᚑ᮶ࡢ⇕ศᯒ⨨ࡼࡿ ᐃࢹ࣮ࢱࡢ ẚ㍑᳨ウࢆ⾜ࡗࡓ⤖ᯝࡘ࠸࡚㏙ࡿ㸬ࡲࡓ㸪㈓ᵴࡢᐃ ᮇಟ⌮㸪ゎయࡢ༴㝤ᛶࡀᠱᛕࡉࢀࡿᛂࡋ࡚㸪ෆᐜ ≀ࡢ⮬ື㓟ࡼࡿ⮬↛Ⓨⅆࢆ㑅ᐃࡋ㸪᪂ᆺࡢ⇕ศᯒ ⨨ࡘ࠸࡚㸪⮬↛Ⓨⅆᛶࡢホ౯ࡢ㐺⏝ᛶࡢ᳨ウࢆ⾜ࡗ ࡓ⤖ᯝࡘ࠸࡚ㄝ᫂ࡍࡿ㸬 2 ⨨ࡢᴫせཎ⌮ ᐇ㦂ࡣ㸪♧ᕪᆺ᩿⇕⇕㔞ィ㸦DifferentialAccelerating Rate Calorimeter㸦௨ୗ DARC㸧㸪Omnical Inc.〇㸧ࢆ⏝ࡋࡓ㸬ᅗ 1 DARC ࡢᴫせࢆ♧ࡍ㸬ẚ㍑
ࡢࡓࡵ㸪ᚑ᮶ࡢ᩿⇕⇕㔞ィ࡛࠶ࡿAccelerating Rate
Calorimeter㸦ARC㸧ࡢᴫせࢆᅗ 2 ♧ࡍ㸬
୧⪅ࡶ㸪ヨᩱᐜჾࡢ࿘ࡾࡢ⎔ቃࢆຍ⇕ࡍࡿࡓࡵࡢࣄ
† ᮏ◊✲ࡢሗ࿌ෆᐜࡣ㸪ປാᏳ⾨⏕◊✲ 8 (2015) 3-12㸪ཬࡧThe 5th World Conference on the Safety of Oil and Gas Industries (WCOGI2014) Ⓨ⾲ࡋࡓࡶࡢࢆ୍㒊ಟṇࡋ࡚ྲྀࡾࡲࡵࡓࡶࡢ࡛࠶ ࡿ *1 ᏛᏳ◊✲ࢢ࣮ࣝࣉ. ᅗ2 ARC ࡢᴫせ ᅽຊィ ୖ㒊 䝠䞊䝍䞊 ഃ㒊 䝠䞊䝍䞊 ୗ㒊 䝠䞊䝍䞊 ヨᩱᐜჾ 䝷䝆䜰䞁䝖 䝠䞊䝍䞊 䝆䝱䜿䝑䝖 ⇕㟁ᑐ య䛾እほ ヨᩱᐜჾᅇ䜚䛾እほ ᴫ␎ᅗ ᅗ1 DARC ࡢᴫせ ᅽຊィ ⇕㟁ᑐ ⇕㟁ᑐ 䝆䝱䜿䝑䝖䝠䞊䝍䞊 䝆䝱䜿䝑䝖 䝠䞊䝍䞊 䝆 䝱 䜿 䝑 䝖 䝠 䞊 䝍 䞊 䝆 䝱 䜿 䝑 䝖 䝠 䞊 䝍 䞊 ⇕⿵ൾ䝠䞊䝍䞊 ཧ↷ഃ ヨᩱഃ య䛾እほ ヨᩱᐜჾᅇ䜚䛾እほ ᴫ␎ᅗ
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࣮ࢱ࣮ࢆഛ࠼࡚࠾ࡾ㸪ヨᩱᐜჾ࿘ࡾࡢ⎔ቃࢆྠࡌ ᗘ ࡍࡿࡇ࡛㸪ఝⓗ࡞᩿⇕≧ែࢆసࡾฟࡍᵓ㐀࡞ࡗ ࡚࠸ࡿ㸬ࡋࡋ㸪᩿⇕᮲௳࡛ࡣ㸪ヨᩱࡽᨺฟࡉࢀࡓ⇕ ࡀ㸪ヨᩱࡢ ᗘࢆୖࡆࡿࡔࡅ࡛࡞ࡃ㸪ヨᩱᐜჾࡢ ᗘࢆ ୖࡆࡿࡇࡶࢃࢀࡿ㸬ᐇつᶍࣉࣛࣥࢺ࡛ࡣ㸪㈓ᵴࡢ 㔜㔞ࡼࡾ㈓ᵴࡢ୰࠶ࡿ≀㉁ࡢ㔜㔞ࡀࡁ࠸ࡇࡀከ࠸㸬 ࡇࡢࡼ࠺࡞᮲௳࡛ࡣ㸪Ꮫ≀㉁ࡢ⇕ᐜ㔞ࡀ㈓ᵴࡢ⇕ᐜ㔞 ࡼࡾࡣࡿࡁ࠸ࡓࡵ㸪㈓ᵴዣࢃࢀࡿ⇕㔞ࡣ↓ど࡛ ࡁࡿࡀ㸪ARC ࡛ࡣ⪏ᅽᛶࡀ㧗࠸๛┤࡞ヨᩱᐜჾࢆ⏝ࡋ ࡚࠸ࡿࡓࡵ㸪ヨᩱᐜჾࡢ⇕ᐜ㔞ࡣ㸪ヨᩱࡢ⇕ᐜ㔞ྠ➼ ࡞ࡾ㸪ヨᩱᐜჾዣࢃࢀࡿ⇕㔞ࡀࡁࡃ↓ど࡛ࡁ࡞࠸㸬 ࡇࡢࡓࡵ㸪ᐇ㦂⤖ᯝࡽᐇ㝿ࡢ㈓ᵴ࡛ࡢⓎ⇕ᣲືࢆ᥎ ࡍࡿࡣ㸪ヨᩱᐜჾዣࢃࢀࡓ⇕ࡢศࢆ⿵ṇࡋ࡞ࡅࢀࡤ ࡞ࡽ࡞࠸10,11)㸬ࡇࡢ⿵ṇࡢ㝿ࡣ㸪╔┠ࡋ࡚࠸ࡿᛂࡢ ぢࡅࡢάᛶ࢚ࢿࣝࢠ࣮ࡣ ᐃ⠊ᅖෆ୍࡛ᐃ௬ᐃࡍ ࡿࡓࡵ12)㸪」ᩘࡢᛂࡸከẁࡢᛂࡀ⏕ࡌࡿࡶࡢᑐࡍ ࡿ⿵ṇ⤖ᯝࡢಙ㢗ᛶࡀၥ㢟࡞ࡿ㸬 ୍᪉㸪DARC ࡛ࡣ㸪ヨᩱᐜჾࡣูヨᩱᐜჾᾘ㈝ ࡉࢀࡿ⇕ࢆぢ✚ࡶࡿࡓࡵࡢཧ↷ᐜჾࢆ᭷ࡋ࡚࠸ࡿ㸬ࡑࢀ ࡽࡢᐜჾࢆタ⨨ࡋࡓࣄ࣮ࢱ࣮ࡼࡾྠࡌ ᗘࡍࡿࡇ ࡛㸪ᐜჾࡢ ᗘୖ᪼ࢃࢀࡓ⇕ࢆࣄ࣮ࢱ࣮ࡼࡗ࡚⿵ ൾࡍࡿࡇࡀ࡛ࡁࡿᵓ㐀࡞ࡗ࡚࠸ࡿ㸬ࡲࡎ㸪ヨᩱࡀⓎ ⇕ࡍࡿࡇࡼࡾ㸪ヨᩱᐜჾཧ↷ᐜჾ ᗘᕪࡀ⏕ࡌ㸪 ୧⪅ࡢ ᗘᕪࢆ࡞ࡃࡍࡓࡵ⿵ൾࣄ࣮ࢱ࣮ࡀຍ⇕ࢆጞࡵ ࡿ㸬ࡇࡇ࡛㸪⿵ൾࣄ࣮ࢱ࣮ࡣ㸪┤ิࡘ࡞ࡀࢀ࡚࠸ࡿࡓ ࡵ㸪ヨᩱᐜჾഃࡢࣄ࣮ࢱ࣮ཧ↷ᐜჾഃࡢࣄ࣮ࢱ࣮ࢆὶ ࢀࡿ㟁ὶࡣ➼ࡋ࠸㸬⿵ൾࣄ࣮ࢱ࣮ࡣᢠ್ࡀྠ୍࡞ࡿ ࡼ࠺タィࡉࢀ࡚࠸ࡿࡓࡵ㸪➼ࡋ࠸⇕㔞ࡀヨᩱᐜჾཬࡧ ཧ↷ᐜჾຍ࠼ࡽࢀࡿ㸬ࡇࡢࡁ㸪ヨᩱᐜჾࡣヨᩱࡀධ ࡗ࡚࠸ࡿࡓࡵ㸪ヨᩱࡢศࡔࡅ⇕ᐜ㔞ࡀཧ↷ᐜჾࡼࡾࡶ ࡁ࠸㸬ࡑࡢࡓࡵ㸪ཧ↷ᐜჾࡢ᪉ࡀ㏿ࡃ ᗘࡀୖ᪼ࡋ㸪࠸ ࡎࢀヨᩱᐜჾཧ↷ᐜჾࡢ ᗘࡣྠ୍࡞ࡿ㸬୧⪅ࡢ ᗘࡀྠ୍࡞ࡗࡓ⿵ൾࣄ࣮ࢱ࣮ࡀṆࡍࡿࡼ࠺࡞ ࡗ࡚࠸ࡿ㸬ࡇࡢ୧⪅ࡢ ᗘࡀྠ୍࡞ࡗࡓࡁ㸪ཧ↷ᐜ ჾࡢ ᗘୖ᪼ࢃࢀࡓ࢚ࢿࣝࢠ࣮ࡣ㸪ヨᩱࡢⓎ⇕ࡼ ࡗ࡚ヨᩱᐜჾࡢ ᗘୖ᪼ࢃࢀࡓ࢚ࢿࣝࢠ࣮➼ࡋ࠸㸬 ࡍ࡞ࢃࡕ㸪ヨᩱࡽⓎ⏕ࡋࡓ࢚ࢿࣝࢠ࣮ࡣࡍ࡚ヨᩱࡢ ᗘୖ᪼ࢃࢀࡿࡇ࡞ࡿ13,14)㸬 ᐇ㝿ࡣDARC ࡢヨᩱᐜჾཧ↷ᐜჾࡢ⇕ᐜ㔞ࢆ ྠ୍ࡍࡿࡇࡣᅔ㞴࡛࠶ࡿࡇ㸪୍᪉ᐇつᶍࣉࣛ ࣥࢺ࠾ࡅࡿ㈓ᵴ࡛ࡢᏛ≀㉁ࡢⓎ⇕࠾࠸࡚ࡶ㈓ᵴ ዣࢃࢀࡿ⇕ࡀᚤᑠ࡞ࡀࡽᏑᅾࡍࡿࡇࡽ㸪DARC ࡼ ࡗ࡚ ᐃࡉࢀࡓᏛ≀㉁ࡢⓎ⇕ᣲືᐇ㝿ࡢ㈓ᵴ࡛ࡢⓎ ⇕ᣲືࡣࡣ୍⮴ࡋ࡞࠸㸬ࡋࡋ㸪⌮ㄽୖࡣDARC ࡛ ᐃࡉࢀࡓᏛ≀㉁ࡢⓎ⇕ᣲືࡣ㸪ᐇ㝿ࡢ㈓ᵴ࡛ࡢ Ꮫ≀㉁ࡢⓎ⇕ᣲືྠࡌ࡛࠶ࡾ㸪ᚑ᮶ࡢ᩿⇕⇕㔞ィࡼࡾ ࡶ⢭ᗘࡼࡃᐇ㝿ࡢ㈓ᵴ࡛ࡢⓎ⇕ᣲືࢆண ࡍࡿࡇࡀྍ ⬟࡛࠶ࡿᛮࢃࢀࡿ㸬 3 ྠ୍ヨᩱࡘ࠸࡚ ARC ཬࡧ DARC ࡼࡾᚓࡽࢀࡓ Ⓨ⇕ᣲືࡢẚ㍑15) 1) ᐃࡢᴫせ (1) ヨᩱ ᐃᑐ㇟ࡣ㸪᩿⇕⇕㔞ィࡢᛶ⬟ホ౯㛗ᖺ⏝ࡉࢀ࡚ ࠸ࡿࢪ-tert-ࣈࢳࣝ࣌ࣝ࢜࢟ࢩࢻ㸦DTBP㸧-ࢺ࢚ࣝࣥᕼ 㔘⁐ᾮࡋࡓ㸬ᙜヱヨᩱࡣ㸪ྛ✀ࡢ᩿⇕⇕㔞ィࡼࡿࣛ ࢘ࣥࢻࣟࣅࣥヨ㦂ࡸศゎᶵᵓࡢ᳨ウ࡞ࡀ㐣ཤ⾜ࢃࢀ ࡚࠾ࡾ16)㸪㐣ཤࡢ▱ぢࡢẚ㍑ࡀᐜ࡛᫆࠶ࡿࡓࡵ㑅ᢥࡋ ࡓ㸬 DTBP ࡣᮾிᡂᕤᴗࡢ≉⣭ヨ⸆㸪ࢺ࢚ࣝࣥࡣග⣧ ⸆ᕤᴗࡢ≉⣭ヨ⸆ࢆ㸪⢭〇ࡍࡿࡇ࡞ࡃヨ⸆ࡢࡲࡲ⏝࠸ ࡓ㸬ࡑࢀࡽࡢヨ⸆࡛5, 10, 15, 20%ࡢ DTBP ࡀᏑᅾࡍࡿ ࡼ࠺ࢺ࢚࡛ࣝࣥᕼ㔘ࡋࡓࡶࡢࢆ ᐃヨᩱࡋࡓ㸬 (2) ᐃ᪉ἲᚑ᮶ࡢ᩿⇕⇕㔞ィࡋ࡚ࡣEuro ARC㸦ARC, Thermal
Hazard Technologies, UK㸧ࢆ⏝࠸ࡓ㸬ࡲࡓ♧ᕪᆺ᩿⇕ ⇕㔞ィࡣDifferential Accelerating Rate Calorimeter
㸦DARC, Omnical Inc., USA㸧ࢆ⏝࠸ࡓ㸬ARC ࡼࡿ
ᐃࡢࡣ6 g㸪DARC ࡼࡿ ᐃࡢࡣ 5 g ࡢヨ ᩱࢆࢽࢵࢣࣝ㸫ࢡ࣒ࣟ㸫ࣔࣜࣈࢹࣥྜ㔠㸦ࣁࢫࢸࣟC㸧 〇ࡢヨᩱᐜჾ࡚ࢇࡋ㸪 ᐃࢆ⾜ࡗࡓ㸬 ࡇࢀࡽࡢ᩿⇕⇕㔞ィ࡛ࡣ㸪ᭀ㉮ᛂࢆឤᗘⰋࡃ᳨▱ࡍ ࡿࡓࡵ≉Ṧ࡞ ᐃ᪉ἲࢆ᥇⏝ࡋ࡚࠾ࡾ㸪ຍ⇕㸫ᚅᶵ㸫 ᥈⣴࣮ࣔࢻ10,11)ࡪ㸬ᮏ ᐃ࣮ࣔࢻࡢ ᗘࡢไᚚ᪉ἲ ࡢᴫせࢆᅗ3 ♧ࡍ㸬ࡑࡢㄝ᫂ࢆ௨ୗ♧ࡍ㸬 ึࡵタᐃࡉࢀࡓึᮇ ᗘࡲ࡛ヨᩱࢆຍ⇕ࡋ㸪⇕ⓗ࡞ ᖹ⾮≧ែ࡞ࡿࡲ࡛ᚅᶵࡋࡓᚋ㸪ヨᩱࡽࡢⓎ⇕ࡢ᭷ ↓ࢆ ᐃࡍࡿ㸬ヨᩱࡽࡢⓎ⇕ࡀ᳨▱ࡉࢀ࡞ࡗࡓሙྜ ࡣ㸪๓タᐃࡋࡓ᪼ ᖜࡔࡅຍ⇕ࡋ㸪ᚅᶵ㸫᥈⣴ࡍࡿ ࡇࢆ⧞ࡾ㏉ࡍ㸬Ⓨ⇕ࡀ᳨▱ࡉࢀࡓሙྜࡣ㸪ヨᩱࡢⓎ⇕ ㏣ᚑࡍࡿࡼ࠺㸪Ⓨ⇕ࡀ⤊ࡍࡿࡲ࡛ຍ⇕ࡍࡿ㸬ࡇࡢ ࡼ࠺࡞ไᚚࢆ⾜࠺ࡇࡼࡾ㸪᩿⇕≧ែ࡛ࡢ㧗ឤᗘ࡛ࡢ
Ⓨ⇕㸦ARC ࡛ࡣ 0.02 Υ/min ௨ୖ㸪DARC ࡛ࡣ 0.01 Υ
/min㸧ࢆ᳨▱ࡍࡿࡇࡀྍ⬟࡞ࡗ࡚࠸ࡿ㸬
ᮏ❶ࡢ ᐃ࡛ࡣ㸪 ᐃࢆ㛤ጞࡍࡿ ᗘࢆ80 Υ㸪ᚅᶵ
㛫ࢆ15 min㸪᪼ ᖜࢆ 5 Υࡋࡓ㸬ARC DARC
ᅗ3 ᩿⇕⇕㔞ィࡢ ᐃ࣮ࣔࢻ ຍ⇕ ᚅᶵ䠉᥈⣴ ㏣ᚑไᚚ 㛫 ᗘ
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ࡢⓎ⇕᳨▱ឤᗘࡣࡑࢀࡒࢀୗ㝈ࡢ0.02㸪0.01 Υ/min ࡋࡓ㸬 2) ᐃ⤖ᯝ (1) DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡢⓎ⇕ᣲືࡢẚ㍑ ᅗ4 ARC ཬࡧ DARC ࡛ ᐃࡋࡓ 20%DTBP-ࢺࣝ ࢚ࣥᕼ㔘⁐ᾮࡢ ᐃ⤖ᯝࢆ♧ࡍ㸬ࡇࡢ ᐃ⤖ᯝࡣ㸪ຍ ⇕㸪ᚅᶵ㸪᥈⣴ࡢ ᗘࡶྵࡲࢀ࡚࠸ࡿ㸬DARC ࡛ ᐃ ࡉࢀࡓ᩿⇕ ᗘୖ᪼ࡣ㸪ARC ࡛ ᐃࡉࢀࡓࡶࡢࡼࡾࡶ ࡁࡗࡓ㸬ࡲࡓ㸪DARC ࡛ ᐃࡉࢀࡓⓎ⇕᳨▱ࡽ᭱ ࡢ⮬ᕫⓎ⇕㏿ᗘࡲ࡛ࡢ㛫ࡣ㸪ARC ࡛ ᐃࡉࢀࡓࡶࡢࡼ ࡾࡶ▷ࡗࡓ㸬๓㏙ࡋࡓࡼ࠺㸪ARC ࡼࡿ ᐃ࡛ࡣヨ ᩱࡽࡢⓎ⇕ࡢ୍㒊ࡀヨᩱᐜჾࡢ ᗘୖ᪼⏝ࡉࢀࡿ㸬 ୍᪉㸪DARC ࡼࡿ ᐃ࡛ࡣ㸪⿵ൾࣄ࣮ࢱ࣮ࡼࡾヨᩱ ᐜჾᩓ㐓ࡍࡿ⇕㔞ࢆຍ࠼ࡿࡓࡵ㸪ヨᩱࡽࡢⓎ⇕ࡣࡍ ࡚ヨᩱᐜჾࡢ ᗘୖ᪼ࢃࢀࡿ㸬ᅗ4 ♧ࡍ ᐃ⤖ ᯝࡣ㸪ࡑࡢ ᗘୖ᪼ࡢ㐪࠸ࡀ᫂ࡽ⾲ࢀ࡚࠸ࡿ㸬 ⾲1 5㹼20%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡘ࠸࡚ ARC ཬࡧDARC ࡛ᚓࡽࢀࡓⓎ⇕㛤ጞ ᗘ㸪᩿⇕ ᗘୖ᪼ཬࡧ ᭱ࡢ⮬ᕫⓎ⇕㏿ᗘࡢ ᐃ⤖ᯝࢆ♧ࡍ㸬࡞࠾㸪࢝ࢵࢥෆ ࡢᩘᏐࡣ㸪ヨᩱᐜჾࡼࡿᙳ㡪ࡢ⿵ṇ㸦I⿵ṇ㸧10,11)ࢆ⾜ ࡗࡓ⤖ᯝࢆ♧ࡍ㸬ࡍ࡚ࡢヨᩱࡘ࠸࡚㸪DARC ࡢ᪉ࡀ ARC ࡼࡾ᩿⇕ ᗘୖ᪼ཬࡧ᭱ࡢ⮬ᕫⓎ⇕㏿ᗘࡀࡁ ࡃ࡞ࡾ㸪DARC ࠾ࡅࡿ ᐃ࡛ࡣ㸪ヨᩱᐜჾᩓ㐓ࡍࡿ ⇕㔞ࡀ⿵ൾࡉࢀ࡚࠸ࡿࡇࢆ☜ㄆࡋࡓ㸬ࡲࡓ㸪ࡍ࡚ࡢ ヨᩱࡘ࠸࡚㸪DARC ࡢ᪉ࡀ ARC ࡼࡾⓎ⇕㛤ጞ ᗘࡀ పࡗࡓ㸬ࡇࢀࡣ㸪ARC ࡛ࡣࡑࡶࡑࡶ DARC ࡼࡾⓎ⇕ ᳨ฟឤᗘࡀప࠸ࡇ㸪ࡲࡓヨᩱࡽ᳨ฟឤᗘࡂࡾࡂࡾࡢ Ⓨ⇕ࡀ࠶ࡗ࡚ࡶ㸪ࡑࡢ୍㒊ࡀヨᩱᐜჾࡢ ᗘୖ᪼⏝ ࡉࢀ᳨࡚▱ࡉࢀࡎィ⟬ࡼࡿ⿵ṇࡶ࡛ࡁ࡞࠸ࡇࡢ2 Ⅼࡀ⌮⏤࡛࠶ࡿ㸬ࡇࡢཎᅉࡼࡿⓎ⇕㛤ጞ ᗘࡀ㧗ࡃ࡞ ࡿഴྥࡣ㸪DTBP ࡢ⃰ᗘࡀᑠࡉࡃ࡞ࡿ㸪ࡍ࡞ࢃࡕⓎ ⇕㔞ࡀᑠࡉࡃ࡞ࡿ㢧ⴭ࡞ࡗࡓ㸬 ௨ୖࡢࡇࡽ㸪DARC ࡣ㸪᩿⇕᮲௳࡛ࡢⓎ⇕ࡢ㏣ᚑ ᛶࡀඃࢀ࡚࠾ࡾ㸪≉Ⓨ⇕㔞ࡀᑠࡉ࠸ᛂࡢⓎ⇕ᣲືࢆ ⢭ᗘࡼࡃ ᐃ࡛ࡁࡿࡇࢆ☜ㄆ࡛ࡁࡓ㸬 (2) ᛂ㏿ᗘࣃ࣓࣮ࣛࢱࡢゎᯒཬࡧ ARC ࡢ ᐃࢹ࣮ ࢱࡢI⿵ṇ⤖ᯝ ᩿⇕᮲௳࡛ࡣ㸪⣔ෆࡢ ᗘᛂ≀⃰ᗘ㸪Ⓨ⇕㏿ᗘ ᛂ㏿ᗘࡀ➼౯࡛࠶ࡿࡓࡵ㸪nḟᛂࡢⓎ⇕㏿ᗘࡣᘧ(1) ࡛⾲ࡉࢀࡿ10,11)㸬 ݀ܶ ݀ݐ ൌ ܣ ȉ ݁ݔ ൬െ ܧ ܴܶ൰ ȉ ܥିଵȉ ൬ ܶെ ܶ ߂ܶ ൰ ȉ ߂ܶሺͳሻ ࡇࡇ࡛㸪T,t,A,E,R,C0,n,Tfཬࡧ'Tࡣ㸪ࡑࢀࡒࢀ ᗘ㸪㛫㸪๓ᣦᩘᅉᏊ㸪άᛶ࢚ࢿࣝࢠ࣮㸪Ẽయᐃᩘ㸪 ᛂ≀ࡢึᮇ ᗘ㸪ᛂḟᩘ㸪᭱⤊฿㐩 ᗘཬࡧ᩿⇕ ᗘୖ᪼ࢆ♧ࡍ㸬ᨃᛂ㏿ᗘᐃᩘk*ࢆᘧ(2)࡛ᐃ⩏ࡍࡿ㸪 ᘧ(1)ࡣᘧ(3)࡛⾲ࡉࢀࡿ10,11)㸬 ݇כൌ ݀ܶൗ݀ݐ ൬ܶ߂ܶ ൰െ ܶ ȉ ߂ܶ ሺʹሻ ݇כൌ ܣ ȉ ܥ ିଵെܴܶሺ͵ሻܧ ᘧ(3)ࡣ㸪 ᗘࡢ㏫ᩘᑐࡋ࡚k*ࡢᑐᩘࢆࣉࣟࢵࢺࡍ ࡿ㸪ࡑࡢࣉࣟࢵࢺࡢഴࡁษ∦ࡽάᛶ࢚ࢿࣝࢠ࣮ ๓ᣦᩘᅉᏊࢆồࡵࡿࡇࡀ࡛ࡁࡿࡇࢆពࡍࡿ㸬 DTBP ࡢ⇕ศゎࡣ㸪1 ḟᛂ࡛㐍⾜ࡍࡿࡇࡀ▱ࡽࢀ࡚ ࠸ࡿ16)ࡓࡵ㸪ᛂ≀ࡢึᮇ⃰ᗘࡣᾘཤࡉࢀ㸪ࣉࣟࢵࢺࡢ ഴࡁࡣE/R㸪ࣉࣟࢵࢺࡢษ∦ࡣlnAࢆ♧ࡍ㸬ࡑࡢࡇ ࡽ㸪ARC ཬࡧ DARC ࡢ ᐃࢹ࣮ࢱࡘ࠸࡚㸪 ᗘࡢ㏫ ᩘᑐࡋ࡚k*ࡢᑐᩘࢆࣉࣟࢵࢺࡋ㸪ࡑࡢഴࡁࡽάᛶ ࢚ࢿࣝࢠ࣮㸪ษ∦ࡽ๓ᣦᩘᅉᏊࢆồࡵࡓ㸬 5㹼20%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡢ ARC ཬࡧ DARC ࡢ ᐃࢹ࣮ࢱࡽồࡵࡓάᛶ࢚ࢿࣝࢠ࣮ཬࡧ๓ᣦᩘᅉ Ꮚࢆ⾲2 ♧ࡍ㸬10%㹼20%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡢ ⤖ᯝࡣ㸪ARC ཬࡧ DARC ࡢࡕࡽࡶ࠾࠾ࡼࡑྠ➼ࡢ⤖ ⾲1 DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡘ࠸࡚ ARC ཬࡧ DARC ࡛ᚓࡽࢀࡓ Ⓨ⇕㛤ጞ ᗘ㸪᩿⇕ ᗘୖ᪼ཬࡧ⮬ᕫⓎ⇕㏿ᗘࡢ್᭱ DTBP ⃰ᗘ [%] Ⓨ⇕㛤ጞ ᗘ [Υ] ᩿⇕ ᗘୖ᪼ [Υ] (dT/dt)max*1 [Υ/min]ARC DARC ARC DARC ARC DARC
5 130 110 11 (19) 39 0.03 0.06 10 124 115 38 (62) 58 0.16 0.63 15 118 115 58 (96) 83 0.84 7.45 20 118 115 72 (120) 130 3.50 66.4 *1 ⮬ᕫⓎ⇕㏿ᗘࡢ್᭱ *2 ⿵ṇ್ࢆ♧ࡍ ᅗ4 20%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡢ ᐃ⤖ᯝ 0 500 1000 1500 0 50 100 150 200 250 300 ARC T e m p e ra tu re [ Υ /m in ] Time [min] DARC (1) (2) (3)
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ᯝࡀᚓࡽࢀࡓ㸬ࡲࡓ㸪15%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡘ ࠸࡚㸪ྛ✀ࡢ᩿⇕⇕㔞ィ࡛⾜ࢃࢀࡓࣛ࢘ࣥࢻࣟࣅࣥヨ㦂 ࡛ホ౯ࡉࢀࡓάᛶ࢚ࢿࣝࢠ࣮࡛࠶ࡿ154.5㹼161.8 kJ/ mol ཬࡧ๓ᣦᩘᅉᏊ࡛࠶ࡿ 2.01017㹼2.01018 /min17) ㏆࠸್࡞ࡗࡓ㸬 ୍᪉㸪5%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡘ࠸࡚ࡣ㸪DARC ࡛ᚓࡽࢀࡓ⤖ᯝࡣ㸪ࡢ⃰ᗘ࡛ᚓࡽࢀࡓ⤖ᯝ㏆ࡗࡓ ࡀ㸪ARC ࡛ᚓࡽࢀࡓ⤖ᯝࡣ㸪ࡢ⃰ᗘ࡛ᚓࡽࢀࡓ⤖ᯝ ࡽࡁࡃࡎࢀࡓ㸬ࡇࢀࡣ㸪 ᐃࡉࢀࡓⓎ⇕㏿ᗘࡀARC ࡢ ᐃ㝈⏺㏆࡞ࡾ㸪ᛂ㏿ᗘࣃ࣓࣮ࣛࢱࢆゎᯒࡍࡿ ࡢ༑ศ࡞ࢹ࣮ࢱࡀᚓࡽࢀ࡞ࡗࡓࡇࡼࡿࡶࡢ࡛࠶ ࡿ㸬 ୖグ࡛ᚓࡽࢀࡓάᛶ࢚ࢿࣝࢠ࣮ࢆ⏝ࡋ࡚㸪ARC ࡛ ᚓࡽࢀࡓ ᐃࢹ࣮ࢱࡢI⿵ṇࢆ⾜ࡗࡓ㸬I⿵ṇࡣ㸪Huff ࡼࡗ࡚ᥦၐࡉࢀࡓ᪉ἲ12,18,19)ࡼࡗ࡚⾜ࡗࡓ㸬 ᐃࡀ ⾜ࢃࢀࡿ⣔ࡢ᩿⇕ᗘa ࢆᘧ(4)ᐃ⩏ࡍࡿ㸪᩿⇕ ᗘୖ ᪼ࡢ ᐃ್⿵ṇ್㸦ヨᩱࡑࡢࡶࡢࡢ್㸧ࡣᘧ(5)࡛⾲ࡉ ࢀࡿ㸬 ܽ ൌ ͳ ͳ ݉௩ȉ ܥ௩ ݉௦ȉ ܥ௦ȉ ቀ݀ܶ݀ݐቁ ௩ ቀ݀ܶ݀ݐቁ ௦ ሺͶሻ οథൌȟܶܽ ሺͷሻ௦ ࡇࡇ࡛㸪m,Cpࡣࡑࢀࡒࢀ㔜㔞㸪ẚ⇕ࢆ♧ࡋ㸪ୗῧᏐ v,s,I,obsࡣࡑࢀࡒࢀヨᩱᐜჾ㸪ヨᩱ㸪⿵ṇ್ཬࡧᐇ ್ࢆ♧ࡍ㸬⮬ᕫⓎ⇕㏿ᗘࡢ⿵ṇ್ࡣᘧ(6)࡛⾲ࡉࢀࡿ㸬 ൬݀ܶ݀ݐ൰ థൌ ቀ݀ܶ݀ݐቁ ௦ ܽ ȉ ݁ݔ ൭െ ܧ ܴ ቆ ͳ ܶథെ ͳ ܶ௦ቇ൱ሺሻ ୖグࡼࡾI⿵ṇࡋࡓARC ࡢ⿵ṇ⤖ᯝ DARC ࡢ ᐃࢹ࣮ࢱࢆẚ㍑ࡋࡓ⤖ᯝࢆᅗ5 ♧ࡍ㸬20%DTBP-ࢺࣝ ࢚ࣥᕼ㔘⁐ᾮࡢDARC ᐃ⤖ᯝ࡛㸪⮬ᕫⓎ⇕㏿ᗘࡀ⣙ 60 Υ/min ୍࡛ᐃ࡞ࡗ࡚࠸ࡿ㒊ศࡀ࠶ࡿࡀ㸪ࡇࢀࡣ DARC ࡢࣄ࣮ࢱ࣮ࡢຍ⇕⬟ຊࡢୖ㝈㏆࡛࠶ࡿࡇ ⏤᮶ࡍࡿࡶࡢ࡛࠶ࡿ㸬ࡼࡗ࡚㸪ᐇ㝿ࡢヨᩱࡢ⮬ᕫⓎ⇕㏿ ᗘࡣࡑࢀ௨ୖ࡞ࡗ࡚࠸ࡿྍ⬟ᛶࡀ㧗࠸㸬ࡑࡢ㒊ศࢆ㝖 ࡁ㸪20% DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡢ ARC ࡢ⿵ṇ⤖ᯝ DARC ࡢ ᐃࢹ࣮ࢱࡣࡼࡃ୍⮴ࡋࡓ㸬10%ཬࡧ 15% DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮ࡛ࡣ㸪ARC ࡢ⿵ṇ⤖ᯝࡢ᪉ࡀ DARC ࡢ ᐃࢹ࣮ࢱࡼࡾ᭱⤊฿㐩 ᗘࡀ㧗ࡃ࡞ࡿഴྥ ࢆ♧ࡋࡓ㸬ࡇࢀࡣ㸪DARC ࡢヨᩱᐜჾཧ↷ᐜჾࡢ㔜㔞 ᅗ5 5㹼20%DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡢ ARC ࡢ⿵ṇ⤖ᯝ DARC ࡢ ᐃ⤖ᯝࡢẚ㍑ 110 120 130 140 150 10-2 10-1 120 140 160 180 10-2 10-1 100 100 120 140 160 180 200 220 10-2 10-1 100 101 100 150 200 250 10-2 10-1 100 101 102 5% DTBP-ࢺ࢚ࣝࣥ DARC ARC㸦ȭ⿵ṇ๓㸧 ARC㸦ȭ⿵ṇᚋ㸧 㻌 Se lf he at ra te [ Υ /m in ] Temperature [Υ] Se lf he at ra te [ Υ /m in ] Temperature [Υ] 10% DTBP-ࢺ࢚ࣝࣥ DARC ARC㸦ȭ⿵ṇ๓㸧 ARC㸦ȭ⿵ṇᚋ㸧 15% DTBP-ࢺ࢚ࣝࣥ DARC ARC㸦ȭ⿵ṇ๓㸧 ARC㸦ȭ⿵ṇᚋ㸧 㻌 㻌 Se lf he at ra te [ Υ /m in ] Temperature [Υ] 20% DTBP-ࢺ࢚ࣝࣥ DARC ARC㸦ȭ⿵ṇ๓㸧 ARC㸦ȭ⿵ṇᚋ㸧 㻌 Se lf he at ra te [ Υ /m in ] Temperature [Υ] ⾲2 DTBP-ࢺ࢚ࣝࣥᕼ㔘⁐ᾮࡘ࠸࡚ ARC ཬࡧ DARC ࡛ ᚓࡽࢀࡓάᛶ࢚ࢿࣝࢠ࣮ཬࡧ๓ᣦᩘᅉᏊ DTBP ⃰ ᗘ [%] άᛶ࢚ࢿࣝࢠ࣮ [kJ/mol] ๓ᣦᩘᅉᏊ [/min] ARC DARC ARC DARC 5 247 148 1.961029 3.281016 10 159 152 7.201017 1.091017 15 158 156 5.481017 9.171017 20 161 155 1.531018 1.831017 (6) (5) (4)--
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ࡀࡣ୍⮴ࡋ࡚࠸࡞࠸ࡓࡵ㸪ࢃࡎヨᩱᐜჾࡢ⇕ ᐜ㔞ࡢᙳ㡪ࡀ⌧ࢀࡓࡶࡢ⪃࠼ࡽࢀࡿ㸬5%DTBP-ࢺࣝ ࢚ࣥᕼ㔘⁐ᾮ࡛ࡣ㸪ARC ࡛ࡣ ᐃ㝈⏺㏆ࡢⓎ⇕ࡋ ᐃ࡛ࡁࡎ㸪⿵ṇ⤖ᯝࡣDARC ࡢ ᐃࢹ࣮ࢱࡽࡁࡃࡎ ࢀࡓ㸬ࡇࡢࡼ࠺࡞ᚤᙅ࡞Ⓨ⇕ࡘ࠸࡚ࡣ㸪ARC ࡢ ᐃࢹ ࣮ࢱࡽ⿵ṇࢆ⾜ࡗ࡚ᐇつᶍ࡛ࡢⓎ⇕ᣲືࢆ⌧ࡍࡿࡇ ࡣᅔ㞴࡛࠶ࡾ㸪DARC ࡼࡿ ᐃࡀ᭷⏝࡛࠶ࡿ⪃࠼ ࡽࢀࡿ㸬 ௨ୖࡢࡇࡽ㸪ARC ࡛ࡢ ᐃࡀᅔ㞴࡛࠶ࡿᚤᙅ࡞Ⓨ ⇕ࢆ♧ࡍᛂࡘ࠸࡚㸪DARC ࡛ࡣᐇつᶍ࡛ࡢⓎ⇕ᣲື ࢆ᥎ ࡍࡿࡓࡵᚲせ࡞ᛂ㏿ᗘࣃ࣓࣮ࣛࢱࢆARC ࡼ ࡾࡶ⢭ᗘࡼࡃண ࡛ࡁࡿࡇࢆ☜ㄆ࡛ࡁࡓ㸬 4 ⮬↛Ⓨⅆᛶ≀㉁ࡢ ᐃ20) 1) ᐃࡢᴫせ (1) ヨᩱ ᐃᑐ㇟ࡣ㸪࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ࢜ࣞࣥ㓟 ࡋࡓ㸬ᙜヱヨᩱࡣ㸪㐣ཤ⾜ࢃࢀࡓຍᅽᆺ♧ᕪ㉮ᰝ⇕ 㔞ィ㸦DSC㸧ࡸ ARC ࡼࡿ⮬↛Ⓨⅆᛶࡢ㎿㏿ホ౯ἲࡢ ᳨ウ21,22)࡛ ᐃᑐ㇟࡞ࡗ࡚࠸ࡓ≀㉁࡛࠶ࡾ㸪㐣ཤࡢ▱ ぢࡢẚ㍑ࡀ࡛ࡁࡿࡓࡵ㑅ᢥࡋࡓ㸬 ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝࡣᖹᆒศᏊ㔞200 ࡢග⣧⸆ ᕤᴗࡢග୍⣭ヨ⸆㸪࢜ࣞࣥ㓟ࡣග⣧⸆ᕤᴗࡢග ୍⣭ヨ⸆ࢆ㸪⢭〇ࡍࡿࡇ࡞ࡃヨ⸆ࡢࡲࡲ⏝࠸ࡓ㸬 (2) ᐃ᪉ἲ ᐃ⨨ࡣ㸪DARC ࢆ⏝ࡋࡓ㸬ࡲࡓ㸪ホ౯⤖ᯝࡢ ẚ㍑ࡢࡓࡵ㸪ARC ཬࡧ⇕ὶ᮰ᆺ㧗ឤᗘ⇕㔞ィ࡛ࡶྠヨ ᩱࡢ ᐃࢆ⾜ࡗࡓ㸬 DARC ࡛ࡢ ᐃ࡛ࡣ㸪ヨᩱࢆࣁࢫࢸࣟ C 〇ࡢヨᩱᐜ ჾ࡚ࢇࡋ㸪ᐜჾෆࢆ㓟⣲࡛0.6 MPa ຍᅽࡋࡓ㸬ヨ ᩱ㔞ࡣ㸪0.7 g ࡲࡓࡣ 6.0 g ࡋࡓ㸬ࡑࡢヨᩱࢆຍ⇕㸫ᚅ ᶵ㸫᥈⣴࣮ࣔࢻ࡛ ᐃࢆ⾜ࡗࡓ㸬 ᐃࢆ㛤ጞࡍࡿ ᗘࡣ 25 Υ㸪ᚅᶵ㛫ࢆ 15 min㸪᪼ ᖜࢆ 5 Υࡋࡓ㸬⨨ ࢆಖㆤࡍࡿࡓࡵ㸪 ᐃ ᗘࡢୖ㝈ࢆ350 Υࡋ࡚ ᐃ ࢆ⾜ࡗࡓ㸬 ARC ࡛ࡢ ᐃ࡛ࡣ㸪1 g ࡢヨᩱࢆࣁࢫࢸࣟ C 〇ࡢヨ ᩱᐜჾ࡚ࢇࡋ㸪ᐜჾෆࢆ㓟⣲࡛0.6 MPa ຍᅽࡋࡓ㸬 ࡑࡢヨᩱࢆຍ⇕㸫ᚅᶵ㸫᥈⣴࣮ࣔࢻ࡛ ᐃࡋࡓ㸬 ᐃࢆ 㛤ጞࡍࡿ ᗘࡣ25 Υ㸪ᚅᶵ㛫ࢆ 15 min㸪᪼ ᖜࢆ 5 Υࡋࡓ㸬ARC ࡢ ᐃࢹ࣮ࢱࡘ࠸࡚ࡣ㸪Huff ࡀᥦ ၐࡋࡓ᪉ἲࡼࡾI⿵ṇࢆ⾜࠸㸪ࡑࡢ⿵ṇ⤖ᯝࢆDARC ࡢ ᐃࢹ࣮ࢱẚ㍑ࡋࡓ㸬 ⇕ὶ᮰ᆺ㧗ឤᗘ⇕㔞ィࡣC80㸦Setaram Instrumentation㸪France㸧ࢆ⏝ࡋࡓ㸬ᮏ⨨ࡢᴫせ ࢆᅗ6 ♧ࡍ㸬ᮏ⨨ࡣ㸪ヨᩱᐜჾ࡚ࢇࡋࡓᅛయࡲ ࡓࡣᾮయヨᩱࢆ㸪⇕ⓗᏳᐃࡋࡓᶆ‽≀㉁ྠຍ⇕ ࡋ㸪┦ᑐⓗ࡞⇕ὶ᮰ࡢኚࢆ ᐃࡍࡿࡶࡢ࡛࠶ࡾ㸪ࡑࡢ Ⅼ࠾࠸࡚ࡣ୍⯡ⓗ⇕ศᯒ࡛⏝ࡉࢀࡿ♧ᕪ㉮ᰝ⇕㔞 ィྠᵝࡢཎ⌮ࡢ⇕㔞ィ࡛࠶ࡿ㸬୍᪉㸪♧ᕪ㉮ᰝ⇕㔞ィ ౪ࡉࢀࡿヨᩱ㔞ࡣmg ࢫࢣ࣮࡛ࣝ࠶ࡿࡢᑐࡋ㸪C80 ౪ࡉࢀࡿヨᩱ㔞ࡣg ࢫࢣ࣮࡛ࣝ࠶ࡿ㸬ࡉࡽ㸪C80 ࡛ ࡣヨᩱᐜჾࡢ࿘ᅖయ㔞ࡢ⇕㟁ᑐࡀタ⨨ࡉࢀ࡚࠸ࡿ ᵓ㐀࡞ࡗ࡚࠾ࡾ㸪᳨ฟឤᗘࢆ㧗ࡵ࡚࠸ࡿ㸬ࡑࡢ᪉ࡢ ຠᯝࡼࡾ㸪C80 ࡢ᳨ฟឤᗘࡣ 0.1 PW/g ࡢ࣮࢜ࢲ࣮࡛ ࠶ࡾ㸪DSC ࡢ᳨ฟឤᗘ࡛࠶ࡿ 1 mW/g ࡢ࣮࢜ࢲ࣮ࡼࡾᴟ ࡵ࡚㧗ឤᗘ࡞ࡗ࡚࠸ࡿ㸬 C80 ࡛ࡢ ᐃ࡛ࡣ㸪1 g ࡢヨᩱࢆࢫࢸࣥࣞࢫ㗰〇ࡢヨ ᩱᐜჾ࡚ࢇࡋ㸪ᐜჾෆࢆ㓟⣲࡛0.6 MPa ຍᅽࡋࡓ㸬 ࡑࡢヨᩱࢆ㸪ᐊ ࡽ200 Υࡲ࡛᪼ ㏿ᗘ 0.1 Υ/min ࡛᪼ ࡋ㸪⇕ὶ᮰ࢆ ᐃࡋࡓ㸬 2) ᐃ⤖ᯝ (1) DARC ࡼࡿ ᐃ⤖ᯝ DARC ࡼࡿ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ࢜ࣞࣥ 㓟㸦ヨᩱ㔞0.7 g㸧ࡢ ᐃ⤖ᯝࢆᅗ 7 ♧ࡍ㸬DARC ࡛ ᐃࢆ⾜ࡗࡓ⤖ᯝ㸪࠸ࡎࢀࡢ≀㉁࠾࠸࡚ࡶ㓟ᛂ ࡼࡿ⪃࠼ࡽࢀࡿⓎ⇕ࢆ᳨▱ࡍࡿࡇࡀ࡛ࡁࡓ㸬ࡲࡓ㸪 ᐃ㛫ࡣ࠸ࡎࢀࡶ⣙1 ᪥࡛࠶ࡗࡓ㸬᪤Ꮡࡢ⮬↛Ⓨⅆホ ౯ヨ㦂ἲ࡛ࡣ㸪᭱ప7 ᪥㛫ࡢ㛫ࡀᚲせ࡛࠶ࡾ㸪ࡑࢀ ẚࡿ▷㛫࡛⮬↛Ⓨⅆ༴㝤ᛶࢆホ౯࡛ࡁࡿྍ⬟ᛶࡀ ᅗ6 C80 ࡢᴫせ య䛾እほ ᴫ␎ᅗ ᅗ7 DARC ࡼࡿ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ ࢜ࣞࣥ㓟㸦ヨᩱ㔞0.7 g㸧ࡢ ᐃ⤖ᯝ 0 200 400 600 800 0 100 200 300 400 Time [min] Te m pe ra tu re [ Υ ] 0 1 2 3 4 P re ss ure [M P a] Polyethylene glycol 0 200 400 600 800 0 100 200 300 400 Time [min] Te m pe ra tu re [ Υ ] Oleic acid 0 1 2 3 4 Pre ss ure [M Pa ]--
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࠶ࡿࡇࡀ♧ࡉࢀࡓ㸬 DARC ࡼࡗ࡚ ᐃࡉࢀࡓⓎ⇕㏿ᗘࢆᅗ 8 ♧ࡍ㸬ẚ ㍑ࡢࡓࡵ㸪ヨᩱ㔞0.7 g ࡢ⤖ᯝ 6.0 g ࡢ⤖ᯝࢆేࡏ࡚ ♧ࡋࡓ㸬ࡑࡢ⤖ᯝ㸪᩿⇕⇕㔞ィࡼࡿ ᐃࡢ㝿ぢࡽࢀ ࡿ୍⯡ⓗ࡞ഴྥ␗࡞ࡾ㸪ヨᩱ㔞ࡀከ࠸ ᐃࡉࢀࡿ Ⓨ⇕㏿ᗘࡀᑠࡉࡃ࡞ࡿ⌧㇟ࡀぢࡽࢀࡓ㸬ࡇࢀࡣ㸪ヨᩱᐜ ჾෆ࡚ࢇࡋࡓヨᩱ㓟⣲ࡢ⏺㠃࡛⏕ࡌࡓᛂࡼࡿ Ⓨ⇕ࢆ ᐃࡋࡓࡇࡼࡿ⪃࠼ࡽࢀࡿ㸬ࡍ࡞ࢃࡕ㸪ヨ ᩱ㔞ࢆቑࡉࡏࡓࡋ࡚ࡶ㸪ヨᩱ㓟⣲ࡢ⏺㠃ࡢ㠃✚ ࡣࢇኚࢃࡽ࡞࠸ࡇࡽ㸪Ⓨ⏕ࡍࡿ⇕㔞ࡣࢇ ኚࡋ࡞࠸㸬ࡼࡗ࡚㸪ヨᩱ㔞ࡀቑຍࡍࡿ㸪ぢࡅୖ ヨᩱ㔜㔞ᙜࡓࡾࡢⓎ⇕㔞ࡣῶᑡࡍࡿ㸬᩿⇕⣔࡛ࡣ᩿⇕ ᗘୖ᪼ヨᩱ㔜㔞ᙜࡓࡾࡢⓎ⇕㔞ࡣ➼౯࡛࠶ࡿࡇࡽ㸪 ヨᩱ㔞ࡀቑຍࡍࡿࡇ࡛㸪 ᐃࡉࢀࡿ᩿⇕ ᗘୖ᪼ࡣῶ ᑡࡍࡿ㸬 (2) DARC ࡼࡿ ᐃ⤖ᯝ㸪ࡢ⇕㔞ィ㸦ARC㸪 C80㸧ࡼࡿ ᐃ⤖ᯝࡢẚ㍑ ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ࢜ࣞࣥ㓟ࡢARC ཬࡧ DARC ࡼࡿ ᐃ⤖ᯝࢆᅗ 9 ♧ࡍ㸬ᅗ 9 ࡣ㸪DARC ࡢ ᐃ⤖ᯝࡣ㸪ヨᩱ㔞0.7 g ࡢࡢ⤖ᯝࢆ♧ࡋࡓ㸬ࡲࡓ㸪 ARC ࡢ ᐃࢹ࣮ࢱࢆI⿵ṇࡋࡓ⿵ṇ⤖ᯝࢆྜࢃࡏ࡚♧ࡋ ࡓ㸬ࡑࡢ⤖ᯝ㸪ARC ࡢI⿵ṇᚋࡢ⿵ṇ⤖ᯝࡣ㸪ヨᩱ㔞0.7 g ࡛ࡢ DARC ࡢ ᐃ⤖ᯝࡰ୍⮴ࡋࡓ㸬ࡼࡗ࡚㸪ᙜヱ ᐃ᮲௳࠾ࡅࡿDARC ࡼࡿ ᐃࡣ㸪ヨᩱᐜჾࡢᙳ㡪 ࡀࢇ࡞࠸᮲௳࡛ࡢⓎ⇕ᣲືࡀ ᐃ࡛ࡁ࡚࠸ࡿ⪃ ࠼ࡽࢀࡿ㸬 ➲⏣ࡽࡣ㸪᪤Ꮡࡢ⮬↛Ⓨⅆホ౯ヨ㦂ἲࡢ௦᭰ἲࡋ࡚ ຍᅽDSC ཬࡧ ARC ࡢ㐺⏝ྍ⬟ᛶࢆ᳨ウࡋ࡚࠾ࡾ㸪᪤Ꮡ ࡢ⮬↛Ⓨⅆホ౯ヨ㦂ἲࡼࡿ᭱ప⮬↛Ⓨⅆ ᗘࡣ㸪㓟⣲ ࡛ຍᅽࡋࡓᐜჾෆࡢヨᩱࡢARC ࡼࡿእᤄⓎ⇕㛤ጞ ᗘ㸦I⿵ṇᚋ0.02 Υ/min ࡢⓎ⇕㏿ᗘ࡞ࡿ ᗘ㸧 ࡢ┦㛵ࡀ࠶ࡿࡋ࡚࠸ࡿ21)㸬ࡉࡽᒾ⏣ࡣ㸪ᾮయᏛ≀ ㉁ࡢ⮬↛Ⓨⅆ༴㝤ᛶホ౯㛵ࡍࡿ᳨ウࢆ⾜ࡗ࡚࠾ࡾ㸪᪤ Ꮡࡢ⮬↛Ⓨⅆホ౯ヨ㦂ἲࡼࡿ᭱ప⮬↛Ⓨⅆ ᗘࡣ㸪 C80 ࡼࡗ࡚ ᐃࡉࢀࡓⓎ⇕㛤ጞ ᗘ㸦࣮࣋ࢫࣛࣥ ࡽ⇕ὶ᮰ࡀ❧ࡕୖࡀࡿ ᗘ㸧ࡰ୍⮴ࡍࡿࡋ࡚࠸ࡿ 23)㸬ࡼࡗ࡚㸪ARC ࡢ⿵ṇ⤖ᯝཬࡧ DARC ࡢ ᐃ⤖ᯝ ࡽእᤄⓎ⇕㛤ጞ ᗘ㸦0.02 Υ/min ࡢⓎ⇕㏿ᗘ࡞ࡿ ᗘ㸧ࢆィ⟬ࡋ㸪ࡑࢀࡽࡢィ⟬⤖ᯝC80 ࡼࡗ࡚ ᐃࡉ ࢀࡓⓎ⇕㛤ጞ ᗘࢆẚ㍑ࡋࡓ㸬እᤄⓎ⇕㛤ጞ ᗘࡢồࡵ ᪉ࡢᴫᛕࢆᅗ10 ♧ࡍ㸬ࡲࡓ㸪C80 ࡼࡗ࡚ ᐃࡉࢀ ࡓ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ࢜ࣞࣥ㓟ࡢⓎ⇕ᣲືࢆ ᅗ11 ♧ࡍ㸬 ୖグࡢ᪉ἲࡼࡾồࡵࡓC80 ᐃࡼࡾᚓࡽࢀࡓⓎ ᅗ8 DARC ࡼࡿ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ ࢜ࣞࣥ㓟ࡢⓎ⇕㏿ᗘࡢẚ㍑ 100 200 300 400 10-2 10-1 100 101 102 100 200 300 400 10-2 10-1 100 101 102 6.0 g 0.7 g 㻌 Se lf h ea t r at e [ Υ /m in ] Temperature [Υ] Oleic acid Polyethylene glycol 6.0 g 㻌 S el f h ea t r ate [ Υ /m in ] Temperature [Υ] 0.7 g ᅗ9 ࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ࢜ࣞࣥ㓟ࡢ ARC ࡢ⿵ṇ⤖ᯝ DARC ࡢ ᐃ⤖ᯝࡢẚ㍑ 100 200 300 400 10-2 10-1 100 101 102 100 200 300 400 10-2 10-1 100 101 102 103 ARCȭ⿵ṇ๓ ARCȭ⿵ṇᚋ DARC 㻌 Se lf he at ra te [ Υ /m in ] Temperature [Υ] Oleic acid S el f h ea t r at e [ Υ /m in ] Temperature [Υ] Polyethylene glycol DARC ARC ȭ⿵ṇᚋ ARCȭ⿵ṇ๓ ᅗ10 ARC ཬࡧ DARC ⤖ᯝࡽࡢእᤄⓎ⇕㛤ጞ ᗘࡢ ồࡵ᪉ࡢᴫせ 100 200 300 400 10-2 10-1 100 101 102 103 DARCࡢ እᤄⓎ⇕㛤ጞ ᗘ ARCࡢ እᤄⓎ⇕㛤ጞ ᗘ ARC ȭ⿵ṇᚋ DARC S el f h ea t r at e [ Υ /m in ] Temperature [Υ]--
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⇕㛤ጞ ᗘཬࡧARC㸪DARC ࡼࡾᚓࡽࢀࡓእᤄⓎ⇕ 㛤ጞ ᗘࢆ⾲3 ࡲࡵࡓ㸬ࡑࡢ⤖ᯝ㸪࢜ࣞࣥ㓟࠾ ࠸࡚㸪ࡑࢀࡒࢀࡢ ᐃ᪉ἲ࡛ᚓࡽࢀࡓⓎ⇕㛤ጞ ᗘࡣ㸪 ࡁ࡞ᕪࡀぢࡽࢀ࡞ࡗࡓ㸬୍᪉㸪࣏࢚ࣜࢳࣞࣥࢢࣜࢥ ࣮ࣝ࠾࠸࡚㸪DARC ࡼࡾᚓࡽࢀࡓⓎ⇕㛤ጞ ᗘࡣ㸪 ARC ཬࡧ C80 ࡼࡾᚓࡽࢀࡓⓎ⇕㛤ጞ ᗘࡼࡾࡶ᫂ࡽ పࡃ࡞ࡗࡓ㸬C80 ࡼࡗ࡚ᚓࡽࢀࡓⓎ⇕ᣲືࢆぢࡿ 㸪࢜ࣞࣥ㓟࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮࡛ࣝࡣⓎ⇕ᣲື ࡀࡁࡃ␗࡞ࡗ࡚࠸ࡿ㸦ᅗ11㸧㸬ࡍ࡞ࢃࡕ㸪ARC ཬࡧ DARC ࡢ ᐃ⤖ᯝࢆእᤄࡍࡿ㝿㸪࢜ࣞࣥ㓟࣏࢚ࣜࢳ ࣞࣥࢢࣜࢥ࣮ࣝࡢᛂᣲືࡢ㐪࠸ࡀホ౯⤖ᯝᙳ㡪ࢆཬ ࡰࡋ࡚࠸ࡿྍ⬟ᛶࡀ⪃࠼ࡽࢀࡿ㸬ࡋࡋ㸪࠸ࡎࢀࡢ ᐃ ᪉ἲ࡛ࡶ࢜ࣞࣥ㓟ࡢⓎ⇕㛤ጞ ᗘࡣ㸪࣏࢚ࣜࢳࣞࣥࢢ ࣜࢥ࣮ࣝࡢⓎ⇕㛤ጞ ᗘࡼࡾࡶప࠸್ࢆ♧ࡋ࡚࠾ࡾ㸪 DARC ࡛ࡢ ᐃࡼࡗ࡚㸪Ꮫ≀㉁ࡢ⮬↛Ⓨⅆ༴㝤ᛶࡢ ᑠࡀホ౯࡛ࡁ࡚࠸ࡿ⪃࠼ࡽࢀࡿ㸬 ௨ୖࡼࡾ㸪DARC ࢆ⏝࠸ࡓ ᐃࡣ㸪᪤Ꮡࡢ⮬↛Ⓨⅆ ホ౯ヨ㦂ἲࡼࡾࡶ▷㛫࡛≀㉁ࡢ⮬↛Ⓨⅆᛶࢆホ౯࡛ࡁ ࡿࢫࢡ࣮ࣜࢽࣥࢢἲࡋ࡚ά⏝࡛ࡁࡿྍ⬟ᛶࡀ♧ࡉࢀࡓ㸬 5 ࠾ࢃࡾ ㈓ᵴ࡞࠼ࡽࢀࡓ㔞ࡢᏛ≀㉁ࡣ㸪ࡑࡢ୰࡛Ⓨ ⇕ᛂࡀ⏕ࡌࡿ㸪⇕ࡋࡸࡍ࠸ࡇࡽᛂࡀ⇕ᭀ㉮ ࡍࡿྍ⬟ᛶࡀ࠶ࡿ㸬ᛂࡢึᮇࡣࡁࢃࡵ࡚ࡺࡗࡃࡾ ㇟ࡀ㐍ᒎࡍࡿࡓࡵసᴗ⪅ࡣㄆ㆑ࡋ࡙ࡽࡃ㸪ᛂࡢ㐍 ᒎࢆㄆ㆑ࡋࡓࡣࡍ࡛⇕ᭀ㉮ࢆṆࡵࡿࡓࡵࡢᥐ⨨ࢆ ㅮࡎࡿࡣ㛫ࡀ㊊ࡾ࡞࠸ሙྜࡀከ࠸㸬ࡋࡓࡀࡗ࡚㸪 ๓ࡢ༴㝤ᛶホ౯ࡀᴟࡵ࡚㔜せ࡞ࡿ㸬ࡑࡇ࡛㸪ᚤᑠ࡞Ⓨ ⇕ࡽከẁ㝵ࡢᛂࡼࡿᭀ㉮ᛂࡸ⮬↛Ⓨⅆࡢ༴㝤ᛶ ࢆ⢭ᐦホ౯࡛ࡁࡿ⪃࠼ࡽࢀࡿ♧ᕪᆺ᩿⇕⇕㔞ィ 㸦DARC㸧ࢆᑟධࡋ㸪ᚑ᮶⨨㸦ARC㸧ࡢẚ㍑᳨ウࢆ ⾜࠺ࡇࡼࡾᚓࡽࢀࡓ⤖ᯝࡢጇᙜᛶࢆ᳨ウࡋࡓ㸬ࡲࡓ㸪 ㈓ᵴࡢᐃᮇಟ⌮࣭ゎయࡢ༴㝤ᛶࡀᠱᛕࡉࢀࡿᛂࡋ ࡚㸪㈓ᵴෆᐜ≀ࡢ㓟ࡼࡿ⮬↛Ⓨⅆࢆ㑅ᐃࡋ㸪Ἔ㢮ࡢ ࣔࢹࣝ≀㉁ࡋ࡚࣏࢚ࣜࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ࢜ࣞࣥ 㓟ࡢ㓟ࡼࡿⓎ⇕ᣲືࢆ ᐃࡋ㸪⮬↛Ⓨⅆᛶࡢホ౯ ࡢ㐺⏝ᛶࢆ᳨ウࡋࡓ㸬 ࡑࡢ⤖ᯝ㸪DARC ࡣ㸪᩿⇕᮲௳࡛ࡢⓎ⇕ࡢ㏣ᚑᛶࡀඃ ࢀ࡚࠾ࡾ㸪≉Ⓨ⇕㔞ࡀᑠࡉ࠸ᛂࡢⓎ⇕ᣲືࢆ⢭ᗘࡼ ࡃ ᐃ࡛ࡁࡿࡇࢆ☜ㄆ࡛ࡁࡓ㸬ࡲࡓ㸪ARC ࡛ࡢ ᐃࡀ ᅔ㞴࡛࠶ࡿᚤᙅ࡞Ⓨ⇕ࢆ♧ࡍᛂࡘ࠸࡚㸪DARC ࡛ࡣ ᐇつᶍ࡛ࡢⓎ⇕ᣲືࢆ᥎ ࡍࡿࡓࡵᚲせ࡞ᛂ㏿ᗘࣃ ࣓࣮ࣛࢱࢆARC ࡼࡾࡶ⢭ᗘࡼࡃண ࡛ࡁࡿࡇࢆ☜ㄆ ࡛ࡁࡓ㸬 ࡉࡽ㸪DARC ࡛ ᐃࢆ⾜ࡗࡓ⤖ᯝ㸪࠸ࡎࢀࡢ≀㉁ ࠾࠸࡚ࡶ㓟ᛂࡼࡿ⪃࠼ࡽࢀࡿⓎ⇕ࢆ᳨▱ࡍࡿࡇ ࡀ࡛ࡁ㸪᪤Ꮡࡢ⮬↛Ⓨⅆホ౯ヨ㦂ἲẚࡿ▷㛫 ࡛⮬↛Ⓨⅆ༴㝤ᛶࢆホ౯࡛ࡁࡿྍ⬟ᛶࡀ࠶ࡿࡇࡀ♧ࡉ ࢀࡓ㸬 ௨ୖࡢ⤖ᯝࢆ㋃ࡲ࠼㸪ᚋ㸪ᚑ᮶ࡢヨ㦂ἲ࡛ホ౯ࡀᅔ 㞴࡛࠶ࡗࡓ」ᩘࡢᛂࡸከẁࡢᛂࡀ⏕ࡌࡿ≀㉁ࡸΰྜ ≀ࡢᭀ㉮ᛂ㛵ࡍࡿ༴㝤ᛶࢆホ౯ࡍࡿࡇࡼࡾ㸪⇿ Ⓨ࣭ⅆ⅏⅏ᐖࡢ㜵Ṇࡢࡓࡵࡢ᳨ウࡢᇶ┙࡞ࡿࢹ࣮ࢱࢆ ᥦ౪ࡋ࡚࠸ࡃ㸬ࡲࡓ㸪DARC ࡢ ᐃࡼࡿ⮬↛Ⓨⅆ༴㝤 ᛶࡢホ౯ࡢ㐺⏝ࢆ✚ࡋ㸪ⅆ⅏⅏ᐖࡢ㜵Ṇ㈉⊩ࡋ ࡚࠸ࡃ㸬 ཧ ⪃ ᩥ ⊩ 1) ⫋ሙࡢ࠶ࢇࡐࢇࢧࢺ㸪Ꮫᕤሙࡢ㈓ⶶࢱࣥࢡࡢࡢࡒࡁ❆ ࡀ◚㸪http://anzeninfo.mhlw.go.jp/anzen_pg/SAI_DET. aspx?joho_no=101325㸪ཧ↷ 2015-06-22. 2) ⫋ሙࡢ࠶ࢇࡐࢇࢧࢺ㸪ࢡࣞ࢜ࢯ࣮ࢺἜࡢ㈓ⶶࢱࣥࢡࡢ㛤 ᨺ᳨ᰝࡢ‽ഛ୰㈓ⶶࢱࣥࢡࡀ⇿Ⓨ㸪http://anzeninfo. mhlw.go.jp/anzen_pg/SAI_DET.aspx?joho_no=101094㸪 ཧ↷2015-06-22. 3) ඵᓥṇ᫂㸬⏘ᴗ⌧ሙ࠾ࡅࡿⅆ⅏࣭⇿Ⓨ⅏ᐖGHS ศ㢮 㸫ᘬⅆᛶᾮయྍ⇞ᛶᅛయࡢሙྜ㸫㸬ປാᏳ⾨⏕⥲ྜ◊ ✲ᡤ≉ู◊✲ሗ࿌JNIOSH-SRR-NO.40㸸2010; 5-12. 4) ᳃ᓮ⦾㸪㥖ᐑᨷ㢠㸪ෆ⸨㐨ኵ㸬ᛂᛶ≀㉁ࡢ⇕Ᏻᐃᛶ㛵 ࡍࡿ◊✲㸫⇕ศᯒཬࡧ᩿⇕ ᐃ㸫㸬⏘ᴗᏳ◊✲ᡤ≉ู◊ ✲ሗ࿌SRR-83-1㸹1983 5) ᳃ᓮ⦾㸪Ᏻ⸨㝯அ㸬Ꮫ≀㉁ࡢ⇕༴㝤ᛶࡢゎᯒண 㸬⏘ ᴗᏳ◊✲ᡤᏳ㈨ᩱRIIS-SD-88㸹1988 6) ⍆ᐤᓫ㸪ෆ⸨㐨ኵ㸬⮬↛Ⓨⅆヨ㦂⨨ࡢᵓ㐀ᛶ⬟㸬⏘ᴗ Ᏻ◊✲ᡤ◊✲ሗ࿌RR-27-2㸹1979 ⾲3 C80 ᐃࡼࡾᚓࡽࢀࡓⓎ⇕㛤ጞ ᗘཬࡧ ARC㸪DARC ࡼࡾᚓࡽࢀࡓእᤄⓎ⇕㛤ጞ ᗘ ᐃ⨨ ᗘ [Υ] ࢜ࣞࣥ㓟 ࣏࢚ࣜࢳࣞࣥ ࢢࣜࢥ࣮ࣝ DARC㸦እᤄⓎ⇕㛤ጞ ᗘ㸧 49 64 ARC㸦እᤄⓎ⇕㛤ጞ ᗘ㸧 46 90 C80㸦࣮࣋ࢫࣛࣥࡽ⇕ὶ᮰ ࡀ❧ࡕୖࡀࡿ ᗘ㸧 55 83 ᅗ11 C80 ࡼࡗ࡚ ᐃࡉࢀࡓ࢚ࢳࣞࣥࢢࣜࢥ࣮ࣝཬࡧ ࢜ࣞࣥ㓟ࡢⓎ⇕ᣲື 50 100 150 200 exo. H ea t f lo w [m W /g ] Temperature [Υ] 10 Oleic acid Polyethylene glycol--
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7) ⍆ᐤᓫ㸪ෆ⸨㐨ኵ㸪⏣㐨⏨㸪⛅⏣୍㞝㸬⮬↛Ⓨⅆヨ㦂 ⨨ࢆ⏝࠸࡚⇕Ⓨⅆ㝈⏺ ᗘࢆ⟬ฟࡍࡿヨࡳ㸬ᏳᕤᏛ㸬 1981; 20(1): 9-15. 8) ⍆ᐤᓫ㸪ෆ⸨㐨ኵ㸬ሁ✚ᮌ⢊㢮ࡢ㓟Ⓨ⇕ᛶ≧㸬⏘ᴗᏳ ◊✲ᡤ≉ู◊✲ሗ࿌SRR-82-1㸸1982; 117-135. 9) ⍆ᐤᓫ㸬᭷ᶵ᪂⣲ᮦ≀㉁ᑐࡍࡿBAM ⇕㈓ⶶヨ㦂ᐇ 㸬⏘ᴗᏳ◊✲ᡤ≉ู◊✲ሗ࿌SRR-No.12㸸1993; 77-82.10) Townsend DI, Tou JC. Thermal hazard evaluation by an accelerating rate calorimeter. Thermochim. Acta. 1980; 37: 1-30.
11) ⳥ụṊྐ㸬ARC ࡼࡿᛂᛶᏛ≀㉁ࡢ⇕ᭀ㉮༴㝤ᛶࡢ ホ౯㸬ఫᏛ㸬1989; 1989-I: 61-81.
12) ⳥ụṊྐ㸬ARC ᐃࢹ࣮ࢱࡢᐇ⨨ࡢ㐺⏝᪉ἲ㸬Ᏻ ᕤᏛ㸬2001; 40: 100-107.
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